Crystal structure of silver carbonate iodide Ag₁₀(CO₃)₃I₄

The new silver carbonate iodide, Ag₁₀(CO₃)₃I₄, comprises layers of I atoms, Ag atoms, and CO₃ groups stacked along [10].

Abstract

The title silver carbonate iodide, Ag₁₀(CO₃)₃I₄, deca­silver(I) tris­(carbonate) tetra­iodide, was recently reported as a precursor of the new superionic conductor Ag₁₇(CO₃)₃I₁₁. Ag₁₀(CO₃)₃I₄, was prepared by heating a stoichiometric powder mixture of AgI and Ag₂CO₃ at 430 K. A single-crystal suitable for X-ray diffraction analysis was obtained by slow cooling of a melt with an AgI-rich composition down from 453 K. Ag₁₀(CO₃)₃I₄ exhibits a layered crystal structure packed along [10], in which Ag atoms are inter­calated between the layers of hexa­gonally close-packed I atoms, and CO₃ groups. Up to now, Cs₃Pb₂(CO₃)₃I is the only other compound containing carbonate groups and iodide ions registered in the Inorganic Crystal Structure Database.

Chemical context  

α-AgI is a representative superionic conductor of silver ions (Tubandt & Lorenz, 1914 ▸; Boyce & Huberman, 1979 ▸), which is synthesized at 420 K from wurzite-type β-AgI and is stable above the phase transition temperature. Many ternary and quaternary compounds containing Ag and I, such as β-Ag₃SI (Takahashi & Yamamoto, 1966 ▸), Ag₄RbI₅ (Owens & Argue, 1967 ▸,1970 ▸; Geller, 1967 ▸; Bradley & Greene, 1967a ▸,b ▸), Ag₄KI₅ (Owens & Argue, 1967 ▸; Bradley & Greene, 1966 ▸,1967b ▸), Ag₃KI₄ (Takahashi et al., 1970 ▸), Ag₁₉I₁₅P₂O₇, Ag₇I₄PO₄ (Takahashi et al., 1972 ▸), Ag₆I₄WO₄ (Takahashi et al., 1973 ▸), and Ag₇(AsO₄)I₄ and Ag₇I₄VO₄ (Scrosati et al., 1975 ▸) have been synthesized and investigated as silver ion conductors. The crystal structures and Ag⁺ ionic conductivity of several silver compounds prepared by combining AgI and a silver oxyanion salt have also been reported (see Database survey). However, our recent report on the new superionic conductor Ag₁₇(CO₃)₃I₁₁ (Watanabe et al., 2021 ▸) was the first example of a compound in the AgI–Ag₂CO₃ pseudo-binary system. The superionic conductor Ag₁₇(CO₃)₃I₁₁ was prepared by a reaction between AgI and another silver carbonate iodide, i.e., Ag₁₀(CO₃)₃I₄. Herein, we report the crystal structure analysis of Ag₁₀(CO₃)₃I₄ by single-crystal X-ray diffraction (XRD). It should be noted that Cs₃Pb₂(CO₃)₃I (Liu et al., 2016 ▸) is the only other compound containing carbonate groups and an iodide ion in its chemical composition that can be currently found in the Inorganic Crystal Structure Database (ICSD; Zagorac et al., 2019 ▸).

A bulk Ag₁₀(CO₃)₃I₄ sample showed an ionic conductivity of 4.4×10⁻⁶ S cm⁻¹ at room temperature (RT) in the alternating-current impedance method using evaporated Au electrodes. This value is comparable with that of Ag₁₃(AsO₄)₃I₄ (6.4×10⁻⁶ S m⁻¹ at 303 K; Pitzschke et al., 2009a ▸) and Ag₄IPO₄ (3×10⁻⁶ S m⁻¹ at RT; Oleneva et al., 2008 ▸).

Structural commentary  

Ag₁₀(CO₃)₃I₄ crystallizes in a monoclinic cell with the space group P2₁/c. The asymmetric unit of the structure comprises 40 sites for Ag, 16 for I, 12 for C, and 36 for O. The Ag atoms are aligned parallel to (10), and an Ag layer is sandwiched between a CO₃ layer and the hexa­gonally aligned I layer, as shown in Fig. 1 ▸. The atomic arrangement of Ag and I atoms and CO₃ groups in the layers is projected on (10) in Fig. 1 ▸, and along [101] and [010] in Fig. 2 ▸ a and Fig. 2 ▸ b, respectively. Reflecting the complexity of the crystal structure, there is a large variation in the inter­atomic distances. The shortest inter­atomic distance for each atom pair (Ag—O, Ag⋯Ag, Ag—I, etc.) is listed in Table 1 ▸.

Figure 1.

Arrangement of Ag and I atoms and CO₃ groups in the crystal structure of Ag₁₀(CO₃)₃I₄ projected on (10). Displacement ellipsoids are drawn at the 99% probability level.

Figure 2.

Projections of the crystal structure of Ag₁₀(CO₃)₃I₄ along [101] (a) and [010] (b).

Table 1. Shortest inter­atomic distances (Å) in the crystal structure of Ag₁₀(CO₃)₃I₄ .

Atom pair	Distance
Ag12—O23	2.252 (9)
Ag7—I6	2.7140 (14)
Ag26⋯Ag32 (in-layer)	2.9901 (15)
Ag13⋯Ag33 (out-of-layer; across CO3 layer)	3.0620 (15)
Ag17⋯Ag27i (out-of-layer; across I layer)	2.9507 (15)
I10⋯I12ii	3.9564 (11)
C1—O1iii (within a CO3 group)	1.251 (15)
O25⋯O26 (within a CO3 group)	2.206 (14)
O15⋯O25 (between different CO3 groups)	2.816 (15)

Symmetry code: (i) x, −y + {1\over 2}, z − {1\over 2}; (ii) −x, −y + 1, −z + 1; (iii) x + 1, y + {1\over 2}, z + {1\over 2}.

Fundamental reflections in the XRD pattern were observed at every eight spots along the b* axis in the reciprocal space (Fig. S1 in the supporting information), and a period of b/8 = ∼4.43 Å corresponds to the average I⋯I distance in the layer of two-dimensionally closely packed I atoms along the b axis. The average I⋯I distance is slightly shorter than that of the close-packed I atom layer of β-AgI [4.5910 (11) Å; Yoshiasa et al., 1987 ▸]. The shortest I⋯I length of 3.9564 (11) Å for I10–I12 in Ag₁₀(CO₃)₃I₄ lies between the values observed in Ag₁₃(AsO₄)₃I₄ [3.9063 (9) Å; Pitzschke et al., 2009a ▸] and Ag₂₆I₁₈(WO₄)₄ [4.03 (3) Å; Chan & Geller, 1977 ▸].

The CO₃ groups are aligned on approximately every b/4 period with the oxygen atoms oriented in different directions. The C—O bond lengths are in the range from 1.251 (15) Å for C1—O1 to 1.328 (15) Å for C1—O3, with the average length being 1.290 Å, which is longer than the C—O length in Ag₂CO₃ (1.274 Å; Norby et al., 2002 ▸) but close to those in CaCO₃ (1.282 Å; Maslen et al., 1995 ▸) and other calcite-type carbonates [1.2852 (4) Å in MgCO₃, 1.2867 (5) Å in MnCO₃, 1.2869 (5) Å in FeCO₃, 1.2859 (6) Å in ZnCO₃, and 1.2853 (4) Å in CaMg(CO₃)₂; Effenberger et al., 1981 ▸]. The short O⋯O distance of 2.816 (15) Å for O15⋯O25 belonging to different CO₃ groups is close to 2.85 Å as observed in MgCO₃ and ZnCO₃ (Effenberger et al., 1981 ▸).

The Ag atoms are coordinated by two or three I atoms, and two, three, or four O atoms of the CO₃ groups, with average distances of 3.20 Å for Ag—I and 2.85 Å for Ag—O. The shortest Ag—I bond length of 2.7140 (14) Å for Ag7—I6 is comparable with that found in Ag₁₃(AsO₄)₃I₄ [2.701 (1) Å; Pitzschke et al., 2009a ▸] but shorter than the Ag—I bond lengths in β-AgI [2.8112 (10) and 2.819 (3) Å; Yoshiasa et al., 1987 ▸]. The shortest Ag—O length is 2.252 (9) Å for Ag12—O23, which is slightly longer than the shortest Ag—O length in Ag₂CO₃ (2.245 Å; Norby et al., 2002 ▸).

The shortest Ag⋯Ag distance of 2.9507 (15) Å is observed between Ag17 and Ag27 generated in another Ag layer across the I layer by the symmetry operation x, −y + , z − . The second shortest Ag⋯Ag distance is 2.9901 (15) Å and corresponds to Ag26⋯Ag32 in the same Ag layer. The shortest Ag⋯Ag distance across the CO₃ layer is 3.0620 (15) Å for Ag13⋯Ag33. These distances are comparable with the Ag⋯Ag distances reported for Ag₂CO₃ [2.8731 (10) Å; Norby et al., 2002 ▸], Ag₈(CrO₄)₃I₂ [2.8797 (8) Å; Pitzschke et al., 2009b ▸], and Ag₃I(NO₃)₂ [2.942 (8) Å; Birnstock & Britton, 1970 ▸]. Such short Ag⋯Ag distances are known to stem from the argentophilic d ¹⁰⋯d ¹⁰ inter­actions between Ag⁺ cations (Schmidbaur & Schier, 2015 ▸; Jansen, 1987 ▸).

Database survey  

The crystal structures of quaternary inorganic compounds composed of silver and iodide ions and oxyanionic groups, such as Ag₂I(NO₃)₂ (Birnstock & Britton, 1970 ▸), Ag₁₆I₁₂P₂O₇ (Garrett et al., 1982 ▸), Ag₅IP₂O₇ (Adams & Preusser, 1999 ▸), Ag₄IPO₄ (Oleneva et al., 2008 ▸), Ag₈(CrO₄)₃I₂ (Pitzschke et al., 2009b ▸), Ag₉(GeO₄)₂I (Pitzschke et al., 2009c ▸), Ag₈I₄V₂O₇ (Adams, 1996 ▸), Ag₁₃(AsO₄)₃I₄ (Pitzschke et al., 2009a ▸), Ag₄I₂SeO₄ (Pitzschke et al., 2008a ▸), Ag₃ITeO₄ (Pitzschke et al., 2008a ▸), Ag₉I₃(IO₃)₂(SeO₄)₂ (Pitzschke et al., 2008b ▸) and Ag₂₆I₁₈(WO₄)₄ (Chan & Geller, 1977 ▸) have been reported.

Synthesis and crystallization  

As starting materials, powders of AgI and Ag₂CO₃ were prepared by precipitation from aqueous solutions containing AgNO₃ (99.8%, Kanto Chemical) and KI (99.5%, Kanto Chemical) at 323 K, and aqueous solutions of AgNO₃ and (NH₄)₂CO₃ (>30%_wt as NH₃, Kanto Chemical) at RT, respectively. The obtained polycrystalline solids were thoroughly mixed in an agate mortar at a molar ratio of 4:3 using a small amount of water as a mixing medium.

A bulk brownish sample was prepared at 430 K in a glass tube with one end open. The sample was then powdered with an agate mortar and subjected to powder XRD analysis using a Rigaku MiniFlex 600 powder X-ray diffractometer with Cu Kα radiation (λ = 1.54183 Å) and a 1D detector (Rigaku D/teX Ultra 250).

As for many other silver compounds, Ag₁₀(CO₃)₃I₄ is photo-sensitive. In contrast, Ag₁₀(CO₃)₃I₄ is thermally stable against heat treatment in air; no substantial mass change was observed up to 473 K in a thermogravimetric and differential thermal analysis (TG–DTA, Rigaku Thermo Evo) (Fig. S2), which was performed under a constant dry air flow of 100 sccm at a ramp rate of 3 K min⁻¹, indicating that neither a thermal decomposition nor oxidation occurred. An endothermic effect around 443 K, which can be attributed to the melting of Ag₁₀(CO₃)₃I₄, was observed in the TG–DTA analysis. A sample suitable for single-crystal XRD was prepared by subjecting a mixture of the starting powders containing a slight AgI excess composition (AgI:Ag₂CO₃ = 4.2:3) to the following heat treatment: after heating to 453 K at a ramp rate of 300 K h⁻¹, this temperature was held for 15 min, followed by cooling to 373 K at 1 K h⁻¹. The solidified sample was soft and easy to cut with a knife; however, all specimens obtained by cutting showed diffuse XRD spots and were not suitable for single-crystal XRD measurement. Relatively sharp XRD spots were observed from a fragment with a size of 252×245×78 µm, which was spontaneously and accidentally separated by cracking. The surface of the fragment was black and covered with polycrystalline Ag, which was presumably formed by photodegradation during handling. The fragment was fixed on a glass fiber with an ep­oxy resin and mounted on a goniometer under red light through a color filter from an LED lamp, and the XRD data were collected at 90 K with an open-flow nitro­gen gas cooler (Oxford Cobra) in the dark.

Refinement  

Crystal data, data collection and structure refinement details are summarized in Table 2 ▸. The initial structure model of the space group P2₁/c was obtained by intrinsic phasing in the APEX3 package (Bruker, 2017 ▸). Large positive and negative difference-Fourier peaks were observed, a feature that was probably caused by reflections overlapped with Debye–Scherrer rings from polycrystalline Ag metal on the surface of the crystal (Fig. S1). From the total independent 16240 reflections, 672 reflection data were excluded to lower the difference level within 2.6 e Å⁻³ with R1 = 0.0573 for 13157 [F _o > 4σ (F _o)] and 0.0689 for all 15568 data with GooF(S) = 1.140. The space groups P2₁, Pc, and P1 with twin models were also tested; however, neither further effective improvement of the R values nor reduction of the residual densities was achieved. The anisotropic displacement parameters of O2, O10, and O15 and the carbon sites were restrained with the ISOR command of SHELXL (Sheldrick, 2015b ▸) in the final refinement. A Rietveld analysis (Rigaku, 2018 ▸) based on the structural model determined by single-crystal XRD led to monoclinic unit-cell parameters of a = 14.2865 (7), b = 35.5959 (18), c = 17.0182 (8) Å, and β = 122.493 (2)° at RT with R _F/wR = 0.0294/0.0436 (Fig.  S3), which validates the structural model determined by single-crystal XRD analysis.

Table 2. Experimental details.

