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. 2022 Jan 21;27(3):708. doi: 10.3390/molecules27030708

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© 2022 by the authors.

Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).

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Scheme 4 — (a) Stereochemical course of deuterium and hydrogen after incubation with IspH in D₂O and isopentenyl diphosphate isomerase in H₂O [75]. (b) Substrate analog 25 used by Liu et al. and the product formed in the IspH catalyzed reaction [76].