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. 2022 Apr 30;12:7081. doi: 10.1038/s41598-022-11146-3

Quantum correlated heat engine in XY chain with Dzyaloshinskii–Moriya interactions

M Asadian 1, S Ahadpour 1,, F Mirmasoudi 1
PMCID: PMC9056535  PMID: 35490156

Abstract

In this paper, we consider a heat engines composed of two interactional qubits with spin-orbit interaction (Dzyaloshinskii–Moriya (DM)) subject to an external magnetic field, so that each qubit is coupled with cold or hot source. One intention of this work is to investigate the following question: is it possible the effects of DM lead to improve basic thermodynamic quantities in this heat engine are coupled to local environments that are not necessarily at equilibrium? Moreover, we study whether or not quantum correlations can be helpful in the performance of quantum work engines. For this end, we investigate the effects of the temperature and the interaction rate of each qubit with its surrounding environment on quantum correlations such as quantum coherence and quantum discord and quantum entanglements, as well as the generated work. Finally we compare three quantum correlations (entanglement, discord, and coherence) with thermodynamic parameters and show that the output work is positive for what values of the magnetic field so that this cycle can be considered as a thermal machine.

Subject terms: Condensed-matter physics; Quantum physics; Statistical physics, thermodynamics and nonlinear dynamics

Introduction

In recent years, there has been a revolution in the thermodynamic concepts, which is referred to as a new found among the physical theories. In this theory, the spread of information is described through quantum systems. This new theory, under the title of quantum thermodynamics, attempts to express thermodynamic concepts such as work, heat, efficiency, and so on by using quantum information theory14. A primary relation exists between thermodynamics and information theory. The laws of thermodynamics are a set of universal rules that explain the interaction between temperature, heat, work, energy, and entropy. The laws of thermodynamics are not only valid in the case of steam engines, but also for any other problem, including the sun, black holes, living things, and even the whole world. Thermodynamic rules are used only to express that a process is feasible or not. Quantum thermodynamics works to develop quantum machines58. The most important application of quantum thermodynamics is quantum heat engines and one of the famous cycles in the quantum thermodynamic is the Carnot cycle911. The most common cyclic process is the Otto cycle1214. The Otto cycle is the basis of all the heat engines performed based on the internal combustion process and hence it is of critical importance. In the following, we will begin to describe the basic processes (strokes) related to the classical form of the Otto cycle, in which the active material is a two-level system. The name of Otto cycle is retrieved from the German engineer Nicholas Otto, who worked for the manufacturing of the first four-stroke engine based on the initial design presented by Alphonse Beau de Rochas. Here, we want to discuss the role of quantum correlations in quantum thermodynamics15. First, Alicki defined the weak connection between heat and work in thermodynamic processes, namely under the influence of slowly varying external conditions. He assumed that a change in the Hamiltonian and state of the sub-system is necessarily associated with the work and heat, respectively16. Afterward, more appropriate definitions are presented for thermodynamic work and heat1720. Different quantum matters such as qubits2125, qudits2629, photons3032, harmonic oscillators13,33,34, and so on are used in the field of heat engines. In this paper, a system is considered with two qubits a and b as the working matter. We consider an Otto cycle with the working matter in the form of two coupled qubits. We compare the behavior of quantum correlation and thermodynamic parameters together. This model we have considered show that there is a connection between quantum correlations and positive work in cycle.

The paper is organized as follows. In "Model system: the quantum Otto engine" Section, we give the model and calculate the density matrix for a system composed of two interactional qubits with spin-orbit interaction in the Otto cycle. In "Work definition" Section, we define work and calculating the work, heat and efficiency of a heat cycle for our proposed model. In "Quantum correlations" Section, we recall briefly entanglement, discord and coherence measures of the quantum correlations and we derive the analytical expression to the entanglement, discord and coherence and show how creating quantum correlations can be limited by the thermodynamics of the system. Finally, we give the conclusions in "Conclusion" Section.