Crystal data
Chemical formula	Ag10(CO3)3I4
M r	1766.33
Crystal system, space group	Monoclinic, P21/c
Temperature (K)	90
a, b, c (Å)	14.2342 (11), 35.421 (3), 16.9683 (12)
β (°)	122.725 (3)
V (Å3)	7197.3 (10)
Z	16
Radiation type	Mo Kα
μ (mm−1)	17.53
Crystal size (mm)	0.25 × 0.25 × 0.08
Data collection
Diffractometer	Bruker D8 goniometer
Absorption correction	Multi-scan (SADABS; Krause et al., 2015 ▸)
Tmin, Tmax	0.376, 0.746
No. of measured, independent and observed [I > 2σ(I)] reflections	75437, 15568, 13140
R int	0.043
(sin θ/λ)max (Å−1)	0.649
Refinement
R[F2 > 2σ(F 2)], wR(F 2), S	0.057, 0.126, 1.14
No. of reflections	15568
No. of parameters	937
No. of restraints	90
Δρmax, Δρmin (e Å−3)	2.22, −2.62

Computer programs: APEX3 (Bruker, 2017 ▸), SAINT (Bruker, 2017 ▸), SHELXT (Sheldrick, 2015a ▸), SHELXL (Sheldrick, 2015b ▸), VESTA (Momma & Izumi, 2011 ▸), and pubCIF (Westrip, 2010 ▸).

Supplementary Material

CCDC reference: 2088991

Additional supporting information: crystallographic information; 3D view; checkCIF report

supplementary crystallographic information

Crystal data

Ag10(CO3)3I4	F(000) = 12352
Mr = 1766.33	Dx = 6.520 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
a = 14.2342 (11) Å	Cell parameters from 4917 reflections
b = 35.421 (3) Å	θ = 2.7–35.6°
c = 16.9683 (12) Å	µ = 17.53 mm−1
β = 122.725 (3)°	T = 90 K
V = 7197.3 (10) Å3	Platelet, brown transparent (black agi precipiated on the surface)
Z = 16	0.25 × 0.25 × 0.08 mm

Data collection

Bruker D8 goniometer diffractometer	15568 independent reflections
Radiation source: micro focus sealed tube	13140 reflections with I > 2σ(I)
Detector resolution: 7.3910 pixels mm-1	Rint = 0.043
ω scans	θmax = 27.5°, θmin = 2.1°
Absorption correction: multi-scan (SADABS; Krause et al., 2015)	h = −18→18
Tmin = 0.376, Tmax = 0.746	k = −45→46
75437 measured reflections	l = −22→22

Refinement

Refinement on F2	90 restraints
Least-squares matrix: full	Primary atom site location: structure-invariant direct methods
R[F2 > 2σ(F2)] = 0.057	w = 1/[σ2(Fo2) + (0.0103P)2 + 615.6616P] where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.126	(Δ/σ)max = 0.001
S = 1.14	Δρmax = 2.22 e Å−3
15568 reflections	Δρmin = −2.61 e Å−3
937 parameters

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Ag1	0.08682 (9)	0.06634 (3)	0.20445 (7)	0.0138 (2)
Ag2	0.27633 (10)	0.03132 (3)	0.41983 (8)	0.0169 (2)
Ag3	0.55662 (9)	0.46648 (3)	0.19380 (7)	0.0150 (2)
Ag4	0.26078 (8)	0.57090 (3)	0.60251 (7)	0.01221 (19)
Ag5	0.03496 (8)	0.15772 (3)	0.17435 (7)	0.0125 (2)
Ag6	0.23310 (9)	0.18599 (3)	0.38229 (8)	0.0156 (2)
Ag7	0.43490 (10)	0.37201 (3)	0.05335 (8)	0.0184 (2)
Ag8	0.57487 (9)	0.31065 (3)	0.19823 (7)	0.0148 (2)
Ag9	0.25196 (9)	0.84280 (3)	0.09874 (7)	0.0160 (2)
Ag10	0.07104 (9)	0.75160 (3)	0.45762 (8)	0.0156 (2)
Ag11	0.07064 (9)	0.31349 (3)	0.19972 (7)	0.0156 (2)
Ag12	0.24584 (10)	0.27747 (3)	0.39764 (8)	0.0180 (2)
Ag13	0.55343 (9)	0.21817 (3)	0.18150 (8)	0.0157 (2)
Ag14	0.27216 (9)	0.67637 (3)	0.12176 (7)	0.0126 (2)
Ag15	0.05820 (8)	0.40832 (3)	0.19626 (7)	0.0130 (2)
Ag16	0.24072 (8)	0.44444 (3)	0.40286 (7)	0.0129 (2)
Ag17	0.42669 (9)	0.12869 (3)	0.03557 (7)	0.0136 (2)
Ag18	0.58339 (9)	0.05792 (3)	0.20303 (7)	0.0132 (2)
Ag19	0.22274 (9)	0.59037 (3)	0.06770 (8)	0.0181 (2)
Ag20	0.04730 (9)	0.00277 (3)	0.43913 (7)	0.0156 (2)
Ag21	0.08463 (9)	0.56456 (3)	0.20467 (7)	0.0129 (2)
Ag22	0.24736 (9)	0.53034 (3)	0.40259 (7)	0.0143 (2)
Ag23	0.46246 (8)	0.47035 (3)	0.32099 (7)	0.0122 (2)
Ag24	0.27468 (9)	0.42928 (3)	0.12342 (8)	0.0154 (2)
Ag25	0.04870 (8)	0.65006 (3)	0.19101 (7)	0.0132 (2)
Ag26	0.76530 (9)	0.19821 (3)	0.10542 (7)	0.0129 (2)
Ag27	0.57192 (9)	0.37693 (3)	0.46144 (7)	0.0137 (2)
Ag28	0.41143 (9)	0.30561 (3)	0.29182 (7)	0.0141 (2)
Ag29	0.22283 (10)	0.34487 (3)	0.07409 (8)	0.0178 (2)
Ag30	0.05501 (9)	0.24478 (3)	0.44679 (8)	0.0165 (2)
Ag31	0.08436 (9)	0.81768 (3)	0.20002 (7)	0.0131 (2)
Ag32	0.73211 (9)	0.28175 (3)	0.08057 (7)	0.0157 (2)
Ag33	0.45882 (8)	0.21862 (3)	0.30624 (7)	0.0128 (2)
Ag34	0.26225 (8)	0.18464 (3)	0.09611 (7)	0.0134 (2)
Ag35	0.03659 (8)	0.59658 (3)	0.67807 (7)	0.0125 (2)
Ag36	0.77018 (9)	0.44587 (3)	0.11381 (8)	0.0152 (2)
Ag37	0.54741 (9)	0.12430 (3)	0.44344 (7)	0.0145 (2)
Ag38	0.42942 (9)	0.05817 (3)	0.30366 (7)	0.0153 (2)
Ag39	0.24947 (9)	0.09758 (3)	0.10141 (7)	0.0145 (2)
Ag40	0.07517 (8)	0.49697 (3)	0.46486 (7)	0.0127 (2)
C1	0.1707 (10)	0.6132 (3)	0.4045 (9)	0.006 (2)
C2	0.1744 (11)	0.1016 (4)	0.4183 (10)	0.013 (3)
C3	0.5142 (11)	0.3904 (4)	0.2635 (9)	0.010 (2)
C4	0.0037 (11)	0.2318 (4)	0.2527 (9)	0.010 (2)
C5	0.3262 (9)	0.2685 (3)	0.0821 (8)	0.003 (2)
C6	0.6713 (12)	0.2601 (4)	0.3967 (10)	0.015 (3)
C7	0.8247 (11)	0.3606 (4)	0.0936 (9)	0.009 (2)
C8	0.1722 (11)	0.3591 (4)	0.4040 (10)	0.012 (2)
C9	0.4816 (11)	0.1403 (4)	0.2353 (9)	0.009 (2)
C10	0.0167 (10)	0.4843 (3)	0.2669 (9)	0.008 (2)
C11	0.3319 (11)	0.0134 (4)	0.0990 (9)	0.010 (2)
C12	0.3234 (12)	0.5137 (4)	0.0915 (10)	0.014 (3)
O1	0.7482 (8)	0.0913 (3)	0.0498 (6)	0.0107 (18)
O2	0.0858 (8)	0.6049 (3)	0.3234 (7)	0.0104 (18)
O3	0.1689 (8)	0.6468 (3)	0.4381 (6)	0.0117 (18)
O4	0.1132 (9)	0.0778 (3)	0.3555 (7)	0.016 (2)
O5	0.2745 (8)	0.0917 (3)	0.4871 (7)	0.018 (2)
O6	0.1392 (8)	0.1358 (3)	0.4168 (8)	0.017 (2)
O7	0.4765 (8)	0.4056 (3)	0.1825 (7)	0.0133 (19)
O8	0.5459 (8)	0.4123 (3)	0.3353 (7)	0.0127 (19)
O9	0.5252 (9)	0.3548 (3)	0.2765 (8)	0.019 (2)
O10	0.0376 (8)	0.7185 (3)	0.3300 (7)	0.0116 (18)
O11	0.0329 (8)	0.2081 (3)	0.3213 (7)	0.0116 (18)
O12	0.0199 (8)	0.2671 (3)	0.2713 (7)	0.0129 (19)
O13	0.2394 (9)	0.2290 (3)	0.4959 (7)	0.021 (2)
O14	0.3574 (9)	0.2988 (3)	0.1329 (7)	0.020 (2)
O15	0.3718 (10)	0.2370 (3)	0.1167 (8)	0.024 (2)
O16	0.5860 (8)	0.2710 (3)	0.3183 (7)	0.015 (2)
O17	0.2442 (8)	0.7812 (3)	0.0509 (7)	0.016 (2)
O18	0.3342 (8)	0.7264 (3)	0.0741 (7)	0.0137 (19)
O19	0.7387 (8)	0.3610 (3)	0.0068 (7)	0.016 (2)
O20	0.1418 (8)	0.8301 (3)	0.3600 (7)	0.0126 (19)
O21	0.8723 (8)	0.3927 (3)	0.1296 (7)	0.0128 (19)
O22	0.0857 (8)	0.3514 (3)	0.3222 (7)	0.0122 (19)
O23	0.2538 (8)	0.3370 (2)	0.4474 (7)	0.0122 (19)
O24	0.1684 (8)	0.3910 (3)	0.4422 (7)	0.015 (2)
O25	0.4524 (8)	0.1625 (3)	0.1640 (6)	0.0125 (19)
O26	0.5245 (8)	0.1561 (3)	0.3156 (6)	0.0116 (18)
O27	0.4623 (8)	0.1051 (3)	0.2223 (7)	0.0138 (19)
O28	0.0239 (8)	0.5311 (3)	0.8153 (6)	0.0119 (19)
O29	0.0494 (8)	0.4614 (3)	0.3380 (6)	0.0100 (18)
O30	0.0301 (8)	0.5192 (3)	0.2810 (7)	0.0135 (19)
O31	0.2471 (8)	0.0360 (3)	0.0549 (7)	0.0116 (18)
O32	0.4167 (8)	0.0220 (3)	0.1802 (7)	0.0128 (19)
O33	0.3297 (8)	0.5180 (3)	0.5604 (7)	0.015 (2)
O34	0.3586 (9)	0.5446 (3)	0.1375 (7)	0.017 (2)
O35	0.2370 (9)	0.5143 (4)	0.0050 (8)	0.026 (3)
O36	0.3710 (9)	0.4821 (3)	0.1274 (8)	0.023 (2)
I1	0.23839 (7)	0.50353 (2)	0.75382 (6)	0.01089 (16)
I2	0.02321 (7)	0.56825 (2)	0.49450 (6)	0.00922 (16)
I3	0.51853 (7)	0.05568 (2)	0.49871 (6)	0.01051 (16)
I4	0.02890 (7)	0.31583 (2)	0.49893 (6)	0.00977 (16)
I5	0.24870 (7)	0.12856 (2)	0.25332 (6)	0.01133 (17)
I6	0.48805 (7)	0.30683 (2)	0.00222 (6)	0.01024 (16)
I7	0.74654 (7)	0.37823 (2)	0.25684 (6)	0.01038 (16)
I8	0.24565 (7)	0.24507 (2)	0.24870 (6)	0.01053 (16)
I9	0.23835 (7)	0.74699 (2)	0.25736 (6)	0.01027 (16)
I10	0.01605 (7)	0.82021 (2)	0.49369 (6)	0.01008 (16)
I11	0.52303 (7)	0.30574 (2)	0.49127 (6)	0.00945 (16)
I12	0.00636 (7)	0.06869 (2)	0.49831 (6)	0.01186 (17)
I13	0.26024 (7)	0.37760 (2)	0.24425 (6)	0.01006 (16)
I14	0.26343 (7)	0.62687 (2)	0.24731 (6)	0.01021 (16)
I15	0.47596 (7)	0.05766 (2)	0.00446 (6)	0.00997 (16)
I16	0.24648 (7)	0.49627 (2)	0.25586 (6)	0.01117 (16)

Atomic displacement parameters (Ų)

