Skip to main content
NCBI home page
ACS AuthorChoice logoLink to ACS AuthorChoice
. 2022 Jul 11;14(28):32157–32165. doi: 10.1021/acsami.2c09129

Engineering the Interfacial Microenvironment via Surface Hydroxylation to Realize the Global Optimization of Electrochemical CO2 Reduction

Xu Han †, Ting Zhang †,‡, Martí Biset-Peiró ‡, Xuan Zhang §, Jian Li ∥,*, Weiqiang Tang ⊥,*, Pengyi Tang #, Joan Ramon Morante ‡,, Jordi Arbiol †,∇,*
PMCID: PMC9305709  PMID: 35815662

Abstract

graphic file with name am2c09129_0007.jpg

The adsorption and activation of CO2 on the electrode interface is a prerequisite and key step for electrocatalytic CO2 reduction reaction (eCO2 RR). Regulating the interfacial microenvironment to promote the adsorption and activation of CO2 is thus of great significance to optimize overall conversion efficiency. Herein, a CO2-philic hydroxyl coordinated ZnO (ZnO–OH) catalyst is fabricated, for the first time, via a facile MOF-assisted method. In comparison to the commercial ZnO, the as-prepared ZnO–OH exhibits much higher selectivity toward CO at lower applied potential, reaching a Faradaic efficiency of 85% at −0.95 V versus RHE. To the best of our knowledge, such selectivity is one of the best records in ZnO-based catalysts reported till date. Density functional theory calculations reveal that the coordinated surficial −OH groups are not only favorable to interact with CO2 molecules but also function in synergy to decrease the energy barrier of the rate-determining step and maintain a higher charge density of potential active sites as well as inhibit undesired hydrogen evolution reaction. Our results indicate that engineering the interfacial microenvironment through the introduction of CO2-philic groups is a promising way to achieve the global optimization of eCO2 RR via promoting adsorption and activation of CO2.

Keywords: ZnO, surficial hydroxyls, CO2 adsorption, CO2 activation, metal−organic frameworks (MOFs)

1. Introduction

The electrochemical CO2 reduction reaction (eCO2 RR) into various fuels and value-added chemicals is a promising method to eliminate excessive greenhouse gas and realize energy reuse toward carbon recycling.1−4 Considering the products of eCO2 RR, carbon monoxide (CO), an important raw material for top-level organic chemical products, has high industrial value.5−7 Theoretically, CO2-to-CO conversion goes through the following steps: (1) adsorption of CO2 and activation through a proton-coupled electron transfer process to generate COOH* intermediates; (2) the adsorbed COOH* intermediate is further reduced to form CO* and water; and (3) CO* is desorbed from the surface of the catalyst to form the CO product.8−12 Due to the poor solubility of CO2 in the aqueous electrolyte, the transformation of CO2 from the gas feed to the surface of active sites is a minimum prerequisite for the follow-up steps of eCO2 RR, thus limiting the overall conversion efficiency.13,14

Zinc oxide (ZnO), characterized by its huge reserves and for being cost-friendly, has been widely investigated for generating CO with moderate selectivity.15−21 The oxidation state of Zn in ZnO as a clear active site provides infinite possibilities to enhance the eCO2 RR efficiency.18−21 For example, an increased number of active sites could be induced by modulating the ZnO morphology to expose abundant edge facets;17 the ratio of H2/CO obtained on ZnO electrocatalysts could be tuned through controlling the defects and facets.19 However, almost no attention has been paid to the interfacial microenvironment between ZnO catalysts and CO2, a key factor to affect its adsorption and activation. Generally, the adsorption and activation of non-polar CO2 occur only at the interface of the solid electrocatalyst with the liquid electrolyte and CO2 molecules by weak interactions.11,22−25

Introducing carbon dioxide-philic functional groups, which have strong interaction with CO2 molecules, is an appealing route to manipulate the interface to enhance CO2 affinities.11,26−30 It is also anticipated that the CO2-philic functional groups on the surface could modulate the electronic structure of the catalyst to further manipulate the formation of the sequent intermediates in the CO2-to-CO conversion.11,29 With this in mind, −OH groups, a kind of CO2-philic functional groups, for the first time, were introduced on the surface of ZnO catalysts (ZnO–OH) via a simple ZIF-8-assisted (ZIF stands for zeolitic imidazolate frameworks) method. Compared to the commercial ZnO, the ZnO–OH exhibited much higher selectivity toward CO at a relatively lower applied potential and reached a FECO maximum of 85% at −0.95 V versus RHE, which is one of the best values among ZnO-based catalysts reported till date (see Table S4). Density functional theory (DFT) calculations indicated the existence of strong attraction between the ZnO–OH and the CO2 molecule, which is beneficial to the adsorption of CO2. Furthermore, the hydroxyl groups play an important role in facilitating the formation of the follow-up intermediates (COOH* and CO*), simultaneously limiting the undesired hydrogen evolution reaction (HER). All the results reveal the crucial role of CO2-philic −OH groups in promoting the interfacial adsorption and activation of CO2 to realize the global optimization of CO2 electroreduction, which benefits the understanding of the relevant mechanism in eCO2 RR and rational design of future high-efficient electrocatalysts.

2. Experimental Section

2.1. Chemicals

If not specified, all chemical reagents were obtained from Sigma-Aldrich and used directly. Zinc nitrate hexahydrate [Zn(NO3)2·6H2O], 2-methylimidazole (2-mim), commercial zinc oxide (ZnO), ethanol, and sodium bicarbonate (NaHCO3) were all of analytical grade. The Nafion membrane (N-117, 0.18 mm thick) and carbon paper were obtained from Alfa Aesar.