Model system: the quantum Otto engine

Here we consider a system consisting of two interacting qubits a and b as the working material a four- level quantum Otto engine, which is described by XY Hamiltonian considering the spin-orbit interaction and magnetic field35:

H=(Jxσxaσxb+Jyσyaσyb)+B(σza+σzb)+D(σxaσyb-σyaσxb) 1

where σ[x,y,z]j denotes the Pauli operators that affect the qubits j=a,b, Jx and Jy are the strength of the antiferromagnetic couplings, B is the intensity of the magnetic field, and D is the spin-orbit interaction factor. We set Jx=Jy=J and assume that the dynamics of the working matter density operator ρ have the Markovian property, and can be stated by Lindblad master equation as follows36:

ρ˙=-[H,ρ]+igiLai(ρ). 2

Accordingly, Lai=2aiρai+-{ai+ai,ρ} and ai is the jump operator that describes the operation of the baths, and gi is the dissipation rate associated with the Lindblad term Li in the above equation. It is assumed that Lindblad operators of Lσ+j with coefficient g+j=γjn¯j, and Lσ-j with coefficient g-j=γj(n¯j+1) are the jump operators in two general forms of raising operator σ+=|10| and lowering operator σ-=|01|. The coefficients γj is the interaction rate of each qubit with its surroundings and n¯j is the population of the corresponding equilibrium temperature (the average particle number) which is defined by the following equation:

n¯j=(e2Bj/Tj-1)-1 3

where Bj and Tj are the magnetic field and temperature for the bath coupled to qubit j, respectively. In the present paper, we consider different temperatures for the cold and hot baths coupled with two qubits. So, n¯Ca and n¯Cb are the population of the corresponding equilibrium temperature of the cold bath coupled with qubits a and b in the cooling process, and n¯Ha and n¯Hb are the population of the corresponding equilibrium temperature of the hot bath coupled with qubits a and b in the heating process. It is assumed that γa=γ1 and γb=γ2 (breakdown rates) take on different values. In this generalized Otto cycle, during the compression (expansion) stroke the magnetic field and spin-orbit interaction factor are changed, for both qubits, from B1 to B2 and D1 to D2 (B2 to B1 and D2 to D1) with B2>B1 and D2>D1. Under this condition, by following Ref36 the density matrix can be expressed as,

ρs=1αr110000r22ir2300-ir23r330000r44 4

where r’s and α are reported in Appendix. The working substance undergoes a generalized Otto cycle37. The four stages of the cycle are as follows:

  1. Adiabatic compression (Isentropic): The system is compressed, and work is done on the system. This stroke consists of volume and temperature variations, while entropy will remain constant throughout it. The material is isolated from the environment, and some of the Hamiltonian parameters Jx, Jy , B or D changes accordingly to involve an increase in the energy gap.

  2. Isochoric heating: The temperature increases while the volume of the system (working substance) is constant. That means heat is absorbed from the source. During the evolution, the working matter proceeds to a steady state of Equation (2) with ρ˙=0.

  3. Adiabatic expansion (Isentropic): The stroke power when a useful work comes out of the engine. Again, this stroke involves volume and temperature variations, and entropy is constant. The material is isolated from the environment, and some of the Hamiltonian parameters Jx, Jy , B or D gets its previous value. This leads to a decrease in the energy gap, which means approaching the classic case.

  4. Isochoric cooling: The environment is cooled in a constant volume and returns to its initial state, and it is ready to start the cycle again. To understand all aspects of the Otto-quantum cycle, we should examine how this four-stroke cycle is performed in the work environment which is a quantum system.

We note that for Hamiltonian Eq. (1) the parameter P(t) changes depending on the evolution of each of the parameters Jx , Jy, B or D. This parameter revolves from the initial P1 to the final value P2 through the equation P(t)=P1+(P2-P1)t/τ, where τ is the duration of the work stroke. In the following, we will study the quantum work and three quantum correlations (entanglement, coherence, and discord) for this density matrix and compare the behavior of these three quantum correlations. We also present the variation of the work against different parameters.

Work definition

In classical thermodynamics, we can define work as the potential energy of an external device that can be stored for later uses. In quantum systems, work is defined as a change in the energy of two systems17. To assess the work extracted or produced by the engine during the cycle we employ the definition of work based on the two-time measurement protocol. We now change the Hamiltonian from Hin to Hfin in time while the system is isolated from any environment. Hin and Hfin are the initial Hamiltonian with eigenvalues Eiin and the final Hamiltonian with eigenvalues Eifin, respectively. Assuming ρτ=UρsU+ we can obtain final state, in this equation ρs is the initial state of the system in the process and ρτ is the final state of the process where U is a unitary operator. Now, the mean work can be obtained as:

W=Tr(ρτHfin)-Tr(ρsHin), 5

An important property in the Otto cycle is that it is isolated during the expansion and compression processes, and the change of energy is only in the form of external work. On the other hand, both work and heat variation may occur in cooling and heating processes and for unbalanced reservoirs. -W1 and -W2 represent the extracted work during the expansion and compression processes, and Q1 and Q2 are the heat obtained by the environment during heating and cooling processes. We assume Q>0 when the heat is absorbed from the environment and the energy level increases in the system. Heat fluctuations cause the system to excite and the system leaves the ground state. Which means an increase in energy levels. So, we have for the cyclic evolution:

W1+W2+Q1+Q2=0. 6

And the total derived work is equal to:

WT=-(W1+W2)=Q1+Q2. 7

In this case, efficiency is defined as the ratio of the extracted work (if positive) to the total heat absorbed by the source15:

η=WTQi>0Qi. 8

Assuming that the heating process corresponds to connecting the two qubits with two local baths with thermal occupation n¯H and the cooling process with n¯C, on condition n¯b=0, the following equations are obtained. Now, we assume ρC and ρH are the stable states for cold and hot baths with rijC and rijH elements, respectively. The total work is given by the following equation:

WT=(B2-B1)(r11C-r11H+r44H-r44C). 9

We remark here that heat absorbed is minus the energy balance of the system during the heating of the system from n¯C to n¯H. Thus, for the heat absorbed from two hot sources, using Eq. (7), we have:

Q1=B2(r11C-r11H+r44H-r44C). 10

And the efficiency is defined as follows:

η=WTQ1=1-B1B2. 11

It is straightforward to see that the efficiency only is under the effect of the magnetic field is identical on both spins can be controlled by it. But, the external work and heat not only depend on the magnetic field but also Dzyaloshinskii–Moriya. How one can detect the adiabatic process in this system? For the illustrating purpose, we will assume two different outlines for the adiabatic stages: At first, the Dzyaloshinski-Moriya (DM) anisotropic antisymmrtric interaction is altered between two values (D1D2D1 ) at a magnetic field, and next the fixed magnetic field is changed between two values (B1B2B1 ) at a Dzyaloshinski-Moriya (DM) anisotropic antisymmrtric interaction. We calculate the total work for different parameters such as the interaction rate of the first qubit with its environment and the interaction factor between the spin-orbit and magnetic field. In Fig. 1, there is work for γ10 and it is maximum at 1γ12. In Fig. 1, the output work is positive for 1B26, so this idea can be implemented as a practical heat engine. Also we observed that the derived total work decreases by increasing the spin-orbit interaction factor. In Fig. 2 contour plots of the total work is plotted as a function γ1 and γ2. It is clear that for T2=4 for γ11 and γ20.2 the total work have the maximum possible value. Also, we observe that by increasing the temperature of hot bath from T2=2 to T2=4, the total work is increased. Considering the Dzyaloshinskii–Moriya interactions, despite the increase in the population of the corresponding equilibrium temperature, the total work is still there. From Eq. (11), we see that increasing the magnetic field has a very positive effect on system efficiency. But increasing the temperature has no effect on efficiency, efficiency is sensitive to changes in magnetic field. We remark here that the two-time energy measurement protocol may affect both the work produced and the quantum correlations of the working substance, which is the main focus of this paper.

Figure 1.

Figure 1

Plots of the total work for an Otto cycle operating between T1=1 and T2=4 using the steady state. (Top left): We fix J=1, D1=0, D2=5, γ1=0.1, γ2=5, n¯b=0 and vary the magnetic field from B1=1 to B2 reported on the horizontal axis. (Top right): We fix J=1, γ1=0.1, γ2=5, D2=5, B1=1 and B2=2; and vary the D1 from 0 to 5. (Bottom): We fix J=1, B1=1, B2=2, D1=0, D2=5, γ2=5 ,n¯b=0 and we change interaction rate of first qubit with its surrounding (γ1) from 0 to the value reported on the horizontal axis.

Figure 2.

Figure 2

Contour plots of the total work for an Otto cycle corresponding to T2=2 (left) and T2=4 (right) as a function of γ1 and γ2, with J=1, B1=1, B2=2, T1=1, n¯b=0, D1=0 and D2=5 for both panels.