	U11	U22	U33	U12	U13	U23
Ag1	0.0155 (5)	0.0147 (5)	0.0103 (5)	−0.0023 (4)	0.0063 (4)	−0.0016 (4)
Ag2	0.0214 (5)	0.0133 (5)	0.0163 (5)	0.0022 (4)	0.0104 (4)	−0.0014 (4)
Ag3	0.0117 (5)	0.0200 (5)	0.0125 (5)	−0.0045 (4)	0.0060 (4)	−0.0011 (4)
Ag4	0.0085 (4)	0.0131 (5)	0.0127 (5)	0.0004 (3)	0.0041 (4)	−0.0010 (4)
Ag5	0.0108 (4)	0.0120 (5)	0.0137 (5)	0.0006 (3)	0.0060 (4)	−0.0007 (4)
Ag6	0.0137 (5)	0.0197 (5)	0.0153 (5)	−0.0005 (4)	0.0092 (4)	−0.0015 (4)
Ag7	0.0198 (5)	0.0203 (5)	0.0127 (5)	0.0083 (4)	0.0073 (4)	−0.0013 (4)
Ag8	0.0201 (5)	0.0124 (5)	0.0097 (5)	0.0007 (4)	0.0066 (4)	0.0005 (4)
Ag9	0.0224 (5)	0.0119 (5)	0.0095 (5)	0.0014 (4)	0.0060 (4)	−0.0018 (4)
Ag10	0.0169 (5)	0.0145 (5)	0.0146 (5)	0.0022 (4)	0.0080 (4)	−0.0036 (4)
Ag11	0.0204 (5)	0.0155 (5)	0.0095 (5)	0.0008 (4)	0.0073 (4)	0.0005 (4)
Ag12	0.0237 (6)	0.0148 (5)	0.0121 (5)	0.0031 (4)	0.0074 (4)	−0.0013 (4)
Ag13	0.0123 (5)	0.0210 (5)	0.0145 (5)	−0.0065 (4)	0.0076 (4)	−0.0026 (4)
Ag14	0.0134 (5)	0.0141 (5)	0.0109 (5)	−0.0013 (4)	0.0070 (4)	0.0019 (4)
Ag15	0.0089 (4)	0.0159 (5)	0.0133 (5)	0.0027 (4)	0.0053 (4)	0.0013 (4)
Ag16	0.0093 (4)	0.0139 (5)	0.0136 (5)	−0.0010 (4)	0.0050 (4)	0.0005 (4)
Ag17	0.0133 (5)	0.0155 (5)	0.0114 (5)	0.0023 (4)	0.0063 (4)	−0.0016 (4)
Ag18	0.0139 (5)	0.0148 (5)	0.0088 (5)	−0.0009 (4)	0.0048 (4)	−0.0010 (4)
Ag19	0.0187 (5)	0.0147 (5)	0.0185 (5)	0.0036 (4)	0.0085 (4)	0.0055 (4)
Ag20	0.0173 (5)	0.0161 (5)	0.0111 (5)	0.0035 (4)	0.0063 (4)	−0.0024 (4)
Ag21	0.0158 (5)	0.0117 (5)	0.0106 (5)	0.0003 (4)	0.0066 (4)	0.0006 (4)
Ag22	0.0182 (5)	0.0115 (5)	0.0082 (5)	0.0014 (4)	0.0038 (4)	−0.0006 (4)
Ag23	0.0084 (4)	0.0128 (5)	0.0138 (5)	−0.0004 (3)	0.0049 (4)	−0.0011 (4)
Ag24	0.0138 (5)	0.0197 (5)	0.0133 (5)	−0.0020 (4)	0.0077 (4)	0.0005 (4)
Ag25	0.0104 (5)	0.0155 (5)	0.0107 (5)	0.0027 (4)	0.0039 (4)	0.0023 (4)
Ag26	0.0112 (5)	0.0116 (4)	0.0144 (5)	0.0005 (3)	0.0060 (4)	−0.0025 (4)
Ag27	0.0142 (5)	0.0138 (5)	0.0125 (5)	−0.0017 (4)	0.0069 (4)	0.0019 (4)
Ag28	0.0154 (5)	0.0153 (5)	0.0095 (5)	−0.0011 (4)	0.0053 (4)	0.0002 (4)
Ag29	0.0236 (6)	0.0136 (5)	0.0159 (5)	0.0048 (4)	0.0105 (5)	0.0039 (4)
Ag30	0.0190 (5)	0.0178 (5)	0.0148 (5)	0.0010 (4)	0.0106 (4)	−0.0034 (4)
Ag31	0.0131 (5)	0.0140 (5)	0.0091 (5)	−0.0003 (4)	0.0040 (4)	0.0004 (4)
Ag32	0.0208 (5)	0.0124 (5)	0.0113 (5)	−0.0035 (4)	0.0071 (4)	−0.0011 (4)
Ag33	0.0106 (5)	0.0134 (5)	0.0147 (5)	0.0006 (4)	0.0069 (4)	−0.0015 (4)
Ag34	0.0085 (4)	0.0161 (5)	0.0132 (5)	−0.0008 (4)	0.0043 (4)	−0.0014 (4)
Ag35	0.0087 (4)	0.0123 (5)	0.0142 (5)	−0.0008 (3)	0.0047 (4)	0.0003 (4)
Ag36	0.0128 (5)	0.0136 (5)	0.0185 (5)	0.0020 (4)	0.0081 (4)	0.0008 (4)
Ag37	0.0155 (5)	0.0150 (5)	0.0119 (5)	−0.0021 (4)	0.0066 (4)	0.0020 (4)
Ag38	0.0213 (5)	0.0147 (5)	0.0094 (5)	−0.0013 (4)	0.0080 (4)	−0.0011 (4)
Ag39	0.0175 (5)	0.0120 (5)	0.0097 (5)	0.0002 (4)	0.0046 (4)	−0.0025 (4)
Ag40	0.0119 (5)	0.0134 (5)	0.0113 (5)	0.0021 (4)	0.0052 (4)	−0.0010 (4)
C1	0.006 (2)	0.006 (2)	0.006 (2)	0.0001 (10)	0.0032 (14)	−0.0001 (10)
C2	0.013 (3)	0.013 (3)	0.013 (3)	0.0002 (10)	0.0069 (16)	−0.0003 (10)
C3	0.010 (3)	0.010 (3)	0.010 (3)	−0.0003 (10)	0.0053 (15)	0.0001 (10)
C4	0.010 (3)	0.010 (3)	0.010 (3)	0.0001 (10)	0.0054 (15)	0.0003 (10)
C5	0.003 (2)	0.003 (2)	0.003 (2)	0.0000 (10)	0.0019 (14)	0.0001 (10)
C6	0.016 (3)	0.016 (3)	0.015 (3)	0.0000 (10)	0.0085 (17)	−0.0001 (10)
C7	0.009 (2)	0.009 (2)	0.009 (2)	0.0004 (10)	0.0048 (15)	−0.0003 (10)
C8	0.012 (3)	0.012 (3)	0.011 (3)	−0.0003 (10)	0.0063 (16)	0.0000 (10)
C9	0.009 (2)	0.009 (2)	0.009 (2)	0.0002 (10)	0.0048 (15)	−0.0002 (10)
C10	0.008 (2)	0.008 (2)	0.008 (2)	−0.0001 (10)	0.0041 (15)	0.0006 (10)
C11	0.010 (3)	0.010 (3)	0.010 (3)	−0.0002 (10)	0.0054 (15)	−0.0001 (10)
C12	0.014 (3)	0.014 (3)	0.014 (3)	0.0001 (10)	0.0079 (16)	−0.0003 (10)
O1	0.013 (4)	0.007 (4)	0.009 (4)	0.001 (3)	0.004 (4)	0.000 (3)
O2	0.010 (2)	0.010 (2)	0.010 (2)	0.0000 (10)	0.0052 (13)	−0.0005 (10)
O3	0.016 (5)	0.012 (4)	0.006 (4)	0.000 (4)	0.006 (4)	0.000 (3)
O4	0.021 (5)	0.015 (5)	0.013 (5)	−0.001 (4)	0.009 (4)	−0.004 (4)
O5	0.012 (5)	0.018 (5)	0.016 (5)	0.002 (4)	0.002 (4)	0.006 (4)
O6	0.010 (5)	0.016 (5)	0.027 (6)	0.001 (4)	0.011 (4)	−0.001 (4)
O7	0.012 (5)	0.018 (5)	0.008 (5)	−0.003 (4)	0.004 (4)	−0.003 (4)
O8	0.013 (5)	0.014 (5)	0.008 (5)	−0.002 (4)	0.004 (4)	−0.002 (4)
O9	0.025 (6)	0.010 (5)	0.030 (6)	0.003 (4)	0.018 (5)	0.003 (4)
O10	0.012 (2)	0.012 (2)	0.011 (2)	−0.0003 (10)	0.0060 (13)	0.0002 (10)
O11	0.012 (4)	0.009 (4)	0.010 (5)	0.000 (3)	0.004 (4)	−0.001 (3)
O12	0.018 (5)	0.006 (4)	0.021 (5)	0.001 (4)	0.015 (4)	0.002 (4)
O13	0.013 (5)	0.029 (6)	0.014 (5)	0.000 (4)	0.002 (4)	−0.005 (4)
O14	0.020 (5)	0.024 (6)	0.014 (5)	0.004 (4)	0.009 (5)	0.006 (4)
O15	0.023 (3)	0.024 (3)	0.024 (3)	0.0003 (10)	0.0129 (15)	0.0003 (10)
O16	0.012 (5)	0.023 (5)	0.009 (5)	0.001 (4)	0.006 (4)	−0.004 (4)
O17	0.010 (5)	0.016 (5)	0.019 (5)	0.001 (4)	0.005 (4)	0.001 (4)
O18	0.017 (5)	0.016 (5)	0.016 (5)	0.003 (4)	0.014 (4)	0.001 (4)
O19	0.016 (5)	0.019 (5)	0.009 (5)	0.001 (4)	0.004 (4)	−0.004 (4)
O20	0.019 (5)	0.014 (5)	0.009 (5)	0.001 (4)	0.010 (4)	0.001 (4)
O21	0.007 (4)	0.012 (4)	0.016 (5)	−0.005 (3)	0.004 (4)	−0.007 (4)
O22	0.016 (5)	0.014 (5)	0.007 (4)	0.001 (4)	0.007 (4)	0.001 (4)
O23	0.011 (4)	0.005 (4)	0.011 (5)	0.003 (3)	0.000 (4)	−0.001 (3)
O24	0.013 (5)	0.015 (5)	0.017 (5)	0.005 (4)	0.007 (4)	0.005 (4)
O25	0.009 (4)	0.014 (5)	0.006 (4)	−0.004 (3)	−0.001 (4)	0.002 (4)
O26	0.013 (5)	0.018 (5)	0.005 (4)	0.003 (4)	0.006 (4)	0.001 (4)
O27	0.012 (5)	0.011 (4)	0.014 (5)	0.001 (4)	0.004 (4)	−0.003 (4)
O28	0.013 (5)	0.011 (4)	0.006 (4)	−0.003 (3)	0.001 (4)	−0.006 (3)
O29	0.008 (4)	0.010 (4)	0.008 (4)	−0.001 (3)	0.002 (4)	0.002 (3)
O30	0.013 (5)	0.009 (4)	0.019 (5)	−0.002 (3)	0.009 (4)	0.000 (4)
O31	0.011 (4)	0.013 (4)	0.010 (5)	0.002 (3)	0.005 (4)	0.003 (4)
O32	0.009 (4)	0.012 (4)	0.011 (5)	−0.003 (3)	0.001 (4)	0.005 (4)
O33	0.018 (5)	0.012 (5)	0.010 (5)	−0.003 (4)	0.005 (4)	0.006 (4)
O34	0.029 (6)	0.013 (5)	0.008 (5)	−0.004 (4)	0.009 (4)	−0.001 (4)
O35	0.010 (5)	0.048 (7)	0.016 (5)	−0.011 (5)	0.004 (4)	−0.002 (5)
O36	0.022 (6)	0.017 (5)	0.031 (6)	−0.002 (4)	0.015 (5)	−0.001 (5)
I1	0.0093 (4)	0.0134 (4)	0.0081 (4)	−0.0014 (3)	0.0035 (3)	−0.0009 (3)
I2	0.0090 (4)	0.0099 (4)	0.0070 (4)	−0.0008 (3)	0.0032 (3)	0.0001 (3)
I3	0.0110 (4)	0.0106 (4)	0.0087 (4)	0.0012 (3)	0.0045 (3)	0.0018 (3)
I4	0.0097 (4)	0.0107 (4)	0.0075 (4)	−0.0008 (3)	0.0037 (3)	0.0001 (3)
I5	0.0087 (4)	0.0119 (4)	0.0092 (4)	−0.0005 (3)	0.0022 (3)	−0.0018 (3)
I6	0.0119 (4)	0.0114 (4)	0.0086 (4)	−0.0006 (3)	0.0063 (3)	−0.0012 (3)
I7	0.0087 (4)	0.0119 (4)	0.0082 (4)	−0.0006 (3)	0.0029 (3)	0.0009 (3)
I8	0.0087 (4)	0.0124 (4)	0.0079 (4)	0.0002 (3)	0.0028 (3)	−0.0004 (3)
I9	0.0094 (4)	0.0129 (4)	0.0071 (4)	0.0016 (3)	0.0035 (3)	0.0010 (3)
I10	0.0107 (4)	0.0102 (4)	0.0080 (4)	0.0001 (3)	0.0041 (3)	−0.0010 (3)
I11	0.0103 (4)	0.0097 (4)	0.0069 (4)	0.0007 (3)	0.0037 (3)	0.0003 (3)
I12	0.0153 (4)	0.0096 (4)	0.0087 (4)	−0.0010 (3)	0.0052 (3)	−0.0010 (3)
I13	0.0080 (4)	0.0126 (4)	0.0083 (4)	0.0012 (3)	0.0035 (3)	0.0019 (3)
I14	0.0087 (4)	0.0124 (4)	0.0085 (4)	0.0014 (3)	0.0040 (3)	0.0025 (3)
I15	0.0094 (4)	0.0109 (4)	0.0082 (4)	−0.0002 (3)	0.0038 (3)	0.0000 (3)
I16	0.0087 (4)	0.0136 (4)	0.0081 (4)	0.0011 (3)	0.0025 (3)	−0.0001 (3)

Geometric parameters (Å, º)