2.2. Material Preparation

2.2.1. Preparation of ZIF-8

The fabrication process of ZIF-8 is similar to the process reported in the literature.31 50 mL of methanol aqueous solution containing 2-mim (1.230 g) was added into the methanol aqueous solution of Zn(NO3)2·6H2O (50 mL, 1.115 g) with magnetic stirring to form homogeneous solution. After 24 h reaction without stirring at room temperature, the white solid was then taken out, washed by methanol several times, and vacuum dried overnight.

2.2.2. Preparation of Zn5(OH)8(NO3)2(H2O)2

100 mg of ZIF-8 was etched by immersing into an ethanol solution (100 mL) containing 0.5 g of Zn(NO3)2·6H2O with stirring for 30 min. The obtained Zn5(OH)8(NO3)2(H2O)2 sample was then taken out, washed with ethanol, and dried in vacuum oven overnight.

2.2.3. Preparation of ZnO–OH

The as-prepared Zn5(OH)8(NO3)2(H2O)2 powders were put at the porcelain boat. Subsequently, the samples were placed in a tube furnace and heated at 400 °C in air for 90 min to yield ZnO–OH (10 °C/min). Similarly, L-ZnO-OH and H–ZnO–OH were prepared by pyrolysis of Zn5(OH)8(NO3)2(H2O)2 that were treated by 0.4 or 0.6 g Zn(NO3)2·6H2O, respectively.

2.2.4. Preparation of D–ZnO

The as-prepared ZIF-8 powders were put at the porcelain boat with a direct pyrolysis at 400 °C for 90 min to yield D–ZnO.

2.3. Ink Preparation

5 mg of the powder sample and 100 μL of Nafion solutions (5 wt %) were dissolved in 1 mL of ethanol under ultrasonication to form a homogeneous solution. 500 μL of the above inks were dropped onto the surface of the carbon paper (1 × 1 cm2). The loading mass of the catalyst was determined as ∼3 mg/cm2.

2.4. Electrochemical Characterization

The electrocatalytic performance was characterized in a three-electrode H-type cell system with two-compartments separated by a Nafion N-117 membrane, including a reference electrode (Ag/AgCl electrode), a counter electrode (Pt plate), and a working electrode (catalyst-loaded carbon paper). All potentials were referred to the RHE with ERHE = E0Ag/AgCl + EAg/AgCl + 0.059 × pH.32,33 A BioLogic VMP3 electrochemical workstation was used to perform electrochemical experiments.

During electrochemical CO2 reduction experiments, the CO2 gas was delivered with a rate of 20 mL min–1 into the cell, and gas chromatography was used to test the final gas phase composition every 20 min. Meanwhile, we collected data three times to get an average value.

3. Results and Discussion

3.1. Characterization of the Sample

In order to understand the influence of the −OH group on the CO2 adsorption, DFT was first used to calculate the free energy of CO2 adsorption on two representative models for ZnO and ZnO–OH (Figure S1). Compared to the negligible adsorption Gibbs free energy of CO2 molecule on the pristine ZnO (−0.0028 eV), a much larger adsorption energy of −0.1466 eV was observed on ZnO–OH, revealing that the CO2 adsorption on the ZnO–OH is more feasible. The increase in the CO2 adsorption affinity is beneficial for the following eCO2 RR and, in parallel, inhibits the reduction of protons (hydrogen evolution) in the electrolyte.26,29

With the guidance of above DFT calculations, ZnO with rich surficial −OH was synthesized via a novel MOF-assisted procedure (Figure 1a). In brief, ZIF-8 as a precursor was first transformed into a hydroxide intermediate by virtue of adding a given amount of Zn(NO3)2 solution at room temperature. Afterward, the ZnO with rich surficial −OH (ZnO–OH) was obtained through pyrolysis of the above hydroxide intermediate under air. The high crystallinity of the as-prepared ZIF-8 and the corresponding hydroxide intermediate were first confirmed by powder X-ray diffraction (XRD) measurements. The ZIF-8 samples exhibited similar crystal patterns as expected for the standard ZIF-8 structure (Figure S2a).31,34 In the case of the hydroxide intermediate sample, new diffraction peaks belonging to the Zn5(OH)8(NO3)2(H2O)2 phase appeared, indicating that the treatment changed the crystal structure of the pristine ZIF-8 (Figure S2b).35,36 Field emission scanning electron microscopy revealed that sheet-shaped nanostructures were formed for the Zn5(OH)8(NO3)2(H2O)2 sample, different from the characteristic rhombic dodecahedral morphology of the ZIF-8 sample (Figures 1b,c and S3). Elemental composition maps indicated the existence of an additional O signal in the Zn5(OH)8(NO3)2(H2O)2 sample (Figures S4 and S5), while high-resolution TEM (HRTEM) analyses (Figure S6) further proved that ZIF-8 successfully transformed into the Zn5(OH)8(NO3)2(H2O)2 structure.

Figure 1.

Figure 1

Open in a new tab

(a) Schematic illustration for the formation process of the ZnO–OH. SEM image of (b) ZIF-8, (c) Zn5(OH)8(NO3)2(H2O)2 and (d) ZnO–OH.

