Table 2.
Lipase-catalyzed modification of methoxylated derivatives of cinnamic acid with neutral fatty acids and triacylglycerols.
| Type of Lipid | Molecule | Type of Reaction | Reaction Conditions | Conv. | Refs. |
|---|---|---|---|---|---|
|
FATTY
ALKOHOLS |
FA | esterification |
Rhizomucor miehei, 50 °C, 12 days, octanol |
30% | [68] |
| FA | esterification | Novozym 435, 92.2 °C, 3 days, octanol |
93% | [69] | |
| FA | esterification | Novozym 435, 78 °C, 1 day,2-ethylhexanol |
100% | [70] | |
| FA | esterification | Novozym 435, 60 °C, 4 days, oleyl alcohol in ionic liquide/isooctane octanol |
97% | [71] | |
| FA | esterification |
Rhizomucor miehei, 50 °C, 3 days, decyl alkohol in n-hexan |
88% | [72] | |
| EF | transesterification | Novozym 435, 60 °C, 6 days, octanol |
83% | [73] | |
| p-MCA | esterification | Novozym 435, 80 °C, 1 day, 2-ethyl hexanol |
90% | [64] | |
| p-MCA | esterification |
Rhizopus oryzae, 45 °C, 4 days, cyclooctan, 2-ethylhexanol |
91% | [65] | |
|
p-MCA 3,4MCA FA |
esterification | Novozym 435, 80 °C, 2.5 days cis-9-octadecen-1-ol |
94% 25% 94% |
[67] | |
| Mp-MCA MF EF |
transesterification | Novozym 435, 80 °C, 3 days, cis-9-octadecen-1-ol |
92% 91% 89% |
[74] | |
| 3,4DMCA | esterification | Novozym 435, 60 °C, 15 days, octanol |
3% | [75] | |
| EF | transesterification | Novozym 435, 45 °C, 6 days, soy oil |
64% | [63] | |
| TRIACYLGLICEROLS | EF | transesterification | Novozym 435, 60 °C, 22 days, cocconut butter shea butter, |
63% 70% |
[76] |
| EF | transesterification | Novozym 435, 50 °C, 5 days, tributyryne in toluene |
75% | [77] | |
| EF | transesterification | Novozym 435, 90 °C, 7 days, castor oil |
100% | [78] | |
| FA | acidolysis | Novozym 435, 55 °C, 10 days, trioleine in hexane/butanone, (85/15) |
62% | [79] | |
| FA 3,4DMCA |
acidolysis | Novozym 435, 55 °C, 10 days, linseed oil in hexane/butanone, (85/15) |
19% 10% |
[80] | |
| FA | acidolysis | Novozym 435, 55 °C, 10 days, trioleine in hexane/butanone, (75/25) |
15% | [81] |
FA—ferulic acid, EF—ethyl ferulate, MF—methyl ferulate, p-MCA—para methoxy cinnamic acid, Ep-MCA—ethyl p-met—oxycinnamate, Mp-MCA—methyl p-methoxycinnamate, 3,4MCA—3,4-dimethoxycinnamic acid.