Ag1—O4	2.416 (10)	Ag30—I4	2.7587 (14)
Ag1—O30i	2.462 (10)	Ag30—O12	2.852 (10)
Ag1—O2i	2.621 (9)	Ag30—I10ix	2.9063 (14)
Ag1—I2i	2.8525 (13)	Ag30—Ag10ix	3.0022 (15)
Ag1—I5	2.9644 (13)	Ag30—Ag31i	3.3862 (15)
Ag1—I1ii	3.0865 (13)	Ag31—O20	2.415 (9)
Ag1—Ag5	3.2978 (15)	Ag31—O12x	2.536 (10)
Ag1—Ag2	3.3930 (16)	Ag31—O22x	2.538 (10)
Ag2—O35iii	2.427 (13)	Ag31—I4x	2.8487 (13)
Ag2—O5	2.432 (11)	Ag31—I7vi	3.0043 (13)
Ag2—O4	2.561 (10)	Ag31—I9	3.1169 (13)
Ag2—I1ii	2.8469 (14)	Ag31—Ag35viii	3.0904 (14)
Ag2—I3	3.0712 (14)	Ag31—Ag30x	3.3862 (15)
Ag2—Ag36iv	3.0846 (15)	Ag32—O18xi	2.277 (10)
Ag3—O36	2.310 (11)	Ag32—O20iv	2.284 (10)
Ag3—O7	2.398 (10)	Ag32—I9iv	2.8293 (14)
Ag3—I1v	2.7620 (13)	Ag32—I6	3.1036 (14)
Ag3—O32vi	2.777 (9)	Ag32—Ag10iv	3.3724 (16)
Ag3—I3ii	3.1508 (14)	Ag33—O26	2.376 (10)
Ag3—Ag23	3.0984 (15)	Ag33—O16	2.522 (10)
Ag3—Ag38vi	3.2525 (15)	Ag33—O18iv	2.532 (10)
Ag3—Ag4v	3.2774 (15)	Ag33—I8	2.7989 (13)
Ag4—O33	2.395 (11)	Ag33—O15	2.827 (12)
Ag4—O8v	2.430 (10)	Ag33—I6iii	3.2480 (14)
Ag4—O1vi	2.620 (10)	Ag34—O15	2.323 (11)
Ag4—I2	2.8465 (13)	Ag34—O25	2.429 (10)
Ag4—I7v	3.0366 (13)	Ag34—O23ii	2.577 (10)
Ag4—Ag9vii	3.0588 (15)	Ag34—I4ii	2.7982 (13)
Ag4—Ag3v	3.2774 (15)	Ag34—I5	3.4141 (14)
Ag5—O10i	2.372 (9)	Ag34—Ag39	3.0935 (15)
Ag5—O3i	2.495 (10)	Ag35—O29ix	2.330 (9)
Ag5—O2i	2.556 (9)	Ag35—O22ix	2.534 (10)
Ag5—I5	2.7769 (13)	Ag35—O24ix	2.536 (10)
Ag5—I4ii	3.0768 (14)	Ag35—I7v	2.8033 (13)
Ag5—Ag25i	3.1071 (15)	Ag35—O21v	2.811 (10)
Ag5—Ag6	3.2630 (15)	Ag35—I2	3.1788 (14)
Ag6—O13	2.420 (11)	Ag35—Ag15ix	3.0836 (15)
Ag6—O6	2.478 (10)	Ag35—Ag31vii	3.0902 (14)
Ag6—O11	2.572 (10)	Ag36—O21	2.303 (10)
Ag6—I6iii	3.0645 (14)	Ag36—O35xi	2.417 (12)
Ag6—I5	3.0827 (14)	Ag36—O28v	2.626 (10)
Ag6—I8	3.1602 (14)	Ag36—I1v	2.9272 (14)
Ag6—Ag12	3.2479 (16)	Ag36—I3ii	3.0141 (13)
Ag7—O7	2.273 (10)	Ag36—Ag2vi	3.0847 (15)
Ag7—O5ii	2.313 (10)	Ag36—Ag19xi	3.3882 (16)
Ag7—I6	2.7140 (14)	Ag37—O26	2.304 (9)
Ag7—I3ii	3.1669 (15)	Ag37—O19iii	2.383 (10)
Ag7—Ag37ii	3.0480 (16)	Ag37—I3	2.7154 (13)
Ag7—Ag8	3.0725 (15)	Ag37—I6iii	2.9276 (14)
Ag8—O9	2.393 (11)	Ag37—Ag7iii	3.0479 (16)
Ag8—O16	2.408 (10)	Ag37—Ag38	3.1027 (15)
Ag8—O14	2.698 (11)	Ag38—O27	2.364 (10)
Ag8—I6	2.8571 (14)	Ag38—O32	2.377 (10)
Ag8—I7	3.1721 (13)	Ag38—O34iv	2.660 (11)
Ag8—I9iv	3.2491 (14)	Ag38—I3	2.8340 (14)
Ag8—Ag9iv	3.1717 (15)	Ag38—I1ii	3.2245 (14)
Ag8—Ag13	3.2882 (15)	Ag38—I5	3.3447 (14)
Ag9—O17	2.308 (10)	Ag38—Ag3iv	3.2525 (15)
Ag9—O3viii	2.340 (9)	Ag38—Ag39	3.2837 (15)
Ag9—O9vi	2.732 (11)	Ag39—O31	2.312 (9)
Ag9—I7vi	2.7431 (14)	Ag39—O24ii	2.329 (10)
Ag9—Ag4viii	3.0588 (14)	Ag39—O27	2.596 (10)
Ag9—Ag8vi	3.1717 (15)	Ag39—I5	2.8069 (14)
Ag9—Ag27vi	3.3996 (16)	Ag40—O29	2.346 (9)
Ag10—O10	2.274 (10)	Ag40—O31iii	2.376 (10)
Ag10—O17vii	2.391 (10)	Ag40—I2	2.7526 (13)
Ag10—I10	2.7225 (13)	Ag40—I2ix	2.9693 (13)
Ag10—I4ix	3.0668 (14)	Ag40—Ag40ix	2.968 (2)
Ag10—Ag30ix	3.0022 (16)	Ag40—O30	2.932 (10)
Ag10—Ag11x	3.1906 (15)	C1—O1vi	1.251 (15)
Ag10—Ag32vi	3.3724 (16)	C1—O2	1.282 (15)
Ag11—O12	2.377 (9)	C1—O3	1.328 (15)
Ag11—O22	2.384 (9)	C2—O4	1.264 (17)
Ag11—O20i	2.684 (10)	C2—O6	1.305 (17)
Ag11—I10i	2.8234 (13)	C2—O5	1.310 (17)
Ag11—I8	3.2455 (14)	C3—O9	1.272 (16)
Ag11—I13	3.2872 (14)	C3—O7	1.293 (16)
Ag11—Ag12	3.1734 (15)	C3—O8	1.302 (16)
Ag11—Ag10i	3.1905 (15)	C4—O12	1.279 (16)
Ag11—Ag15	3.3624 (15)	C4—O10i	1.283 (16)
Ag12—O23	2.252 (9)	C4—O11	1.307 (16)
Ag12—O13	2.428 (12)	C5—O15	1.267 (16)
Ag12—O12	2.761 (10)	C5—O14	1.295 (16)
Ag12—I8	2.7745 (14)	C5—O13ii	1.312 (15)
Ag13—O15	2.294 (12)	C6—O17iv	1.281 (17)
Ag13—O25	2.363 (9)	C6—O16	1.283 (17)
Ag13—I9iv	2.7529 (13)	C6—O18iv	1.310 (17)
Ag13—O16	2.817 (10)	C7—O20iv	1.267 (16)
Ag13—I11ii	3.1325 (14)	C7—O21	1.297 (15)
Ag13—Ag33	3.0620 (15)	C7—O19	1.311 (16)
Ag13—Ag14iv	3.2462 (15)	C8—O23	1.256 (16)
Ag14—O18	2.313 (10)	C8—O22	1.291 (17)
Ag14—O19xi	2.484 (10)	C8—O24	1.319 (17)
Ag14—O26vi	2.589 (10)	C9—O27	1.272 (16)
Ag14—I14	2.8131 (13)	C9—O26	1.282 (16)
Ag14—I10viii	3.0760 (13)	C9—O25	1.306 (16)
Ag14—Ag19	3.1494 (15)	C10—O30	1.256 (15)
Ag14—Ag13vi	3.2463 (15)	C10—O28ix	1.305 (16)
Ag15—O21xii	2.313 (9)	C10—O29	1.312 (15)
Ag15—O28ix	2.400 (9)	C11—O33ii	1.284 (16)
Ag15—I13	2.7543 (13)	C11—O32	1.284 (16)
Ag15—O22	2.808 (9)	C11—O31	1.297 (16)
Ag15—I12ii	3.1320 (14)	C12—O36	1.279 (18)
Ag15—Ag35ix	3.0836 (15)	C12—O34	1.280 (17)
Ag15—Ag16	3.2907 (15)	C12—O35	1.310 (18)
Ag16—O29	2.397 (9)	O1—C1iv	1.251 (15)
Ag16—O24	2.415 (10)	O1—Ag22iv	2.294 (9)
Ag16—O31iii	2.625 (10)	O1—Ag27ii	2.396 (9)
Ag16—I15iii	2.8193 (13)	O2—Ag5x	2.555 (9)
Ag16—I16	3.1336 (13)	O3—Ag9vii	2.340 (9)
Ag16—Ag22	3.0444 (14)	O3—Ag26vi	2.342 (9)
Ag17—O25	2.336 (10)	O3—Ag5x	2.495 (10)
Ag17—O23ii	2.407 (9)	O4—Ag21i	2.467 (11)
Ag17—I15	2.7388 (13)	O5—Ag7iii	2.312 (10)
Ag17—I11ii	2.9924 (13)	O5—Ag24iii	2.429 (11)
Ag17—Ag27ii	2.9507 (15)	O6—Ag25i	2.338 (10)
Ag18—O34iv	2.409 (10)	O6—Ag29iii	2.362 (11)
Ag18—O32	2.530 (9)	O8—Ag4v	2.430 (10)
Ag18—O27	2.545 (10)	O10—C4x	1.283 (16)
Ag18—I15	2.8498 (13)	O10—Ag5x	2.373 (9)
Ag18—I16iv	3.0485 (13)	O10—Ag26vi	2.503 (10)
Ag18—I14iv	3.0730 (13)	O11—Ag25i	2.314 (9)
Ag18—Ag23iv	3.1508 (14)	O12—Ag31i	2.536 (9)
Ag19—O34	2.300 (11)	O13—C5iii	1.312 (15)
Ag19—O19xi	2.370 (11)	O17—C6vi	1.281 (17)
Ag19—O21xi	2.915 (10)	O17—Ag10viii	2.391 (10)
Ag19—I12x	2.9205 (15)	O18—C6vi	1.310 (17)
Ag19—O35	2.944 (13)	O18—Ag32xi	2.277 (10)
Ag19—I14	3.0637 (15)	O18—Ag33vi	2.532 (10)
Ag19—Ag36xi	3.3883 (16)	O19—Ag19xi	2.370 (11)
Ag20—O28ii	2.282 (10)	O19—Ag37ii	2.383 (10)
Ag20—O35iii	2.376 (10)	O19—Ag14xi	2.484 (10)
Ag20—I12	2.7264 (13)	O20—C7vi	1.267 (16)
Ag20—I12xiii	2.9991 (14)	O20—Ag32vi	2.284 (10)
Ag20—Ag20xiii	3.021 (2)	O21—Ag15xiv	2.313 (9)
Ag20—Ag21i	3.0523 (15)	O22—Ag35ix	2.535 (10)
Ag21—O30	2.440 (10)	O22—Ag31i	2.538 (10)
Ag21—O2	2.462 (9)	O23—Ag17iii	2.407 (9)
Ag21—O4x	2.467 (11)	O23—Ag34iii	2.577 (10)
Ag21—I12x	2.9562 (13)	O24—Ag39iii	2.329 (10)
Ag21—I16	3.1225 (13)	O24—Ag35ix	2.536 (10)
Ag21—I14	3.1435 (13)	O26—Ag14iv	2.589 (10)
Ag21—Ag20x	3.0524 (15)	O28—C10ix	1.305 (16)
Ag21—Ag25	3.0592 (14)	O28—Ag20iii	2.282 (10)
Ag21—Ag22	3.1148 (14)	O28—Ag15ix	2.400 (9)
Ag22—O1vi	2.294 (9)	O29—Ag35ix	2.330 (9)
Ag22—O33	2.311 (10)	O30—Ag1x	2.462 (10)
Ag22—O30	2.661 (10)	O31—Ag40ii	2.376 (10)
Ag22—I16	2.7609 (14)	O32—Ag23iv	2.520 (10)
Ag22—Ag40	3.3647 (16)	O33—C11iii	1.284 (16)
Ag23—O8	2.321 (10)	O33—Ag23v	2.556 (10)
Ag23—O32vi	2.520 (10)	O34—Ag18vi	2.410 (10)
Ag23—O33v	2.556 (10)	O35—Ag20ii	2.376 (10)
Ag23—I16	2.8004 (13)	O35—Ag36xi	2.417 (12)
Ag23—O36	2.835 (12)	O35—Ag2ii	2.427 (13)
Ag23—I15iii	3.1727 (14)	I1—Ag3v	2.7620 (13)
Ag23—Ag18vi	3.1507 (14)	I1—Ag2iii	2.8470 (14)
Ag23—Ag24	3.2879 (15)	I1—Ag36v	2.9272 (14)
Ag24—O36	2.299 (11)	I1—Ag1iii	3.0867 (13)
Ag24—O5ii	2.429 (11)	I1—Ag38iii	3.2246 (14)
Ag24—O7	2.617 (10)	I2—Ag1x	2.8525 (13)
Ag24—I13	2.8377 (14)	I2—Ag40ix	2.9692 (13)
Ag24—Ag29	3.0848 (15)	I3—Ag36iii	3.0141 (13)
Ag24—I12ii	3.2144 (14)	I3—Ag3iii	3.1509 (14)
Ag25—O11x	2.314 (9)	I3—Ag7iii	3.1669 (15)
Ag25—O6x	2.338 (10)	I4—Ag34iii	2.7982 (13)
Ag25—O2	2.569 (9)	I4—Ag31i	2.8487 (13)
Ag25—I14	2.7879 (13)	I4—Ag10ix	3.0670 (14)
Ag25—I10viii	3.2942 (13)	I4—Ag5iii	3.0769 (14)
Ag25—Ag5x	3.1070 (15)	I6—Ag37ii	2.9276 (14)