In order to clarify the uniqueness of the ZnO–OH obtained by our method, a reference D–ZnO sample was synthesized through direct pyrolysis under air of an as-prepared ZIF-8 sample without Zn(NO3)2 treatment. Meanwhile, commercial ZnO was also used as a reference sample and was labeled as C–ZnO. As shown in Figure 2a, all samples clearly showed a similar diffraction pattern with that of simulated ZnO, indicating the successful synthesis of the ZnO skeleton.18,19 To investigate the morphology and phase evolution processes, SEM and TEM images of the three ZnO-based samples were obtained (Figures 1d, 2 and S7–10). The as-prepared ZnO–OH and the corresponding ZnO-based samples exhibited similar quasi-spherical shapes with irregular sizes. HRTEM analyses showed that all the ZnO-based samples displayed the typical hexagonal wurtzite ZnO phase (space group = P63/mmc) with a = b = 3.2900 Å and c = 5.3000 Å.37−40 Electron energy loss spectroscopy (EELS) demonstrated the uniform distributions of Zn and O throughout all samples.

Figure 2.

Figure 2

Open in a new tab

(a) XRD patterns. (b) Bright field TEM images showing the morphology of the ZnO–OH sample. The inset corresponds to a magnified detail of the studied area; (c) HRTEM image (left) and corresponding magnified detail (middle) with the corresponding indexed fast Fourier transform spectrum (right); (d) high-angle annular dark field scanning transmission electron microscopy (HAADF STEM) image; (e) HAADF STEM image and representative EELS chemical composition maps obtained from the red squared area in the STEM micrograph. Individual maps obtained from the Zn L2,3-edges at 1020 eV (red), O K-edges at 532 eV (blue), and Zn–O composite map. Inset in (e) shows a 3D atomic supercell model of a ZnO nanoparticle (Zn and O atoms are represented in red and blue, respectively).

X-ray photoelectron spectroscopy (XPS) was used to characterize the chemical valence state and surface compositions of the different catalysts. Figure 3a shows the presence of C, O, and Zn elements in all samples. The Zn 2p XPS core level spectra for all samples can be deconvoluted into two peaks, corresponding to Zn 2p3/2 and Zn 2p1/2 centered at around 1021 and 1044 eV, respectively, which indicates the presence of Zn2+ in all samples (Figure 3b).19,31 The high-resolution XPS spectra obtained on the O 1s show three peaks in all three samples, corresponding to the typical metal–oxygen bond (Zn–O, 529.8 eV),18,19 oxygen vacancy (Ov, 531.0 eV),41 and −OH (531.7 eV),42−44 respectively (Figure 3c). It is worth noting that there is a significant signal enhancement of the corresponding −OH peak obtained on the ZnO–OH sample in comparison to the C–ZnO and D–ZnO, which is ascribed to the higher density of surficial −OH groups. The integral-area ratios of the peak of surficial −OH groups to the peak of oxygen vacancy were calculated to be 51.3, 2.1, and 1.3 for ZnO–OH, C–ZnO, and D–ZnO. In comparison to C–ZnO, the much stronger FTIR peaks at around 1500 and 3400 cm–1 for ZnO–OH (Figure S11), which are attributed to the O–H stretch mode,45 further confirmed the existence of large amount of −OH groups on the surface of ZnO–OH. All these observations demonstrated that the prepared ZnO–OH maintained the basic skeleton of ZnO with large amount of −OH groups on the surface. CO2 adsorption measurements on different samples were further performed to support the strong interaction between −OH groups and CO2 experimentally (Figure S12). The higher CO2 uptake is observed on ZnO–OH sample, with the order following ZnO–OH (15.44 m2/g) > D–ZnO (5.93 m2/g) > C–ZnO (1.64 m2/g). Such results demonstrated that the surface −OH groups of ZnO–OH promoted CO2 adsorption remarkably, consistent with the DFT results (Figure S1).

Figure 3.

Figure 3

Open in a new tab

(a) XPS survey spectra and (b) high-resolution XPS spectra of Zn 2p and (c) O 1s for ZnO–OH (top), C–ZnO (middle), and D–ZnO (bottom).

3.2. eCO2 RR Performance

Next, electrochemical CO2 RR performances of the different samples were evaluated in 0.5 M NaHCO3. All electrodes were pre-treated in an Ar-saturated electrolyte at −0.70 V versus RHE for 30 min to reach a stable current (Figure S13). The eCO2 RR performance on the ZnO–OH sample was first evaluated by linear sweep voltammetry in both Ar- and CO2-saturated electrolytes (Figure S14). A large increase in the current density observed on the ZnO–OH sample after replacement of an Ar atmosphere by CO2 suggested that CO2 was electrochemically reduced by the ZnO–OH sample.46,47 Meanwhile, no obvious redox peaks were observed in the CO2-saturated aqueous solution, which displayed that ZnO–OH tended to react with CO2 molecules instead of suffering from self-reduction.26Figure 4a summarizes the measured total current density for ZnO–OH, D–ZnO, and C–ZnO samples. Although ZnO–OH and C–ZnO showed similar total reduction current densities, ZnO–OH showed the highest selectivity toward CO in a potential range from −0.80 to −1.15 V versus RHE, reaching the maximum Faradaic efficiency (FE) (CO) (85%) at −0.95 V versus RHE (Figure 4b). To the best of our knowledge, such high selectivity for CO at a low applied potential is the best record in ZnO-based catalysts reported so far (Table S4). The largest potential-dependent CO partial current densities observed on ZnO–OH further demonstrated the excellent activity and selectivity toward CO (Figure 4c). A decreasing trend in FE (CO) for ZnO–OH and C–ZnO was observed when the potential shifted to more negative values, which mainly stems from the dominance of the H2 generation over the eCO2 RR (Figure 4d). This assumption was further confirmed by the potential-dependent H2 current densities for the different catalysts (Figure 4e). The intrinsic activity of the catalysts was disclosed by the electrochemical active surface area (ECSA).32 As shown in Figure S15, the Cdl of ZnO–OH, D–ZnO, and C–ZnO samples was 0.05, 0.07, and 0.02 μF cm–2, respectively, which indicated that the ECSA is not responsible for the activity of ZnO–OH. A similar phenomenon could be observed on the nitrogen adsorption–desorption isotherms and BET surface area (Figure S16). It is well known that those electrocatalysts with high specific surface area should endow the efficient exposure of electrocatalytic active sites, fast electrolyte penetration/diffusion, and free diffusion of intermediates.48,49 In our case, the specific surface area of the ZnO–OH was much lower than that of D–ZnO, which suggests that the intrinsic catalytic activity of ZnO–OH sample arise from the presence of surficial −OH groups instead of the specific surface area.