Quantum correlations

In this section, we investigate the effects of quantum correlations at the end of the two isochoric processes of the Otto cycle. We discuss the quantum correlations in our system by analyzing the behavior of the entanglement, quantum discord and quantum coherence. Since, the elements of our density matrix are independent of the magnetic field, the quantum correlations will not be dependent on the magnetic field. Depending on the inter qubit couplings, the reservoir temperatures, and the decay rates, the steady state might become entangled. To measure the amount of the latter we employ the concurrence.

Quantum entanglement

Entanglement is one of the important and Unintuitive phenomena in the quantum world. The entanglement is the property shared between two or more systems showing correlations that cannot be described by classical physics, and this kind of correlation does not exist in the macroscopic world. Two particles may be very far from each other, but they can relate to each other, and whatever happens to one, it immediately causes a change in the other one. In quantum mechanics, the entanglement relates to quantum correlations that are rooted in the inseparable nature of the state vector of the quantum system15,3840. If ρ is the density matrix of two qubits, so λi represent the roots of matrix ρρ~ where ρ~ is defined as ρ~=(σyaσyb)ρ(σyaσyb). Also, the concurrence as an entanglement measure, can be calculated with C(ρ)=max(0,λ1-λ2-λ3-λ4), where λ1>λ2>λ3>λ4. Because our matrix is X-state, concurrence is obtained as follows:

C(ρ)=max[0,t1,t2], 12

where t1=2(r23×r32-r11×r44) and t2=2(r14×r41-r22×r33).

In Fig. 3 contour plots of the concurrence obtained from Eq. (12) is plotted as a function γ1 and γ2. We observe that the entanglement gets smaller by increasing the temperature. Even, the maximum amount of entanglement in this case is a small amount. We can see in Fig. 3 that the entanglement persists only for very low values of n¯.

Figure 3.

Figure 3

Contour plots of the concurrence of state ρ in Eq. (4) corresponding to n¯b=0 and n¯a=1 (left) and n¯a=2 (right) as a function of γ1 and γ2, with J=1 and D=1 for both panels.

Quantum discord

A bipartite quantum state consists of classical and conventional correlations. These correlations are jointly measured by their quantum mutual information which is a theoretical measure of the total correlation in a bipartite quantum state. In particular, if ρAB is the density operator of a compound binary system AB and ρA(ρB) describes the density operator of term A(B), thus the quantum mutual information is defined as40,

L(ρ(AB))=S(ρA)+S(ρB)-S(ρAB) 13

where S(ρ)=-Tr(ρlog2ρ) is the von Neumann entropy. Quantum mutual information may be written as the sum of the classical correlation C(ρAB) and the quantum correlation Q(ρAB) that is L(ρ(AB))=C(ρAB)+Q(ρAB)4144. This quantum term Q(ρ) is called quantum discord42. This is a different kind of quantum correlation compared to the entanglement since the separable mixed modes (i.e., without entanglement) can have a nonzero quantum discord. Quantum discord is not always bigger than the entanglement45,46. The quantum discord (QD) for the X-state matrix is obtained as follows43:

QD(ρAB)=min(Q1,Q2), 14

that Q1 and Q2 are obtained as follows,

ϵ1=12(r11+r44)+(r11-r44)2+4|r14|2, 15a
ϵ2=12(r11+r44)-(r11-r44)2+4|r14|2, 15b
ϵ3=12(r11+r33)+(r22-r33)2+4|r23|2, 15c
ϵ4=12(r22+r33)-(r22-r33)2+4|r23|2, 15d
H(x)=-xlog2x-(1-x)log2(1-x), 16
d1=H1+[1-2(r33+r44]2+4(|r14|+|r23|)22, 17a
d2=iriilog2rii-H(r11+r33), 17b
Qj=H(r11+r33)+i=14ϵilog2ϵi+dj. 18

In Fig. 4 using the Eq. (14) contour plots of the quantum discord is plotted as a function γ1 and γ2. We find from Fig. 4 which quantum discord is sensitive to reservoir temperatures. It is important to note under what the condition quantum discord can be sustain more. Moreover, by compareing Figs. 3 and 4 we can find with increasing the interaction rate of the second qubit with its environment, the entanglement becomes more tangible and the quantum discord first increases, then decreases. Also, with increasing the population of the corresponding equilibrium temperature, both entanglement and quantum discord are decreasing.

Figure 4.

Figure 4

Contour plots of the discord of state ρ in Eq. ( 4) corresponding to n¯b=0 and n¯a=1 (left) and n¯a=2 (right) as a function of γ1 and γ2, with J=1 and D=1 for both panels.