Ag26—O3iv	2.342 (9)	I6—Ag6ii	3.0645 (14)
Ag26—O10iv	2.503 (10)	I6—Ag33ii	3.2478 (14)
Ag26—O17xi	2.683 (11)	I7—Ag9iv	2.7430 (14)
Ag26—I11ii	2.9055 (13)	I7—Ag35v	2.8034 (13)
Ag26—I9iv	2.9222 (13)	I7—Ag31iv	3.0042 (13)
Ag26—Ag32	2.9901 (15)	I7—Ag4v	3.0367 (13)
Ag27—O8	2.330 (10)	I9—Ag13vi	2.7528 (13)
Ag27—O1iii	2.396 (9)	I9—Ag32vi	2.8294 (14)
Ag27—I11	2.7347 (13)	I9—Ag26vi	2.9223 (13)
Ag27—O9	2.941 (11)	I9—Ag8vi	3.2491 (14)
Ag27—I15iii	2.9739 (13)	I10—Ag11x	2.8234 (13)
Ag27—Ag17iii	2.9508 (15)	I10—Ag30ix	2.9062 (14)
Ag27—Ag9iv	3.3997 (16)	I10—Ag29x	3.0691 (15)
Ag28—O14	2.383 (11)	I10—Ag14vii	3.0759 (13)
Ag28—O9	2.488 (11)	I11—Ag26iii	2.9055 (13)
Ag28—O16	2.584 (10)	I11—Ag17iii	2.9925 (13)
Ag28—I11	2.8574 (13)	I11—Ag13iii	3.1326 (14)
Ag28—I8	2.9725 (13)	I12—Ag19i	2.9205 (15)
Ag28—I13	3.1476 (13)	I12—Ag21i	2.9562 (13)
Ag28—Ag33	3.1352 (15)	I12—Ag20xiii	2.9990 (14)
Ag29—O14	2.292 (11)	I12—Ag15iii	3.1320 (14)
Ag29—O6ii	2.362 (11)	I12—Ag24iii	3.2144 (14)
Ag29—I13	2.8812 (14)	I14—Ag18vi	3.0729 (13)
Ag29—O5ii	2.989 (11)	I15—Ag16ii	2.8192 (13)
Ag29—I10i	3.0690 (15)	I15—Ag27ii	2.9741 (13)
Ag29—O13ii	3.001 (12)	I15—Ag23ii	3.1726 (14)
Ag30—O13	2.352 (11)	I16—Ag18vi	3.0486 (13)
Ag30—O11	2.366 (10)
O4—Ag1—O30i	74.6 (3)	O20—Ag31—I7vi	81.7 (2)
O4—Ag1—I2i	157.3 (3)	O12x—Ag31—I7vi	158.8 (2)
O30i—Ag1—I2i	99.6 (2)	O22x—Ag31—I7vi	106.0 (2)
O4—Ag1—I5	85.8 (2)	I4x—Ag31—I7vi	99.83 (4)
O30i—Ag1—I5	160.3 (2)	O20—Ag31—Ag35viii	82.8 (2)
I2i—Ag1—I5	99.20 (4)	O12x—Ag31—Ag35viii	127.2 (2)
O4—Ag1—I1ii	99.3 (2)	O22x—Ag31—Ag35viii	52.4 (2)
O30i—Ag1—I1ii	80.8 (2)	I4x—Ag31—Ag35viii	86.17 (4)
I2i—Ag1—I1ii	101.31 (4)	I7vi—Ag31—Ag35viii	54.75 (3)
I5—Ag1—I1ii	101.33 (4)	O20—Ag31—I9	92.4 (2)
O4—Ag1—Ag5	83.8 (2)	O12x—Ag31—I9	76.0 (2)
O30i—Ag1—Ag5	125.1 (2)	O22x—Ag31—I9	151.3 (2)
I2i—Ag1—Ag5	81.94 (4)	I4x—Ag31—I9	101.74 (4)
I5—Ag1—Ag5	52.32 (3)	I7vi—Ag31—I9	99.32 (4)
I1ii—Ag1—Ag5	153.39 (4)	Ag35viii—Ag31—I9	154.01 (4)
O35iii—Ag2—O5	104.0 (4)	O18xi—Ag32—O20iv	110.0 (3)
O35iii—Ag2—O4	103.6 (3)	O18xi—Ag32—I9iv	144.7 (3)
O5—Ag2—O4	52.9 (3)	O20iv—Ag32—I9iv	103.2 (2)
O35iii—Ag2—I1ii	108.6 (3)	O18xi—Ag32—Ag26	88.4 (2)
O5—Ag2—I1ii	143.3 (2)	O20iv—Ag32—Ag26	130.8 (3)
O4—Ag2—I1ii	102.4 (2)	I9iv—Ag32—Ag26	60.21 (3)
O35iii—Ag2—I3	119.6 (3)	O18xi—Ag32—I6	82.7 (2)
O5—Ag2—I3	80.9 (2)	O20iv—Ag32—I6	113.9 (2)
O4—Ag2—I3	123.4 (2)	I9iv—Ag32—I6	94.86 (4)
I1ii—Ag2—I3	96.94 (4)	Ag26—Ag32—I6	113.49 (4)
O35iii—Ag2—Ag36iv	50.3 (3)	O18xi—Ag32—Ag10iv	66.9 (2)
O5—Ag2—Ag36iv	153.5 (3)	O20iv—Ag32—Ag10iv	77.7 (2)
O4—Ag2—Ag36iv	119.9 (2)	I9iv—Ag32—Ag10iv	110.28 (4)
I1ii—Ag2—Ag36iv	58.98 (3)	Ag26—Ag32—Ag10iv	68.25 (3)
I3—Ag2—Ag36iv	115.74 (4)	I6—Ag32—Ag10iv	149.57 (4)
O36—Ag3—O7	78.9 (4)	O26—Ag33—O16	116.2 (3)
O36—Ag3—I1v	142.7 (3)	O26—Ag33—O18iv	78.6 (3)
O7—Ag3—I1v	138.2 (2)	O16—Ag33—O18iv	51.8 (3)
O36—Ag3—Ag23	61.2 (3)	O26—Ag33—I8	130.4 (2)
O7—Ag3—Ag23	74.3 (2)	O16—Ag33—I8	112.2 (2)
I1v—Ag3—Ag23	122.58 (4)	O18iv—Ag33—I8	144.6 (2)
O36—Ag3—I3ii	92.6 (3)	O26—Ag33—Ag13	74.8 (2)
O7—Ag3—I3ii	83.5 (2)	O16—Ag33—Ag13	59.7 (2)
I1v—Ag3—I3ii	89.18 (4)	O18iv—Ag33—Ag13	78.4 (2)
Ag23—Ag3—I3ii	148.13 (4)	I8—Ag33—Ag13	124.03 (5)
O36—Ag3—Ag38vi	79.2 (3)	O26—Ag33—Ag28	169.0 (2)
O7—Ag3—Ag38vi	157.2 (2)	O16—Ag33—Ag28	53.0 (2)
I1v—Ag3—Ag38vi	64.24 (3)	O18iv—Ag33—Ag28	93.6 (2)
Ag23—Ag3—Ag38vi	89.60 (4)	I8—Ag33—Ag28	59.80 (3)
I3ii—Ag3—Ag38vi	103.73 (4)	Ag13—Ag33—Ag28	96.18 (4)
O36—Ag3—Ag4v	131.1 (3)	O26—Ag33—I6iii	81.0 (2)
O7—Ag3—Ag4v	78.0 (2)	O16—Ag33—I6iii	115.6 (2)
I1v—Ag3—Ag4v	73.65 (4)	O18iv—Ag33—I6iii	76.1 (2)
Ag23—Ag3—Ag4v	71.24 (3)	I8—Ag33—I6iii	87.98 (4)
I3ii—Ag3—Ag4v	126.53 (4)	Ag13—Ag33—I6iii	147.73 (4)
Ag38vi—Ag3—Ag4v	112.42 (4)	Ag28—Ag33—I6iii	104.82 (4)
O33—Ag4—O8v	76.7 (3)	O26—Ag33—Ag34	78.9 (2)
O33—Ag4—I2	108.5 (2)	O16—Ag33—Ag34	120.0 (2)
O8v—Ag4—I2	163.8 (2)	O18iv—Ag33—Ag34	146.5 (2)
O33—Ag4—I7v	153.1 (2)	I8—Ag33—Ag34	67.94 (3)
O8v—Ag4—I7v	91.4 (2)	Ag13—Ag33—Ag34	71.85 (4)
I2—Ag4—I7v	89.55 (4)	Ag28—Ag33—Ag34	104.45 (4)
O33—Ag4—Ag9vii	142.6 (2)	I6iii—Ag33—Ag34	124.16 (4)
O8v—Ag4—Ag9vii	77.8 (2)	O15—Ag34—O25	72.6 (4)
I2—Ag4—Ag9vii	89.91 (4)	O15—Ag34—O23ii	93.3 (4)
I7v—Ag4—Ag9vii	53.49 (3)	O25—Ag34—O23ii	79.6 (3)
O33—Ag4—Ag3v	77.3 (2)	O15—Ag34—I4ii	125.4 (3)
O8v—Ag4—Ag3v	64.8 (2)	O25—Ag34—I4ii	160.2 (2)
I2—Ag4—Ag3v	130.88 (4)	O23ii—Ag34—I4ii	90.5 (2)
I7v—Ag4—Ag3v	75.85 (3)	O15—Ag34—Ag39	146.7 (3)
Ag9vii—Ag4—Ag3v	115.22 (4)	O25—Ag34—Ag39	74.4 (2)
O10i—Ag5—O3i	79.0 (3)	O23ii—Ag34—Ag39	76.1 (2)
O10i—Ag5—O2i	112.3 (3)	I4ii—Ag34—Ag39	86.64 (4)
O3i—Ag5—O2i	52.0 (3)	O15—Ag34—Ag33	56.4 (3)
O10i—Ag5—I5	134.3 (2)	O25—Ag34—Ag33	62.3 (2)
O3i—Ag5—I5	146.0 (2)	O23ii—Ag34—Ag33	136.0 (2)
O2i—Ag5—I5	106.9 (2)	I4ii—Ag34—Ag33	132.24 (4)
O10i—Ag5—I4ii	84.8 (2)	Ag39—Ag34—Ag33	110.85 (4)
O3i—Ag5—I4ii	83.9 (2)	O29ix—Ag35—O22ix	108.9 (3)
O2i—Ag5—I4ii	124.8 (2)	O29ix—Ag35—O24ix	75.8 (3)
I5—Ag5—I4ii	91.75 (4)	O22ix—Ag35—O24ix	51.8 (3)
O10i—Ag5—Ag25i	76.6 (2)	O29ix—Ag35—I7v	136.3 (2)
O3i—Ag5—Ag25i	78.4 (2)	O22ix—Ag35—I7v	112.2 (2)
O2i—Ag5—Ag25i	52.9 (2)	O24ix—Ag35—I7v	143.6 (2)
I5—Ag5—Ag25i	111.60 (4)	O29ix—Ag35—Ag15ix	68.4 (2)
I4ii—Ag5—Ag25i	156.42 (4)	O22ix—Ag35—Ag15ix	59.0 (2)
O10i—Ag5—Ag6	82.1 (2)	O24ix—Ag35—Ag15ix	79.8 (2)
O3i—Ag5—Ag6	147.4 (2)	I7v—Ag35—Ag15ix	123.08 (4)
O2i—Ag5—Ag6	113.8 (2)	O29ix—Ag35—Ag31vii	161.4 (2)
I5—Ag5—Ag6	60.75 (3)	O22ix—Ag35—Ag31vii	52.5 (2)
I4ii—Ag5—Ag6	120.56 (4)	O24ix—Ag35—Ag31vii	90.5 (2)
Ag25i—Ag5—Ag6	71.49 (3)	I7v—Ag35—Ag31vii	61.06 (3)
O10i—Ag5—Ag1	162.4 (2)	Ag15ix—Ag35—Ag31vii	97.01 (4)
O3i—Ag5—Ag1	92.1 (2)	O29ix—Ag35—I2	81.8 (2)
O2i—Ag5—Ag1	51.3 (2)	O22ix—Ag35—I2	123.4 (2)
I5—Ag5—Ag1	57.66 (3)	O24ix—Ag35—I2	80.4 (2)
I4ii—Ag5—Ag1	109.61 (4)	I7v—Ag35—I2	87.50 (4)
Ag25i—Ag5—Ag1	86.73 (4)	Ag15ix—Ag35—I2	147.46 (4)
Ag6—Ag5—Ag1	98.25 (4)	Ag31vii—Ag35—I2	108.73 (4)
O13—Ag6—O6	93.2 (4)	O21—Ag36—O35xi	108.3 (4)
O13—Ag6—O11	71.7 (3)	O21—Ag36—I1v	134.1 (3)
O6—Ag6—O11	72.0 (3)	O35xi—Ag36—I1v	106.4 (3)
O13—Ag6—I6iii	84.1 (3)	O21—Ag36—I3ii	121.0 (2)
O6—Ag6—I6iii	119.9 (2)	O35xi—Ag36—I3ii	88.3 (3)
O11—Ag6—I6iii	154.0 (2)	I1v—Ag36—I3ii	88.88 (4)
O13—Ag6—I5	174.2 (3)	O21—Ag36—Ag2vi	151.9 (2)
O6—Ag6—I5	87.1 (2)	O35xi—Ag36—Ag2vi	50.6 (3)
O11—Ag6—I5	113.8 (2)	I1v—Ag36—Ag2vi	56.46 (3)
I6iii—Ag6—I5	90.70 (4)	I3ii—Ag36—Ag2vi	80.62 (4)
O13—Ag6—I8	99.3 (3)	O26—Ag37—O19iii	82.2 (3)
O6—Ag6—I8	153.1 (3)	O26—Ag37—I3	142.3 (2)
O11—Ag6—I8	89.4 (2)	O19iii—Ag37—I3	112.9 (2)
I6iii—Ag6—I8	85.16 (3)	O26—Ag37—I6iii	89.6 (2)
I5—Ag6—I8	82.76 (3)	O19iii—Ag37—I6iii	97.7 (3)
O13—Ag6—Ag12	48.0 (3)	I3—Ag37—I6iii	120.18 (5)
O6—Ag6—Ag12	135.3 (2)	O26—Ag37—Ag7iii	134.5 (2)
O11—Ag6—Ag12	74.4 (2)	O19iii—Ag37—Ag7iii	124.4 (3)
I6iii—Ag6—Ag12	82.49 (4)	I3—Ag37—Ag7iii	66.37 (4)
I5—Ag6—Ag12	133.87 (4)	I6iii—Ag37—Ag7iii	53.98 (3)
I8—Ag6—Ag12	51.29 (3)	O26—Ag37—Ag38	84.6 (2)
O13—Ag6—Ag5	133.8 (3)	O19iii—Ag37—Ag38	121.6 (3)
O6—Ag6—Ag5	76.9 (3)	I3—Ag37—Ag38	57.84 (3)
O11—Ag6—Ag5	62.4 (2)	I6iii—Ag37—Ag38	138.84 (5)
I6iii—Ag6—Ag5	139.87 (4)	Ag7iii—Ag37—Ag38	104.70 (4)
I5—Ag6—Ag5	51.81 (3)	O27—Ag38—O32	79.0 (3)
I8—Ag6—Ag5	77.20 (3)	O27—Ag38—I3	126.8 (2)
Ag12—Ag6—Ag5	111.78 (4)	O32—Ag38—I3	141.8 (2)
O7—Ag7—O5ii	81.5 (4)	O27—Ag38—Ag37	73.7 (2)