Figure 4.

Figure 4

Open in a new tab

Electrocatalytic performance tests for ZnO–OH, D–ZnO and C–ZnO. (a) Total current density at various potentials. (b) FE of CO. (c) Current density of CO and (d) FE of H2. (e) Current density of H2 on ZnO–OH, D–ZnO, and C–ZnO. (f) Stability test for the ZnO–OH catalyst at −0.95 V vs RHE.

To investigate the reaction kinetics on ZnO–OH during eCO2 RR, Tafel slopes derived from the static state current densities for CO were calculated. The C–ZnO samples exhibit a Tafel slope of 36 mV dec–1, close to 39 mV dec–1, indicating that the rate-determining step (RDS) of CO2 RR on C–ZnO powder corresponds to the initial proton-coupled electron transfer (Figure S17).50 The much lower Tafel slopes (30 mV dec–1) for the ZnO–OH catalyst indicated its remarkably improved kinetics toward CO conversion.51−55 In addition, the effects of ZnO–OH samples treated by different amounts of Zn(NO3)2 on the CO2 RR activity were also studied, which were denoted as L–ZnO–OH and H–ZnO–OH, respectively. Both the referential samples showed similar crystal patterns with simulated ZnO (Figure S18a) and morphology in comparison with spherical ZnO–OH (Figure S18b,c). However, the selectivity of L–ZnO–OH and H–ZnO–OH changed negatively (Figure S19), which is due to the decreased ratio between surficial −OH groups and oxygen vacancy (Figure S20).

To further investigate the stability of the ZnO–OH during the eCO2 RR, a 10 h stability measurement was conducted. A current density of ca. −8.2 mA cm–2 and a FE(CO) over 80% were maintained during the 10 h test (Figure 4f). After the stability test, TEM analyses were performed to reveal the morphology and phase changes on the ZnO–OH sample, as shown in Figure S21. EELS compositional maps demonstrate that most of the ZnO–OH areas showed a uniform distribution of Zn and O. HRTEM analyses showed the presence of some metallic Zn nanoparticles with hexagonal phase (space group = P63/mmc). The presence of reduced Zn nanostructure can explain the slight efficiency loss after the stability test, evidencing the competition in the metal oxides between self-reduction and CO2 reduction.26,56

3.3. DFT Calculations

The CO2 RR process for the ZnO and ZnO–OH models was studied by DFT calculations to illustrate the origin of the improved CO2 RR. The free-energy profiles at a potential of 0 V versus RHE for the three elementary steps and the two important intermediates (COOH* and CO*) in the CO2 RR process are shown in Figure 5a. The ΔG for the formation of COOH* over commercial ZnO and the ZnO–OH catalysts is −0.52 and −0.63 eV, respectively. The stronger stabilization of surface COOH* on the ZnO–OH could increase the selectivity for the desired product CO. Besides, the following dissociation of COOH* assisted by the proton-electron transfer to produce CO* and H2O is an endothermic and the RDS. To our excitement, ΔG increases by 1.72 and 1.5 eV on ZnO and ZnO–OH catalyst models, respectively, which means that the process of the CO* generation on the ZnO–OH slab is thermodynamically more favorable than that on the ZnO slab. As for the final step of CO desorption, the ΔG over the reference ZnO and the ZnO–OH catalyst is −0.59 and −0.26 eV, respectively. Such a relatively weak binding of CO* and above stronger stabilization of COOH* steer the electron and proton transfer to the formation of the CO product. Similar trends are also observed on the free-energy profiles at −0.95 V (vs RHE) (Figure 5b). The differential charge density for CO2, CO, and COOH* on the ZnO–OH and ZnO slabs was also calculated and is shown in Figure 5c–h. The charge accumulation and deficit between them and the corresponding surface were presented with yellow and cyan iso-surfaces. Through contrastive analysis, the charge density difference of CO on the ZnO–OH slab was more prominent than that on the ZnO slab. To summarize, the ZnO–OH slab stabilizes the key intermediates via electronic interactions, which in synergy leads to an enhanced CO selectivity. More importantly, the Gibbs free energy for the CO2 activation process on ZnO with two surficial −OH decreased by ca. 0.17 eV with respect to the ZnO with only one surficial −OH, which revealed that more surficial −OH coverage enhanced the adsorption of CO2 (Figure S22). These calculated results were in good agreement with the experimental observations that the ZnO–OH sample exhibited better selectivity for CO2 RR in comparison to the C–ZnO catalyst. Additionally, HER as a competing side reaction is also studied here (Figure S23). The stronger stability of H* on the surface could suppress HER effectively. It can be concluded that the HER is less active on ZnO–OH than that on the reference ZnO sample (−1.87 and −1.67 eV, respectively), suggesting that HER occurs more easily on ZnO without the surficial −OH coverage. Taken in all, the surface hydroxyls can not only facilitate the formation of COOH* and CO* via electronic interactions but also limit the undesired HER.

