Table 1.
Summary table showing average TON and initial TOF values for Co4, Co9, Co20 and the Weakley‐type POM {Co4P2W18} as well as the O2 yield generated by the respective POM with varying concentration (2–20 μm) in borate buffer [80 mm], pH=8.0.
|
Co‐POM (μm) |
O2 [μmol] (TON) |
TOF [s−1] |
O2 yield [%] |
|---|---|---|---|
|
Co4 (2) |
0.480 (120.50) |
0.422 |
9.60 |
|
Co9 (2) |
0.640 (159.90) |
0.608 |
12.80 |
|
Co20 (2) |
0.450 (111.40) |
0.405 |
4.50 |
|
Co4 (5) |
0.470 (46.90) |
0.148 |
9.40 |
|
Co9 (5) |
0.710 (71.30) |
0.263 |
14.20 |
|
Co20 (5) |
0.575 (57.50) |
0.189 |
28.40 |
|
Co4 (10) |
0.520 (25.90) |
0.091 |
10.40 |
|
Co9 (10) |
0.790 (39.30) |
0.125 |
15.80 |
|
Co20 (10) |
0.690 (34.40) |
0.105 |
13.80 |
|
Co4 (20) |
0.450 (11.30) |
0.047 |
9.00 |
|
Co9 (20) |
0.860 (21.60) |
0.069 |
17.20 |
|
Co20 (20) |
0.810 (20.40) |
0.068 |
16.20 |
|
{Co4P2W18} (20) |
0.430 (10.90) |
0.015 |
8.60 |