O7—Ag7—I6	141.4 (3)	O32—Ag38—Ag37	146.3 (2)
O5ii—Ag7—I6	133.6 (3)	I3—Ag38—Ag37	54.21 (3)
O7—Ag7—Ag37ii	128.2 (3)	O27—Ag38—I1ii	136.8 (2)
O5ii—Ag7—Ag37ii	112.7 (3)	O32—Ag38—I1ii	75.7 (2)
I6—Ag7—Ag37ii	60.75 (3)	I3—Ag38—I1ii	93.83 (4)
O7—Ag7—Ag8	83.1 (3)	Ag37—Ag38—I1ii	138.02 (4)
O5ii—Ag7—Ag8	145.5 (3)	O27—Ag38—Ag3iv	132.8 (2)
I6—Ag7—Ag8	58.78 (3)	O32—Ag38—Ag3iv	56.6 (2)
Ag37ii—Ag7—Ag8	101.07 (4)	I3—Ag38—Ag3iv	88.16 (4)
O7—Ag7—I3ii	85.2 (3)	Ag37—Ag38—Ag3iv	137.71 (5)
O5ii—Ag7—I3ii	80.6 (3)	I1ii—Ag38—Ag3iv	50.48 (3)
I6—Ag7—I3ii	112.37 (5)	O27—Ag38—Ag39	51.6 (2)
Ag37ii—Ag7—I3ii	51.77 (3)	O32—Ag38—Ag39	70.3 (2)
Ag8—Ag7—I3ii	128.50 (5)	I3—Ag38—Ag39	146.88 (5)
O7—Ag7—Ag29	80.2 (2)	Ag37—Ag38—Ag39	105.78 (4)
O5ii—Ag7—Ag29	60.2 (3)	I1ii—Ag38—Ag39	86.75 (4)
I6—Ag7—Ag29	102.20 (4)	Ag3iv—Ag38—Ag39	116.48 (4)
Ag37ii—Ag7—Ag29	151.00 (5)	O31—Ag39—O24ii	82.0 (3)
Ag8—Ag7—Ag29	86.82 (4)	O31—Ag39—O27	99.3 (3)
I3ii—Ag7—Ag29	139.69 (4)	O24ii—Ag39—O27	122.3 (3)
O9—Ag8—O16	79.4 (3)	O31—Ag39—I5	132.5 (2)
O9—Ag8—I6	127.2 (3)	O24ii—Ag39—I5	138.8 (3)
O16—Ag8—I6	138.3 (2)	O27—Ag39—I5	79.4 (2)
O9—Ag8—Ag7	73.9 (3)	O31—Ag39—Ag34	157.0 (2)
O16—Ag8—Ag7	143.8 (2)	O24ii—Ag39—Ag34	78.1 (2)
I6—Ag8—Ag7	54.33 (3)	O27—Ag39—Ag34	81.9 (2)
O9—Ag8—Ag9iv	56.8 (3)	I5—Ag39—Ag34	70.52 (3)
O16—Ag8—Ag9iv	68.5 (2)	O31—Ag39—Ag38	79.3 (2)
I6—Ag8—Ag9iv	150.99 (5)	O24ii—Ag39—Ag38	154.6 (3)
Ag7—Ag8—Ag9iv	113.71 (4)	O27—Ag39—Ag38	45.6 (2)
O9—Ag8—I7	75.0 (3)	I5—Ag39—Ag38	66.08 (3)
O16—Ag8—I7	119.2 (2)	Ag34—Ag39—Ag38	115.42 (4)
I6—Ag8—I7	100.13 (4)	O29—Ag40—O31iii	85.5 (3)
Ag7—Ag8—I7	76.91 (4)	O29—Ag40—I2	137.4 (2)
Ag9iv—Ag8—I7	51.24 (3)	O31iii—Ag40—I2	128.2 (2)
O9—Ag8—I9iv	140.8 (3)	O29—Ag40—Ag40ix	128.2 (2)
O16—Ag8—I9iv	74.2 (2)	O31iii—Ag40—Ag40ix	119.5 (2)
I6—Ag8—I9iv	91.25 (4)	I2—Ag40—Ag40ix	62.40 (4)
Ag7—Ag8—I9iv	140.53 (5)	O29—Ag40—I2ix	86.3 (2)
Ag9iv—Ag8—I9iv	86.51 (4)	O31iii—Ag40—I2ix	85.3 (2)
I7—Ag8—I9iv	93.21 (4)	I2—Ag40—I2ix	117.65 (4)
O9—Ag8—Ag13	131.2 (3)	Ag40ix—Ag40—I2ix	55.24 (4)
O16—Ag8—Ag13	56.8 (2)	O29—Ag40—Ag22	71.3 (2)
I6—Ag8—Ag13	83.73 (4)	O31iii—Ag40—Ag22	72.7 (2)
Ag7—Ag8—Ag13	130.23 (5)	I2—Ag40—Ag22	92.77 (4)
Ag9iv—Ag8—Ag13	115.64 (4)	Ag40ix—Ag40—Ag22	155.05 (6)
I7—Ag8—Ag13	143.00 (4)	I2ix—Ag40—Ag22	149.47 (4)
I9iv—Ag8—Ag13	49.81 (3)	O1vi—C1—O2	122.8 (11)
O17—Ag9—O3viii	80.9 (3)	O1vi—C1—O3	121.0 (11)
O17—Ag9—I7vi	136.2 (3)	O2—C1—O3	116.1 (11)
O3viii—Ag9—I7vi	136.3 (2)	O4—C2—O6	121.2 (13)
O17—Ag9—Ag4viii	160.9 (3)	O4—C2—O5	119.7 (12)
O3viii—Ag9—Ag4viii	81.7 (2)	O6—C2—O5	119.1 (12)
I7vi—Ag9—Ag4viii	62.84 (3)	O9—C3—O7	122.6 (12)
O17—Ag9—Ag8vi	84.5 (3)	O9—C3—O8	118.7 (12)
O3viii—Ag9—Ag8vi	158.1 (2)	O7—C3—O8	118.7 (12)
I7vi—Ag9—Ag8vi	64.39 (3)	O12—C4—O10i	122.9 (12)
Ag4viii—Ag9—Ag8vi	109.69 (4)	O12—C4—O11	118.7 (12)
O10—Ag10—O17vii	89.4 (4)	O10i—C4—O11	118.4 (11)
O10—Ag10—I10	137.4 (2)	O15—C5—O14	121.2 (11)
O17vii—Ag10—I10	127.2 (2)	O15—C5—O13ii	120.8 (11)
O10—Ag10—Ag30ix	131.1 (2)	O14—C5—O13ii	117.7 (11)
O17vii—Ag10—Ag30ix	111.5 (3)	O17iv—C6—O16	123.4 (13)
I10—Ag10—Ag30ix	60.78 (4)	O17iv—C6—O18iv	119.7 (13)
O10—Ag10—I4ix	86.7 (2)	O16—C6—O18iv	116.7 (13)
O17vii—Ag10—I4ix	84.7 (2)	O20iv—C7—O21	122.0 (12)
I10—Ag10—I4ix	114.46 (4)	O20iv—C7—O19	121.1 (12)
Ag30ix—Ag10—I4ix	54.06 (3)	O21—C7—O19	116.9 (12)
O10—Ag10—Ag11x	81.1 (2)	O23—C8—O22	122.7 (12)
O17vii—Ag10—Ag11x	147.9 (3)	O23—C8—O24	121.1 (12)
I10—Ag10—Ag11x	56.37 (3)	O22—C8—O24	116.2 (12)
Ag30ix—Ag10—Ag11x	97.51 (4)	O27—C9—O26	123.0 (12)
I4ix—Ag10—Ag11x	124.80 (4)	O27—C9—O25	119.9 (12)
O10—Ag10—Ag32vi	75.4 (2)	O26—C9—O25	117.0 (11)
O17vii—Ag10—Ag32vi	67.4 (3)	O30—C10—O28ix	123.3 (12)
I10—Ag10—Ag32vi	97.49 (4)	O30—C10—O29	119.4 (12)
Ag30ix—Ag10—Ag32vi	153.06 (5)	O28ix—C10—O29	117.2 (11)
I4ix—Ag10—Ag32vi	146.54 (4)	O33ii—C11—O32	120.2 (12)
Ag11x—Ag10—Ag32vi	80.60 (4)	O33ii—C11—O31	118.9 (12)
O12—Ag11—O22	81.5 (3)	O32—C11—O31	120.9 (12)
O12—Ag11—I10i	126.1 (3)	O36—C12—O34	121.8 (13)
O22—Ag11—I10i	138.0 (2)	O36—C12—O35	118.8 (13)
O12—Ag11—Ag12	57.5 (3)	O34—C12—O35	119.4 (13)
O22—Ag11—Ag12	69.8 (2)	C1iv—O1—Ag22iv	121.6 (8)
I10i—Ag11—Ag12	149.72 (5)	C1iv—O1—Ag27ii	113.6 (8)
O12—Ag11—Ag10i	73.9 (2)	Ag22iv—O1—Ag27ii	118.9 (4)
O22—Ag11—Ag10i	146.6 (2)	C1—O2—Ag21	126.6 (8)
I10i—Ag11—Ag10i	53.41 (3)	C1—O2—Ag5x	93.9 (7)
Ag12—Ag11—Ag10i	112.89 (4)	Ag21—O2—Ag5x	136.9 (4)
O12—Ag11—I8	75.9 (2)	C1—O2—Ag25	115.2 (8)
O22—Ag11—I8	120.1 (2)	Ag21—O2—Ag25	74.9 (3)
I10i—Ag11—I8	98.81 (4)	Ag5x—O2—Ag25	74.6 (2)
Ag12—Ag11—I8	51.20 (3)	C1—O3—Ag9vii	121.8 (8)
Ag10i—Ag11—I8	75.62 (3)	C1—O3—Ag26vi	117.3 (8)
O12—Ag11—Ag15	132.2 (2)	Ag9vii—O3—Ag26vi	102.1 (4)
O22—Ag11—Ag15	55.4 (2)	C1—O3—Ag5x	95.5 (7)
I10i—Ag11—Ag15	84.82 (4)	Ag9vii—O3—Ag5x	120.9 (4)
Ag12—Ag11—Ag15	115.09 (4)	Ag26vi—O3—Ag5x	97.8 (3)
Ag10i—Ag11—Ag15	131.93 (4)	C2—O4—Ag1	130.4 (9)
I8—Ag11—Ag15	140.93 (4)	C2—O4—Ag21i	126.0 (9)
O23—Ag12—O13	114.7 (4)	Ag1—O4—Ag21i	92.3 (3)
O23—Ag12—I8	134.8 (3)	C2—O4—Ag2	90.9 (8)
O13—Ag12—I8	110.6 (3)	Ag1—O4—Ag2	85.9 (3)
O23—Ag12—Ag11	82.6 (2)	Ag21i—O4—Ag2	128.5 (4)
O13—Ag12—Ag11	135.3 (2)	C2—O5—Ag7iii	126.7 (9)
I8—Ag12—Ag11	65.74 (4)	C2—O5—Ag24iii	111.7 (9)
O23—Ag12—Ag6	162.5 (3)	Ag7iii—O5—Ag24iii	102.4 (4)
O13—Ag12—Ag6	47.8 (3)	C2—O5—Ag2	95.7 (8)
I8—Ag12—Ag6	62.72 (3)	Ag7iii—O5—Ag2	117.3 (4)
Ag11—Ag12—Ag6	109.78 (4)	Ag24iii—O5—Ag2	100.5 (4)
O15—Ag13—O25	74.4 (4)	C2—O6—Ag25i	118.7 (9)
O15—Ag13—I9iv	141.1 (3)	C2—O6—Ag29iii	107.0 (9)
O25—Ag13—I9iv	144.6 (2)	Ag25i—O6—Ag29iii	119.1 (4)
O15—Ag13—Ag33	61.7 (3)	C2—O6—Ag6	114.9 (8)
O25—Ag13—Ag33	68.0 (3)	Ag25i—O6—Ag6	101.2 (4)
I9iv—Ag13—Ag33	121.59 (5)	Ag29iii—O6—Ag6	93.0 (4)
O15—Ag13—I11ii	95.3 (3)	C3—O7—Ag7	123.3 (8)
O25—Ag13—I11ii	84.8 (2)	C3—O7—Ag3	112.6 (8)
I9iv—Ag13—I11ii	90.54 (4)	Ag7—O7—Ag3	114.4 (4)
Ag33—Ag13—I11ii	147.81 (4)	C3—O8—Ag23	122.1 (8)
O15—Ag13—Ag14iv	131.5 (3)	C3—O8—Ag27	110.0 (8)
O25—Ag13—Ag14iv	79.8 (2)	Ag23—O8—Ag27	113.0 (4)
I9iv—Ag13—Ag14iv	73.29 (4)	C3—O8—Ag4v	106.9 (8)
Ag33—Ag13—Ag14iv	70.68 (4)	Ag23—O8—Ag4v	102.9 (4)
I11ii—Ag13—Ag14iv	122.63 (4)	Ag27—O8—Ag4v	98.8 (3)
O15—Ag13—Ag8	77.3 (3)	C3—O9—Ag8	126.6 (9)
O25—Ag13—Ag8	149.8 (3)	C3—O9—Ag28	133.2 (9)
I9iv—Ag13—Ag8	64.36 (3)	Ag8—O9—Ag28	90.2 (3)
Ag33—Ag13—Ag8	89.43 (4)	C4x—O10—Ag10	126.1 (8)
I11ii—Ag13—Ag8	108.24 (4)	C4x—O10—Ag5x	111.3 (8)
Ag14iv—Ag13—Ag8	112.45 (4)	Ag10—O10—Ag5x	111.1 (4)
O18—Ag14—O19xi	87.5 (3)	C4x—O10—Ag26vi	109.1 (8)
O18—Ag14—O26vi	78.6 (3)	Ag10—O10—Ag26vi	97.1 (3)
O19xi—Ag14—O26vi	74.8 (3)	Ag5x—O10—Ag26vi	96.8 (3)
O18—Ag14—I14	157.5 (3)	C4—O11—Ag25i	126.0 (8)
O19xi—Ag14—I14	109.0 (2)	C4—O11—Ag30	105.8 (8)
O26vi—Ag14—I14	90.8 (2)	Ag25i—O11—Ag30	112.6 (4)
O18—Ag14—I10viii	104.7 (3)	C4—O11—Ag6	107.7 (8)
O19xi—Ag14—I10viii	85.0 (2)	Ag25i—O11—Ag6	99.2 (3)
O26vi—Ag14—I10viii	159.4 (2)	Ag30—O11—Ag6	103.0 (3)
I14—Ag14—I10viii	92.23 (4)	C4—O12—Ag11	127.9 (9)
O18—Ag14—Ag19	135.0 (2)	C4—O12—Ag31i	133.8 (8)
O19xi—Ag14—Ag19	48.0 (2)	Ag11—O12—Ag31i	88.9 (3)
O26vi—Ag14—Ag19	82.8 (2)	C5iii—O13—Ag30	125.2 (9)
I14—Ag14—Ag19	61.53 (3)	C5iii—O13—Ag6	122.5 (8)
I10viii—Ag14—Ag19	80.76 (4)	Ag30—O13—Ag6	108.3 (4)
O18—Ag14—Ag13vi	77.6 (3)	C5iii—O13—Ag12	110.9 (8)
O19xi—Ag14—Ag13vi	142.8 (2)	Ag30—O13—Ag12	92.2 (4)
O26vi—Ag14—Ag13vi	69.0 (2)	Ag6—O13—Ag12	84.1 (4)