Quantum coherence

The quantum coherence derived from the superposition of quantum states differentiates quantum from classical mechanics. The quantum coherence contained between different parts of quantum systems is the basis for the creation of quantum correlations4749. The quantum coherence, which arises from the superposition principle, is one of the best non-classical features of a quantum system. Based on the research works conducted in this field5052, quantum coherence is achieved through the following equation:

I(ρ,k)=-12Tr[ρ,k]2 19

where ρ is the quantum state density matrix, k is an observable, and [,] is the displacement. Minimum skew information achievable on a single local measurement defined as,

uAminKAI(ρAB,KA) 20

The minimization is performed over all local maximally informative observable (or nondegenerate) KA=KAIB. We use a closed form of the quantum coherence for 2d quantum systems which is introduced by Girolami as,

uA=1-λmax(χ) 21

where λmax is the maximum eigenvalue of the 3×3 matrix χ with the elements χij=Tr{ρ(σiAIB)ρ(σjAIB)} and σi(i=1,2,3) represent the Pauli matrices.

In Fig. 5 using the Eq. (21) contour plots of the quantum coherence is ploted as a function γ1 and γ2. We find from Fig. 5 which quantum coherence is sensitive to reservoir temperatures. It is important to note under what the condition quantum coherence can be sustain more. We observe that by increasing the interaction rate of any qubit with its environment, the quantum coherence further increases compared to the entanglement (see Figs. 3, 4 and 5 ). As can be seen, the quantum coherence is decreasing in terms of the population of the corresponding equilibrium temperature such as the entanglement and the quantum discord. Also, for constant γ1, by increasing the γ2, the entanglement becomes more perceptible and the quantum discord the first increases then decreases. But the quantum coherence further increases compared to the entanglement. To compairing the behavior of quantum correlations and quantum work, we draw Fig. 6 and set D=D1. Figure 6 shows the plots of three quantum correlations and the total work, as a function spin-orbit interaction factor D. Based on this Figure, DM interaction parameter releases the positive work condition compared to export quantum correlations in the XY chain under the condition that D1D2 in adiabatic process. In the area D>2.2 even when the concurrence is absent, quantum correlation can be exported by way discord, so that positive works happening in our cycle as long as D0. As a result, Fig. 6 shows that the discord of system decreases as the total work done by the system decreases. We can see a clear relation, for this type of engine, between quantum correlations and energetic performances.

Figure 5.

Figure 5

Contour plots of the coherence of state ρ in Eq. (4) corresponding to n¯b=0 and n¯a=1 (left) and n¯a=2 (right) as a function of γ1 and γ2, with J=1 and D=1 for both panels.

Figure 6.

Figure 6

Plots of the total work, coherence, concurrence and discord for an Otto cycle operating between T1=1 and T2=4 using the steady state. We fix J=1, γ1=0.1, γ2=5, D2=5, n¯a=2, n¯b=0, B1=1 and B2=2, and change D.

Conclusion

In summary, we proposed a composite system composed of two interactional qubits with spin-orbit interaction. We discussed the work extraction from the engine and its efficiency as well as the role of quantum correlations, characterized by the quantum entanglement, quantum discord and quantum coherence in the thermodynamical processes. The density matrix and quantum correlations are calculated for the state XY, and we observe that three quantum correlations decrease by increasing the population of the corresponding equilibrium temperature. We also saw that, in the absence of entanglement in the system, the work done in the system is not necessarily zero, while discord can be a powerful tool for identifying positive work in the system. We also see that with increasing the spin-orbit interaction factor, three quantum correlations and the total work decrease. Therefore, three quantum correlations behavior in terms of the Dzyaloshinskii–Moriya interactions coefficient are the agree on the total work behavior. We have identified for what range of magnetic fields, we can consider this system as a heat engine. Our work show new light on the study of the work extraction from the engine and its efficiency as well as the role of quantum correlations. Interestingly, we have shown that it is possible to make a direct link between the work and the quantum correlations, entanglement, coherence and discord in during the Otto cycle.

Supplementary Information

Author contributions

M.A. developed the theoretical formalism, performed the analytic calculations and performed the numerical simulations. Both F.M and S.A. authors contributed to the final version of the manuscript. S.A. supervised the project.

Competing interests

The authors declare no competing interests.

Footnotes

Publisher's note

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Supplementary Information

The online version contains supplementary material available at 10.1038/s41598-022-11146-3.

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