Figure 5.

Figure 5

Open in a new tab

DFT studies of CO2 RR. Free-energy profiles for the (a) CO2 RR to CO at 0 and (b) −0.95 V (vs RHE) on the simulated models. Charge density difference for CO2, CO, and *COOH adsorbed on a (c–e) ZnO slab and a (f–h) ZnO–OH slab. The gray, red, brown, and pink spheres represent Zn, O, C, and H atoms, respectively.

4. Conclusions

In summary, ZnO covered by surficial −OH groups was synthesized through a novel MOF-assisted method, which delicately optimize the interfacial microenvironment to promote the interfacial adsorption and activation of CO2. The synthesized −OH-rich ZnO presents a FECO maximum of 85% at −0.95 V versus RHE, which is one of the best records among the state-of-the-art ZnO-based catalysts. DFT calculations confirmed that the surface −OH first boosts the adsorption of CO2 at the interface and then promotes the generation of COOH* and CO* intermediates. Our findings revealed that tuning the interfacial microenvironment via the introduction of dioxide-philic functional groups is a promising way to achieve the global optimization via promotion of interfacial adsorption and activation of CO2, which paves a new way to rationally design future highly active electrocatalysts for eCO2 RR.

Acknowledgments

The authors acknowledge funding from Generalitat de Catalunya 2017 SGR 327 and 2017 SGR 1246. X.H., T.Z., J.R.M., and J.A. acknowledge funding from the projects (PID2020-116093RB-C42 and -C43), funded by MCIN/AEI/10.13039/501100011033/. ICN2 is supported by the Severo Ochoa program from Spanish MINECO (grant no. SEV-2017-0706). ICN2 and IREC are funded by the CERCA Programme/Generalitat de Catalunya. X.Z. acknowledges funding from FWO project (12ZV320N). Part of the present work has been performed in the framework of Universitat Autònoma de Barcelona Materials Science PhD program. X.H. thanks China Scholarship Council for scholarship support (201804910551).

Supporting Information Available

The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsami.2c09129.

  • Additional characterizations, DFT results, and electrocatalytic testing curves (PDF)

Author Contributions

○ X.H. and T.Z. contributed equally to this paper.

The authors declare no competing financial interest.

Supplementary Material

am2c09129_si_001.pdf (5MB, pdf)