I14—Ag14—Ag13vi	80.08 (4)	C5—O14—Ag29	113.3 (8)
I10viii—Ag14—Ag13vi	131.61 (4)	C5—O14—Ag28	128.4 (8)
Ag19—Ag14—Ag13vi	131.82 (4)	Ag29—O14—Ag28	96.0 (4)
O21xii—Ag15—O28ix	78.2 (3)	C5—O15—Ag13	129.8 (9)
O21xii—Ag15—I13	141.8 (2)	C5—O15—Ag34	120.1 (9)
O28ix—Ag15—I13	139.6 (2)	Ag13—O15—Ag34	109.4 (5)
O21xii—Ag15—Ag35ix	60.8 (3)	C6—O16—Ag8	130.2 (9)
O28ix—Ag15—Ag35ix	74.4 (2)	C6—O16—Ag33	95.6 (9)
I13—Ag15—Ag35ix	123.41 (4)	Ag8—O16—Ag33	130.1 (4)
O21xii—Ag15—I12ii	89.6 (3)	C6—O16—Ag28	127.2 (9)
O28ix—Ag15—I12ii	81.8 (2)	Ag8—O16—Ag28	87.6 (3)
I13—Ag15—I12ii	91.30 (4)	Ag33—O16—Ag28	75.8 (3)
Ag35ix—Ag15—I12ii	144.96 (4)	C6vi—O17—Ag9	117.4 (9)
O21xii—Ag15—Ag16	130.5 (2)	C6vi—O17—Ag10viii	114.8 (9)
O28ix—Ag15—Ag16	79.0 (2)	Ag9—O17—Ag10viii	121.9 (4)
I13—Ag15—Ag16	75.04 (3)	C6vi—O18—Ag32xi	118.7 (9)
Ag35ix—Ag15—Ag16	70.96 (3)	C6vi—O18—Ag14	116.9 (9)
I12ii—Ag15—Ag16	129.35 (4)	Ag32xi—O18—Ag14	107.9 (4)
O21xii—Ag15—Ag11	78.8 (2)	C6vi—O18—Ag33vi	94.4 (8)
O28ix—Ag15—Ag11	156.0 (2)	Ag32xi—O18—Ag33vi	119.2 (4)
I13—Ag15—Ag11	64.11 (3)	Ag14—O18—Ag33vi	97.7 (4)
Ag35ix—Ag15—Ag11	88.30 (4)	C7—O19—Ag19xi	105.2 (8)
I12ii—Ag15—Ag11	104.95 (4)	C7—O19—Ag37ii	130.9 (9)
Ag16—Ag15—Ag11	111.47 (4)	Ag19xi—O19—Ag37ii	97.9 (4)
O29—Ag16—O24	77.0 (3)	C7—O19—Ag14xi	123.9 (8)
O29—Ag16—I15iii	165.1 (2)	Ag19xi—O19—Ag14xi	80.9 (3)
O24—Ag16—I15iii	110.7 (2)	Ag37ii—O19—Ag14xi	101.9 (4)
O29—Ag16—Ag22	77.1 (2)	C7vi—O20—Ag32vi	115.0 (8)
O24—Ag16—Ag22	143.3 (2)	C7vi—O20—Ag31	129.7 (8)
I15iii—Ag16—Ag22	89.99 (4)	Ag32vi—O20—Ag31	93.9 (3)
O29—Ag16—I16	90.0 (2)	C7—O21—Ag36	121.8 (8)
O24—Ag16—I16	151.4 (3)	C7—O21—Ag15xiv	127.4 (8)
I15iii—Ag16—I16	88.21 (4)	Ag36—O21—Ag15xiv	110.2 (4)
Ag22—Ag16—I16	53.06 (3)	C8—O22—Ag11	129.8 (9)
O29—Ag16—Ag15	64.0 (2)	C8—O22—Ag35ix	95.9 (8)
O24—Ag16—Ag15	77.3 (2)	Ag11—O22—Ag35ix	132.0 (4)
I15iii—Ag16—Ag15	129.34 (4)	C8—O22—Ag31i	122.5 (8)
Ag22—Ag16—Ag15	113.22 (4)	Ag11—O22—Ag31i	88.7 (3)
I16—Ag16—Ag15	74.05 (3)	Ag35ix—O22—Ag31i	75.1 (3)
O25—Ag17—O23ii	85.0 (3)	C8—O23—Ag12	121.3 (9)
O25—Ag17—I15	136.3 (2)	C8—O23—Ag17iii	111.2 (8)
O23ii—Ag17—I15	128.8 (2)	Ag12—O23—Ag17iii	122.2 (4)
O25—Ag17—Ag27ii	129.8 (2)	C8—O23—Ag34iii	107.3 (9)
O23ii—Ag17—Ag27ii	119.1 (2)	Ag12—O23—Ag34iii	93.1 (3)
I15—Ag17—Ag27ii	62.90 (3)	Ag17iii—O23—Ag34iii	92.9 (3)
O25—Ag17—I11ii	88.6 (2)	C8—O24—Ag39iii	126.3 (8)
O23ii—Ag17—I11ii	84.6 (2)	C8—O24—Ag16	113.6 (8)
I15—Ag17—I11ii	117.69 (4)	Ag39iii—O24—Ag16	99.6 (4)
Ag27ii—Ag17—I11ii	54.79 (3)	C8—O24—Ag35ix	95.1 (8)
O34iv—Ag18—O32	78.3 (3)	Ag39iii—O24—Ag35ix	122.4 (4)
O34iv—Ag18—O27	80.2 (3)	Ag16—O24—Ag35ix	96.8 (3)
O32—Ag18—O27	72.9 (3)	C9—O25—Ag17	111.5 (8)
O34iv—Ag18—I15	165.0 (3)	C9—O25—Ag13	121.2 (8)
O32—Ag18—I15	87.6 (2)	Ag17—O25—Ag13	108.8 (4)
O27—Ag18—I15	100.7 (2)	C9—O25—Ag34	110.4 (8)
O34iv—Ag18—I16iv	81.7 (2)	Ag17—O25—Ag34	98.7 (3)
O32—Ag18—I16iv	103.8 (2)	Ag13—O25—Ag34	103.7 (4)
O27—Ag18—I16iv	161.8 (2)	C9—O26—Ag37	122.2 (8)
I15—Ag18—I16iv	96.91 (4)	C9—O26—Ag33	113.0 (8)
O34iv—Ag18—I14iv	94.9 (3)	Ag37—O26—Ag33	111.7 (4)
O32—Ag18—I14iv	155.4 (2)	C9—O26—Ag14iv	109.9 (8)
O27—Ag18—I14iv	82.7 (2)	Ag37—O26—Ag14iv	101.0 (3)
I15—Ag18—I14iv	100.05 (4)	Ag33—O26—Ag14iv	94.6 (3)
I16iv—Ag18—I14iv	98.54 (4)	C9—O27—Ag38	133.0 (9)
O34iv—Ag18—Ag23iv	82.8 (2)	C9—O27—Ag18	124.7 (8)
O32—Ag18—Ag23iv	51.3 (2)	Ag38—O27—Ag18	88.6 (3)
O27—Ag18—Ag23iv	123.8 (2)	C9—O27—Ag39	106.7 (8)
I15—Ag18—Ag23iv	84.41 (4)	Ag38—O27—Ag39	82.8 (3)
I16iv—Ag18—Ag23iv	53.68 (3)	Ag18—O27—Ag39	114.4 (4)
I14iv—Ag18—Ag23iv	152.21 (4)	C10ix—O28—Ag20iii	121.7 (8)
O34—Ag19—O19xi	114.5 (4)	C10ix—O28—Ag15ix	111.8 (8)
O34—Ag19—I12x	117.8 (3)	Ag20iii—O28—Ag15ix	111.6 (4)
O19xi—Ag19—I12x	121.3 (2)	C10—O29—Ag35ix	122.2 (8)
O34—Ag19—I14	97.5 (2)	C10—O29—Ag40	108.3 (8)
O19xi—Ag19—I14	104.5 (2)	Ag35ix—O29—Ag40	113.1 (4)
I12x—Ag19—I14	93.67 (4)	C10—O29—Ag16	109.1 (8)
O34—Ag19—Ag14	122.6 (3)	Ag35ix—O29—Ag16	103.1 (3)
O19xi—Ag19—Ag14	51.1 (2)	Ag40—O29—Ag16	97.9 (3)
I12x—Ag19—Ag14	113.16 (4)	C10—O30—Ag21	127.3 (9)
I14—Ag19—Ag14	53.82 (3)	C10—O30—Ag1x	130.3 (8)
O28ii—Ag20—O35iii	82.1 (4)	Ag21—O30—Ag1x	91.9 (3)
O28ii—Ag20—I12	146.7 (2)	C11—O31—Ag39	123.2 (8)
O35iii—Ag20—I12	117.4 (3)	C11—O31—Ag40ii	112.4 (8)
O28ii—Ag20—I12xiii	86.8 (2)	Ag39—O31—Ag40ii	120.2 (4)
O35iii—Ag20—I12xiii	93.5 (3)	C11—O32—Ag38	130.8 (9)
I12—Ag20—I12xiii	116.52 (4)	C11—O32—Ag23iv	93.9 (8)
O28ii—Ag20—Ag20xiii	134.3 (3)	Ag38—O32—Ag23iv	132.2 (4)
O35iii—Ag20—Ag20xiii	118.4 (3)	C11—O32—Ag18	122.9 (8)
I12—Ag20—Ag20xiii	62.66 (4)	Ag38—O32—Ag18	88.6 (3)
I12xiii—Ag20—Ag20xiii	53.86 (4)	Ag23iv—O32—Ag18	77.2 (3)
O28ii—Ag20—Ag21i	85.4 (2)	C11iii—O33—Ag22	127.7 (9)
O35iii—Ag20—Ag21i	127.6 (3)	C11iii—O33—Ag4	115.3 (9)
I12—Ag20—Ag21i	61.23 (3)	Ag22—O33—Ag4	99.5 (4)
I12xiii—Ag20—Ag21i	136.37 (5)	C11iii—O33—Ag23v	92.3 (8)
Ag20xiii—Ag20—Ag21i	106.51 (5)	Ag22—O33—Ag23v	121.9 (4)
O30—Ag21—O2	79.1 (3)	Ag4—O33—Ag23v	97.2 (3)
O30—Ag21—O4x	74.1 (3)	C12—O34—Ag19	110.2 (9)
O2—Ag21—O4x	74.3 (3)	C12—O34—Ag18vi	129.5 (9)
O30—Ag21—I12x	125.9 (2)	Ag19—O34—Ag18vi	97.1 (4)
O2—Ag21—I12x	136.8 (2)	C12—O35—Ag20ii	131.5 (9)
O4x—Ag21—I12x	79.9 (2)	C12—O35—Ag36xi	122.3 (9)
O30—Ag21—Ag20x	73.6 (2)	Ag20ii—O35—Ag36xi	103.4 (4)
O2—Ag21—Ag20x	143.1 (2)	C12—O35—Ag2ii	106.1 (9)
O4x—Ag21—Ag20x	74.6 (2)	Ag20ii—O35—Ag2ii	96.9 (4)
I12x—Ag21—Ag20x	53.94 (3)	Ag36xi—O35—Ag2ii	79.1 (4)
O30—Ag21—Ag25	127.2 (2)	C12—O36—Ag24	123.0 (9)
O2—Ag21—Ag25	54.2 (2)	C12—O36—Ag3	127.8 (9)
O4x—Ag21—Ag25	70.9 (2)	Ag24—O36—Ag3	109.0 (4)
I12x—Ag21—Ag25	84.99 (4)	Ag3v—I1—Ag2iii	104.24 (4)
Ag20x—Ag21—Ag25	130.08 (4)	Ag3v—I1—Ag36v	89.58 (4)
O30—Ag21—Ag22	55.6 (2)	Ag2iii—I1—Ag36v	64.56 (4)
O2—Ag21—Ag22	70.8 (2)	Ag3v—I1—Ag1iii	149.04 (4)
O4x—Ag21—Ag22	122.5 (2)	Ag2iii—I1—Ag1iii	69.62 (4)
I12x—Ag21—Ag22	151.34 (5)	Ag36v—I1—Ag1iii	112.72 (4)
Ag20x—Ag21—Ag22	111.13 (4)	Ag3v—I1—Ag38iii	65.28 (4)
Ag25—Ag21—Ag22	117.60 (4)	Ag2iii—I1—Ag38iii	76.39 (4)
O30—Ag21—I16	75.0 (2)	Ag36v—I1—Ag38iii	126.35 (4)
O2—Ag21—I16	123.0 (2)	Ag1iii—I1—Ag38iii	83.94 (4)
O4x—Ag21—I16	140.2 (2)	Ag40—I2—Ag4	78.75 (4)
I12x—Ag21—I16	98.92 (4)	Ag40—I2—Ag1x	77.99 (4)
Ag20x—Ag21—I16	73.11 (3)	Ag4—I2—Ag1x	117.64 (4)
Ag25—Ag21—I16	148.87 (4)	Ag40—I2—Ag40ix	62.35 (4)
Ag22—Ag21—I16	52.54 (3)	Ag4—I2—Ag40ix	114.93 (4)
O30—Ag21—I14	142.3 (2)	Ag1x—I2—Ag40ix	103.32 (4)
O2—Ag21—I14	76.0 (2)	Ag40—I2—Ag35	126.08 (4)
O4x—Ag21—I14	124.2 (2)	Ag4—I2—Ag35	86.42 (3)
I12x—Ag21—I14	91.35 (4)	Ag1x—I2—Ag35	150.55 (4)
Ag20x—Ag21—I14	139.39 (4)	Ag40ix—I2—Ag35	78.70 (3)
Ag25—Ag21—I14	53.40 (3)	Ag37—I3—Ag38	67.95 (4)
Ag22—Ag21—I14	89.28 (4)	Ag37—I3—Ag36iii	83.76 (4)
I16—Ag21—I14	95.52 (4)	Ag38—I3—Ag36iii	112.46 (4)
O1vi—Ag22—O33	82.5 (3)	Ag37—I3—Ag2	116.41 (4)
O1vi—Ag22—I16	135.6 (2)	Ag38—I3—Ag2	79.14 (4)
O33—Ag22—I16	135.6 (3)	Ag36iii—I3—Ag2	159.74 (4)
O1vi—Ag22—Ag16	159.3 (2)	Ag37—I3—Ag3iii	127.86 (4)
O33—Ag22—Ag16	78.8 (2)	Ag38—I3—Ag3iii	161.60 (4)
I16—Ag22—Ag16	65.13 (3)	Ag36iii—I3—Ag3iii	81.11 (4)
O1vi—Ag22—Ag21	82.9 (2)	Ag2—I3—Ag3iii	84.43 (4)
O33—Ag22—Ag21	159.8 (3)	Ag37—I3—Ag7iii	61.85 (3)
I16—Ag22—Ag21	63.87 (3)	Ag38—I3—Ag7iii	108.36 (4)
Ag16—Ag22—Ag21	112.64 (4)	Ag36iii—I3—Ag7iii	109.16 (4)
O1vi—Ag22—Ag40	96.1 (2)	Ag2—I3—Ag7iii	81.01 (3)
O33—Ag22—Ag40	64.5 (3)	Ag3iii—I3—Ag7iii	76.84 (3)
I16—Ag22—Ag40	118.73 (4)	Ag30—I4—Ag34iii	81.99 (4)
Ag16—Ag22—Ag40	67.66 (3)	Ag30—I4—Ag31i	74.28 (4)
Ag21—Ag22—Ag40	103.41 (4)	Ag34iii—I4—Ag31i	115.44 (4)
O8—Ag23—O32vi	109.4 (3)	Ag30—I4—Ag10ix	61.77 (3)
O8—Ag23—O33v	75.6 (3)	Ag34iii—I4—Ag10ix	114.25 (4)
O32vi—Ag23—O33v	52.0 (3)	Ag31i—I4—Ag10ix	105.30 (4)
O8—Ag23—I16	136.2 (2)	Ag30—I4—Ag5iii	130.53 (4)
O32vi—Ag23—I16	111.5 (2)	Ag34iii—I4—Ag5iii	91.62 (4)
O33v—Ag23—I16	144.5 (2)	Ag31i—I4—Ag5iii	147.28 (4)
O8—Ag23—Ag3	69.2 (2)	Ag10ix—I4—Ag5iii	77.21 (3)
O32vi—Ag23—Ag3	58.2 (2)	Ag5—I5—Ag39	104.44 (4)
O33v—Ag23—Ag3	78.6 (2)	Ag5—I5—Ag1	70.03 (4)
I16—Ag23—Ag3	122.38 (4)	Ag39—I5—Ag1	80.84 (4)
O8—Ag23—Ag18vi	160.8 (2)	Ag5—I5—Ag6	67.44 (3)
O32vi—Ag23—Ag18vi	51.5 (2)	Ag39—I5—Ag6	161.34 (4)
O33v—Ag23—Ag18vi	90.8 (2)	Ag1—I5—Ag6	110.23 (4)
I16—Ag23—Ag18vi	61.30 (3)	Ag7—I6—Ag8	66.89 (4)
Ag3—Ag23—Ag18vi	95.20 (4)	Ag7—I6—Ag37ii	65.28 (4)
O8—Ag23—I15iii	82.2 (2)	Ag8—I6—Ag37ii	109.53 (4)
O32vi—Ag23—I15iii	123.7 (2)	Ag7—I6—Ag6ii	72.96 (4)
O33v—Ag23—I15iii	81.2 (2)	Ag8—I6—Ag6ii	112.38 (4)
I16—Ag23—I15iii	87.77 (4)	Ag37ii—I6—Ag6ii	99.26 (4)
Ag3—Ag23—I15iii	148.22 (4)	Ag7—I6—Ag32	123.20 (4)
Ag18vi—Ag23—I15iii	109.47 (4)	Ag8—I6—Ag32	80.53 (4)
O8—Ag23—Ag24	78.6 (2)	Ag37ii—I6—Ag32	85.53 (4)
O32vi—Ag23—Ag24	119.7 (2)	Ag6ii—I6—Ag32	163.28 (4)
O33v—Ag23—Ag24	146.2 (2)	Ag7—I6—Ag33ii	131.29 (4)
I16—Ag23—Ag24	68.21 (3)	Ag8—I6—Ag33ii	160.12 (4)
Ag3—Ag23—Ag24	71.92 (3)	Ag37ii—I6—Ag33ii	77.48 (3)
Ag18vi—Ag23—Ag24	107.84 (4)	Ag6ii—I6—Ag33ii	83.85 (3)
I15iii—Ag23—Ag24	116.54 (4)	Ag32—I6—Ag33ii	81.56 (3)
O36—Ag24—O5ii	88.3 (4)	Ag9iv—I7—Ag35v	108.57 (4)
O36—Ag24—I13	141.2 (3)	Ag9iv—I7—Ag31iv	80.64 (4)
O5ii—Ag24—I13	121.8 (3)	Ag35v—I7—Ag31iv	64.19 (3)
O36—Ag24—Ag29	148.0 (3)	Ag9iv—I7—Ag4v	63.67 (3)
O5ii—Ag24—Ag29	64.4 (3)	Ag35v—I7—Ag4v	89.99 (4)
I13—Ag24—Ag29	58.04 (3)	Ag31iv—I7—Ag4v	126.55 (4)
O36—Ag24—I12ii	118.6 (3)	Ag9iv—I7—Ag8	64.37 (3)
O5ii—Ag24—I12ii	89.4 (2)	Ag35v—I7—Ag8	149.45 (4)
I13—Ag24—I12ii	88.12 (4)	Ag31iv—I7—Ag8	85.27 (4)
Ag29—Ag24—I12ii	79.51 (4)	Ag4v—I7—Ag8	110.26 (4)
O36—Ag24—Ag23	57.8 (3)	Ag12—I8—Ag33	110.71 (4)
O5ii—Ag24—Ag23	133.5 (2)	Ag12—I8—Ag28	82.39 (4)
I13—Ag24—Ag23	83.41 (4)	Ag33—I8—Ag28	65.73 (3)
Ag29—Ag24—Ag23	130.45 (4)	Ag12—I8—Ag6	65.99 (4)
I12ii—Ag24—Ag23	133.17 (4)	Ag33—I8—Ag6	89.96 (4)
O11x—Ag25—O6x	79.4 (3)	Ag28—I8—Ag6	130.27 (4)
O11x—Ag25—O2	119.2 (3)	Ag12—I8—Ag11	63.06 (3)
O6x—Ag25—O2	99.0 (3)	Ag33—I8—Ag11	151.23 (4)
O11x—Ag25—I14	134.1 (2)	Ag28—I8—Ag11	85.50 (4)
O6x—Ag25—I14	141.5 (3)	Ag6—I8—Ag11	110.18 (4)
O2—Ag25—I14	81.2 (2)	Ag13vi—I9—Ag32vi	103.36 (4)
O11x—Ag25—Ag21	160.3 (2)	Ag13vi—I9—Ag26vi	87.69 (4)
O6x—Ag25—Ag21	85.3 (2)	Ag32vi—I9—Ag26vi	62.62 (3)
O2—Ag25—Ag21	51.0 (2)	Ag13vi—I9—Ag31	147.96 (4)
I14—Ag25—Ag21	64.85 (3)	Ag32vi—I9—Ag31	70.35 (3)
O11x—Ag25—Ag5x	67.4 (2)	Ag26vi—I9—Ag31	114.28 (4)
O6x—Ag25—Ag5x	82.1 (3)	Ag13vi—I9—Ag8vi	65.83 (4)
O2—Ag25—Ag5x	52.5 (2)	Ag32vi—I9—Ag8vi	78.44 (4)
I14—Ag25—Ag5x	123.97 (4)	Ag26vi—I9—Ag8vi	126.18 (4)
Ag21—Ag25—Ag5x	98.37 (4)	Ag31—I9—Ag8vi	82.18 (3)
O3iv—Ag26—O10iv	79.4 (3)	Ag10—I10—Ag11x	70.22 (4)
O3iv—Ag26—I11ii	106.6 (2)	Ag10—I10—Ag30ix	64.37 (4)
O10iv—Ag26—I11ii	162.0 (2)	Ag11x—I10—Ag30ix	108.77 (4)
O3iv—Ag26—I9iv	153.3 (2)	Ag10—I10—Ag29x	124.39 (4)
O10iv—Ag26—I9iv	88.8 (2)	Ag11x—I10—Ag29x	83.63 (4)
I11ii—Ag26—I9iv	91.93 (4)	Ag30ix—I10—Ag29x	80.35 (4)
O3iv—Ag26—Ag32	141.6 (2)	Ag10—I10—Ag14vii	79.57 (4)
O10iv—Ag26—Ag32	80.3 (2)	Ag11x—I10—Ag14vii	115.52 (4)
I11ii—Ag26—Ag32	85.04 (4)	Ag30ix—I10—Ag14vii	106.73 (4)
I9iv—Ag26—Ag32	57.17 (3)	Ag29x—I10—Ag14vii	154.60 (4)
O8—Ag27—O1iii	85.1 (3)	Ag27—I11—Ag28	79.43 (4)
O8—Ag27—I11	137.3 (2)	Ag27—I11—Ag26iii	80.72 (4)
O1iii—Ag27—I11	127.0 (2)	Ag28—I11—Ag26iii	119.27 (4)
O8—Ag27—Ag17iii	128.9 (2)	Ag27—I11—Ag17iii	61.83 (3)
O1iii—Ag27—Ag17iii	120.2 (2)	Ag28—I11—Ag17iii	105.19 (4)
I11—Ag27—Ag17iii	63.38 (3)	Ag26iii—I11—Ag17iii	114.20 (4)
O8—Ag27—I15iii	86.6 (2)	Ag27—I11—Ag13iii	122.19 (4)
O1iii—Ag27—I15iii	86.8 (2)	Ag28—I11—Ag13iii	153.98 (4)
I11—Ag27—I15iii	118.44 (4)	Ag26iii—I11—Ag13iii	81.20 (3)
Ag17iii—Ag27—I15iii	55.06 (3)	Ag17iii—I11—Ag13iii	77.16 (3)
O14—Ag28—O9	77.4 (4)	Ag20—I12—Ag19i	120.04 (4)
O14—Ag28—O16	80.8 (3)	Ag20—I12—Ag21i	64.83 (3)
O9—Ag28—O16	74.4 (3)	Ag19i—I12—Ag21i	82.59 (4)
O14—Ag28—I11	166.7 (3)	Ag20—I12—Ag20xiii	63.48 (4)
O9—Ag28—I11	98.4 (3)	Ag19i—I12—Ag20xiii	84.97 (4)
O16—Ag28—I11	85.9 (2)	Ag21i—I12—Ag20xiii	109.61 (4)
O14—Ag28—I8	85.5 (3)	Ag20—I12—Ag15iii	130.11 (4)
O9—Ag28—I8	162.8 (3)	Ag19i—I12—Ag15iii	84.83 (4)
O16—Ag28—I8	105.2 (2)	Ag21i—I12—Ag15iii	164.41 (4)
I11—Ag28—I8	98.73 (4)	Ag20xiii—I12—Ag15iii	78.30 (3)
O14—Ag28—Ag33	85.1 (3)	Ag20—I12—Ag24iii	81.27 (4)
O9—Ag28—Ag33	124.9 (2)	Ag19i—I12—Ag24iii	158.30 (4)
O16—Ag28—Ag33	51.2 (2)	Ag21i—I12—Ag24iii	112.73 (4)
I11—Ag28—Ag33	87.18 (4)	Ag20xiii—I12—Ag24iii	102.95 (4)
I8—Ag28—Ag33	54.47 (3)	Ag15iii—I12—Ag24iii	77.23 (3)
O14—Ag28—I13	91.9 (3)	Ag15—I13—Ag24	90.20 (4)
O9—Ag28—I13	78.4 (2)	Ag15—I13—Ag29	105.36 (4)
O16—Ag28—I13	152.8 (2)	Ag24—I13—Ag29	65.28 (4)
I11—Ag28—I13	99.65 (4)	Ag15—I13—Ag28	148.85 (4)
I8—Ag28—I13	100.34 (4)	Ag24—I13—Ag28	113.66 (4)
Ag33—Ag28—I13	154.77 (4)	Ag29—I13—Ag28	70.21 (3)
O14—Ag29—O6ii	119.4 (4)	Ag25—I14—Ag14	92.63 (4)
O14—Ag29—I13	101.0 (3)	Ag25—I14—Ag19	101.58 (4)
O6ii—Ag29—I13	136.3 (3)	Ag14—I14—Ag19	64.65 (3)
O14—Ag29—I10i	117.1 (3)	Ag25—I14—Ag18vi	144.30 (4)
O6ii—Ag29—I10i	83.1 (2)	Ag14—I14—Ag18vi	112.82 (4)
I13—Ag29—I10i	93.27 (4)	Ag19—I14—Ag18vi	70.24 (3)
O14—Ag29—Ag24	123.4 (3)	Ag25—I14—Ag21	61.75 (3)
O6ii—Ag29—Ag24	85.7 (2)	Ag14—I14—Ag21	128.69 (4)
I13—Ag29—Ag24	56.68 (3)	Ag19—I14—Ag21	77.33 (3)
I10i—Ag29—Ag24	115.57 (4)	Ag18vi—I14—Ag21	82.60 (3)
O14—Ag29—Ag7	70.3 (3)	Ag17—I15—Ag16ii	78.40 (4)
O6ii—Ag29—Ag7	74.4 (2)	Ag17—I15—Ag18	78.39 (4)
I13—Ag29—Ag7	107.45 (4)	Ag16ii—I15—Ag18	115.08 (4)
I10i—Ag29—Ag7	156.56 (5)	Ag17—I15—Ag27ii	62.03 (3)
Ag24—Ag29—Ag7	69.80 (4)	Ag16ii—I15—Ag27ii	114.94 (4)
O13—Ag30—O11	76.6 (3)	Ag18—I15—Ag27ii	105.28 (4)
O13—Ag30—I4	114.9 (3)	Ag17—I15—Ag23ii	126.19 (4)
O11—Ag30—I4	144.5 (2)	Ag16ii—I15—Ag23ii	88.27 (4)
O13—Ag30—I10ix	102.7 (3)	Ag18—I15—Ag23ii	150.50 (4)
O11—Ag30—I10ix	88.6 (2)	Ag27ii—I15—Ag23ii	78.17 (3)
I4—Ag30—I10ix	118.60 (5)	Ag22—I16—Ag23	108.58 (4)
O13—Ag30—Ag10ix	134.2 (3)	Ag22—I16—Ag18vi	82.22 (4)
O11—Ag30—Ag10ix	133.0 (2)	Ag23—I16—Ag18vi	65.03 (3)
I4—Ag30—Ag10ix	64.17 (3)	Ag22—I16—Ag21	63.58 (3)
I10ix—Ag30—Ag10ix	54.85 (3)	Ag23—I16—Ag21	148.35 (4)
O20—Ag31—O12x	77.9 (3)	Ag18vi—I16—Ag21	83.34 (4)
O20—Ag31—O22x	78.3 (3)	Ag22—I16—Ag16	61.81 (3)
O12x—Ag31—O22x	75.6 (3)	Ag23—I16—Ag16	89.39 (4)
O20—Ag31—I4x	165.3 (2)	Ag18vi—I16—Ag16	126.65 (4)
O12x—Ag31—I4x	101.3 (2)	Ag21—I16—Ag16	110.02 (4)
O22x—Ag31—I4x	87.2 (2)

Symmetry codes: (i) −x, y−1/2, −z+1/2; (ii) x, −y+1/2, z−1/2; (iii) x, −y+1/2, z+1/2; (iv) −x+1, y−1/2, −z+1/2; (v) −x+1, −y+1, −z+1; (vi) −x+1, y+1/2, −z+1/2; (vii) x, −y+3/2, z+1/2; (viii) x, −y+3/2, z−1/2; (ix) −x, −y+1, −z+1; (x) −x, y+1/2, −z+1/2; (xi) −x+1, −y+1, −z; (xii) x−1, y, z; (xiii) −x, −y, −z+1; (xiv) x+1, y, z.

Funding Statement

This work was funded by Murata Science Foundation grant H30-95.