References

  1. Jin S.; Hao Z.; Zhang K.; Yan Z.; Chen J. Advances and Challenges for the Electrochemical Reduction of CO2 to CO: From Fundamentals to Industrialization. Angew. Chem., Int. Ed. 2021, 60, 20627–20648. 10.1002/anie.202101818. [DOI] [PubMed] [Google Scholar]
  2. Zhong M.; Tran K.; Min Y.; Wang C.; Wang Z.; Dinh C.-T.; De Luna P.; Yu Z.; Rasouli A. S.; Brodersen P.; Sun S.; Voznyy O.; Tan C.-S.; Askerka M.; Che F.; Liu M.; Seifitokaldani A.; Pang Y.; Lo S.-C.; Ip A.; Ulissi Z.; Sargent E. H. Accelerated Discovery of CO2 Electrocatalysts Using Active Machine Learning. Nature 2020, 581, 178–183. 10.1038/s41586-020-2242-8. [DOI] [PubMed] [Google Scholar]
  3. Yang B.; Liu K.; Li H.; Liu C.; Fu J.; Li H.; Huang J. E.; Ou P.; Alkayyali T.; Cai C.; Duan Y.; Liu H.; An P.; Zhang N.; Li W.; Qiu X.; Jia C.; Hu J.; Chai L.; Lin Z.; Gao Y.; Miyauchi M.; Cortés E.; Maier S. A.; Liu M. Accelerating CO2 Electroreduction to Multicarbon Products via Synergistic Electric–Thermal Field on Copper Nanoneedles. J. Am. Chem. Soc. 2022, 144, 3039–3049. 10.1021/jacs.1c11253. [DOI] [PubMed] [Google Scholar]
  4. Li H.; Zhou H.; Zhou Y.; Hu J.; Miyauchi M.; Fu J.; Liu M. Electric-Field Promoted C–C Coupling over Cu Nanoneedles for CO2 Electroreduction to C2 Products. Chin. J. Catal. 2022, 43, 519–525. 10.1016/s1872-2067(21)63866-4. [DOI] [Google Scholar]
  5. Guo Q.; Liang F.; Li X.-B.; Gao Y.-J.; Huang M.-Y.; Wang Y.; Xia S.-G.; Gao X.-Y.; Gan Q.-C.; Lin Z.-S.; Tung C.-H.; Wu L.-Z. Efficient and Selective CO2 Reduction Integrated with Organic Synthesis by Solar Energy. Chem 2019, 5, 2605–2616. 10.1016/j.chempr.2019.06.019. [DOI] [Google Scholar]
  6. Yuan X.; Wu Y.; Jiang B.; Wu Z.; Tao Z.; Lu X.; Liu J.; Qian T.; Lin H.; Zhang Q. Interface Engineering of Silver-Based Heterostructures for CO2 Reduction Reaction. ACS Appl. Mater. Interfaces 2020, 12, 56642–56649. 10.1021/acsami.0c19031. [DOI] [PubMed] [Google Scholar]
  7. Navarro R. M.; Peña M. A.; Fierro J. L. G. Hydrogen Production Reactions from Carbon Feedstocks: Fossil Fuels and Biomass. Chem. Rev. 2007, 107, 3952–3991. 10.1021/cr0501994. [DOI] [PubMed] [Google Scholar]
  8. Rosen B. A.; Salehi-Khojin A.; Thorson M. R.; Zhu W.; Whipple D. T.; Kenis P. J. A.; Masel R. I. Ionic Liquid-Mediated Selective Conversion of CO2 to CO at Low Overpotentials. Science 2011, 334, 643–644. 10.1126/science.1209786. [DOI] [PubMed] [Google Scholar]
  9. Zhu D. D.; Liu J. L.; Qiao S. Z. Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide. Adv. Mater. 2016, 28, 3423–3452. 10.1002/adma.201504766. [DOI] [PubMed] [Google Scholar]
  10. Zhang W.; Hu Y.; Ma L.; Zhu G.; Wang Y.; Xue X.; Chen R.; Yang S.; Jin Z. Progress and Perspective of Electrocatalytic CO2 Reduction for Renewable Carbonaceous Fuels and Chemicals. Adv. Sci. 2018, 5, 1700275. 10.1002/advs.201700275. [DOI] [PMC free article] [PubMed] [Google Scholar]
  11. Huang Q.; Li Q.; Liu J.; Wang Y. R.; Wang R.; Dong L. Z.; Xia Y. H.; Wang J. L.; Lan Y.-Q. Disclosing CO2 Activation Mechanism by Hydroxyl-Induced Crystalline Structure Transformation in Electrocatalytic Process. Matter 2019, 1, 1656–1668. 10.1016/j.matt.2019.07.003. [DOI] [Google Scholar]
  12. Zhang X.; Zhou Y.; Zhang H.; Li H.; Liu K.; Li H.; Pan H.; Hu J.; Fu J.; Chen S.; Liu M. Tuning the Electron Structure Enables the Nizn Alloy for CO2 Electroreduction to Formate. J. Energy Chem. 2021, 63, 625–632. 10.1016/j.jechem.2021.08.060. [DOI] [Google Scholar]
  13. Xu S.; Carter E. A. Theoretical Insights into Heterogeneous (Photo)electrochemical CO2 Reduction. Chem. Rev. 2019, 119, 6631–6669. 10.1021/acs.chemrev.8b00481. [DOI] [PubMed] [Google Scholar]
  14. Zhao K.; Quan X. Carbon-Based Materials for Electrochemical Reduction of CO2 to C2+ Oxygenates: Recent Progress and Remaining Challenges. ACS Catal. 2021, 11, 2076–2097. 10.1021/acscatal.0c04714. [DOI] [Google Scholar]
  15. Tan D.; Lee W.; Kim Y. E.; Ko Y. N.; Youn M. H.; Jeon Y. E.; Hong J.; Jeong S. K.; Park K. T. SnO2/ZnO Composite Hollow Nanofiber Electrocatalyst for Efficient CO2 Reduction to Formate. ACS Sustain. Chem. Eng. 2020, 8, 10639–10645. 10.1021/acssuschemeng.0c03481. [DOI] [Google Scholar]
  16. Nguyen D. L. T.; Jee M. S.; Won D. H.; Jung H.; Oh H.-S.; Min B. K.; Hwang Y. J. Selective CO2 Reduction on Zinc Electrocatalyst: The Effect of Zinc Oxidation State Induced by Pretreatment Environment. ACS Sustain. Chem. Eng. 2017, 5, 11377–11386. 10.1021/acssuschemeng.7b02460. [DOI] [Google Scholar]
  17. Xiang Q.; Li F.; Wang J.; Chen W.; Miao Q.; Zhang Q.; Tao P.; Song C.; Shang W.; Zhu H.; Deng T.; Wu J. Heterostructure of ZnO Nanosheets/Zn with a Highly Enhanced Edge Surface for Efficient CO2 Electrochemical Reduction to CO. ACS Appl. Mater. Interfaces 2021, 13, 10837–10844. 10.1021/acsami.0c20302. [DOI] [PubMed] [Google Scholar]
  18. Geng Z.; Kong X.; Chen W.; Su H.; Liu Y.; Cai F.; Wang G.; Zeng J. Oxygen Vacancies in ZnO Nanosheets Enhance CO2 Electrochemical Reduction to CO. Angew. Chem., Int. Ed. 2018, 57, 6054–6059. 10.1002/anie.201711255. [DOI] [PubMed] [Google Scholar]
  19. Daiyan R.; Lovell E. C.; Huang B.; Zubair M.; Leverett J.; Zhang Q.; Lim S.; Horlyck J.; Tang J.; Lu X.; Kalantar-Zadeh K.; Hart J. N.; Bedford N. M.; Amal R. Uncovering Atomic-Scale Stability and Reactivity in Engineered Zinc Oxide Electrocatalysts for Controllable Syngas Production. Adv. Energy Mater. 2020, 10, 2001381. 10.1002/aenm.202001381. [DOI] [Google Scholar]
  20. Franco F.; Rettenmaier C.; Jeon H. S.; Roldan Cuenya B. Transition Metal-Based Catalysts for the Electrochemical CO2 Reduction: From Atoms and Molecules to Nanostructured Materials. Chem. Soc. Rev. 2020, 49, 6884–6946. 10.1039/d0cs00835d. [DOI] [PubMed] [Google Scholar]
  21. Liu Y.; Yu L.; Hu Y.; Guo C.; Zhang F.; Lou X. W. A Magnetically Separable Photocatalyst Based on Nest-Like γ-Fe2O3/ZnO Double-Shelled Hollow Structures with Enhanced Photocatalytic Activity. Nanoscale 2012, 4, 183–187. 10.1039/c1nr11114k. [DOI] [PubMed] [Google Scholar]
  22. Resasco J.; Chen L. D.; Clark E.; Tsai C.; Hahn C.; Jaramillo T. F.; Chan K.; Bell A. T. Promoter Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon Dioxide. J. Am. Chem. Soc. 2017, 139, 11277–11287. 10.1021/jacs.7b06765. [DOI] [PubMed] [Google Scholar]
  23. Resasco J.; Lum Y.; Clark E.; Zeledon J. Z.; Bell A. T. Effects of Anion Identity and Concentration on Electrochemical Reduction of CO2. ChemElectroChem 2018, 5, 1064–1072. 10.1002/celc.201701316. [DOI] [Google Scholar]
  24. Liu P.; Zheng N. Coordination Chemistry of Atomically Dispersed Catalysts. Natl. Sci. Rev. 2018, 5, 636–638. 10.1093/nsr/nwy051. [DOI] [Google Scholar]
  25. Wang Q.; Liu K.; Fu J.; Cai C.; Li H.; Long Y.; Chen S.; Liu B.; Li H.; Li W.; Qiu X.; Zhang N.; Hu J.; Pan H.; Liu M. Atomically Dispersed s-Block Magnesium Sites for Electroreduction of CO2 to CO. Angew. Chem., Int. Ed. 2021, 60, 25241–25245. 10.1002/anie.202109329. [DOI] [PubMed] [Google Scholar]
  26. Deng W.; Zhang L.; Li L.; Chen S.; Hu C.; Zhao Z.-J.; Wang T.; Gong J. Crucial Role of Surface Hydroxyls on the Activity and Stability in Electrochemical CO2 Reduction. J. Am. Chem. Soc. 2019, 141, 2911–2915. 10.1021/jacs.8b13786. [DOI] [PubMed] [Google Scholar]
  27. Yang P.; Zhao Z.-J.; Chang X.; Mu R.; Zha S.; Zhang G.; Gong J. The Functionality of Surface Hydroxy Groups on the Selectivity and Activity of Carbon Dioxide Reduction over Cuprous Oxide in Aqueous Solutions. Angew. Chem., Int. Ed. 2018, 57, 7724–7728. 10.1002/anie.201801463. [DOI] [PubMed] [Google Scholar]
  28. Peng Y.; Wang L.; Luo Q.; Cao Y.; Dai Y.; Li Z.; Li H.; Zheng X.; Yan W.; Yang J.; Zeng J. Molecular-Level Insight into How Hydroxyl Groups Boost Catalytic Activity in CO2 Hydrogenation into Methanol. Chem 2018, 4, 613–625. 10.1016/j.chempr.2018.01.019. [DOI] [Google Scholar]
  29. Cui C.; Han J.; Zhu X.; Liu X.; Wang H.; Mei D.; Ge Q. Promotional Effect of Surface Hydroxyls on Electrochemical Reduction of CO2 over Snox/Sn Electrode. J. Catal. 2016, 343, 257–265. 10.1016/j.jcat.2015.12.001. [DOI] [Google Scholar]
  30. Yao D.; Tang C.; Vasileff A.; Zhi X.; Jiao Y.; Qiao S. Z. The Controllable Reconstruction of Bi-MOFs for Electrochemical CO2 Reduction through Electrolyte and Potential Mediation. Angew. Chem., Int. Ed. 2021, 60, 18178–18184. 10.1002/anie.202104747. [DOI] [PubMed] [Google Scholar]
  31. Dou S.; Song J.; Xi S.; Du Y.; Wang J.; Huang Z. F.; Xu Z. J.; Wang X. Boosting Electrochemical CO2 Reduction on Metal–Organic Frameworks via Ligand Doping. Angew. Chem., Int. Ed. 2019, 58, 4041–4045. 10.1002/anie.201814711. [DOI] [PubMed] [Google Scholar]
  32. Zhang T.; Du J.; Xi P.; Xu C. Hybrids of Cobalt/Iron Phosphides Derived from Bimetal–Organic Frameworks as Highly Efficient Electrocatalysts for Oxygen Evolution Reaction. ACS Appl. Mater. Interfaces 2017, 9, 362–370. 10.1021/acsami.6b12189. [DOI] [PubMed] [Google Scholar]
  33. Zhang T.; Han X.; Liu H.; Biset-Peiró M.; Li J.; Zhang X.; Tang P.; Yang B.; Zheng L.; Morante J. R.; Arbiol J. Site-Specific Axial Oxygen Coordinated FeN4 Active Sites for Highly Selective Electroreduction of Carbon Dioxide. Adv. Funct. Mater. 2022, 32, 2111446. 10.1002/adfm.202111446. [DOI] [Google Scholar]
  34. Saliba D.; Ammar M.; Rammal M.; Al-Ghoul M.; Hmadeh M. Crystal Growth of ZIF-8, ZIF-67, and Their Mixed-Metal Derivatives. J. Am. Chem. Soc. 2018, 140, 1812–1823. 10.1021/jacs.7b11589. [DOI] [PubMed] [Google Scholar]
  35. Schwenzer B.; Pop L. Z.; Neilson J. R.; Sbardellati T. B.; Morse D. E. Nanostructured ZnS and CdS Films Synthesized Using Layered Double Hydroxide Films as Precursor and Template. Inorg. Chem. 2009, 48, 1542–1550. 10.1021/ic801865w. [DOI] [PubMed] [Google Scholar]
  36. Shinagawa T.; Watanabe M.; Mori T.; Tani J.-i.; Chigane M.; Izaki M. Oriented Transformation from Layered Zinc Hydroxides to Nanoporous ZnO: A Comparative Study of Different Anion Types. Inorg. Chem. 2018, 57, 13137–13149. 10.1021/acs.inorgchem.8b01242. [DOI] [PubMed] [Google Scholar]
  37. Utama M. I. B.; Belarre F. J.; Magen C.; Peng B.; Arbiol J.; Xiong Q. Incommensurate van der Waals Epitaxy of Nanowire Arrays: A Case Study with ZnO on Muscovite Mica Substrates. Nano Lett. 2012, 12, 2146–2152. 10.1021/nl300554t. [DOI] [PubMed] [Google Scholar]
  38. de la Mata M.; Magen C.; Gazquez J.; Utama M. I. B.; Heiss M.; Lopatin S.; Furtmayr F.; Fernández-Rojas C. J.; Peng B.; Morante J. R.; Rurali R.; Eickhoff M.; Fontcuberta i Morral A.; Xiong Q.; Arbiol J. Polarity Assignment in ZnTe, GaAs, ZnO, and GaN-AlN Nanowires from Direct Dumbbell Analysis. Nano Lett. 2012, 12, 2579–2586. 10.1021/nl300840q. [DOI] [PubMed] [Google Scholar]
  39. de la Mata M.; Zamani R. R.; Martí-Sánchez S.; Eickhoff M.; Xiong Q.; Fontcuberta i Morral A.; Caroff P.; Arbiol J. The Role of Polarity in Nonplanar Semiconductor Nanostructures. Nano Lett. 2019, 19, 3396–3408. 10.1021/acs.nanolett.9b00459. [DOI] [PubMed] [Google Scholar]
  40. Li J.; Slassi A.; Han X.; Cornil D.; Ha-Thi M. H.; Pino T.; Debecker D. P.; Colbeau-Justin C.; Arbiol J.; Cornil J.; Ghazzal M. N. Tuning the Electronic Bandgap of Graphdiyne by H-Substitution to Promote Interfacial Charge Carrier Separation for Enhanced Photocatalytic Hydrogen Production. Adv. Funct. Mater. 2021, 31, 2100994. 10.1002/adfm.202100994. [DOI] [Google Scholar]
  41. Lei F.; Sun Y.; Liu K.; Gao S.; Liang L.; Pan B.; Xie Y. Oxygen Vacancies Confined in Ultrathin Indium Oxide Porous Sheets for Promoted Visible-Light Water Splitting. J. Am. Chem. Soc. 2014, 136, 6826–6829. 10.1021/ja501866r. [DOI] [PubMed] [Google Scholar]
  42. Bang S.; Lee S.; Ko Y.; Park J.; Shin S.; Seo H.; Jeon H. Photocurrent Detection of Chemically Tuned Hierarchical ZnO Nanostructures Grown on Seed Layers Formed by Atomic Layer Deposition. Nanoscale Res. Lett. 2012, 7, 290. 10.1186/1556-276x-7-290. [DOI] [PMC free article] [PubMed] [Google Scholar]
  43. Kim Y. H.; Kim D. G.; Maduwu R. D.; Jin H. C.; Moon D. K.; Kim J. H. Organic Electrolytes Doped ZnO Layer as the Electron Transport Layer for Bulk Heterojunction Polymer Solar Cells. Sol. RRL 2018, 2, 1800086. 10.1002/solr.201800086. [DOI] [Google Scholar]
  44. Jiang L.; Li J.; Huang K.; Li S.; Wang Q.; Sun Z.; Mei T.; Wang J.; Zhang L.; Wang N.; Wang X. Low-Temperature and Solution-Processable Zinc Oxide Transistors for Transparent Electronics. ACS Omega 2017, 2, 8990–8996. 10.1021/acsomega.7b01420. [DOI] [PMC free article] [PubMed] [Google Scholar]
  45. Hu Z.-A.; Xie Y.-L.; Wang Y.-X.; Xie L.-J.; Fu G.-R.; Jin X.-Q.; Zhang Z.-Y.; Yang Y.-Y.; Wu H.-Y. Synthesis of α-Cobalt Hydroxides with Different Intercalated Anions and Effects of Intercalated Anions on Their Morphology, Basal Plane Spacing, and Capacitive Property. J. Phys. Chem. C 2009, 113, 12502–12508. 10.1021/jp8106809. [DOI] [Google Scholar]
  46. Liu S.; Yang H. B.; Hung S. F.; Ding J.; Cai W.; Liu L.; Gao J.; Li X.; Ren X.; Kuang Z.; Huang Y.; Zhang T.; Liu B. Elucidating the Electrocatalytic CO2 Reduction Reaction over a Model Single-Atom Nickel Catalyst. Angew. Chem., Int. Ed. 2020, 59, 798–803. 10.1002/anie.201911995. [DOI] [PubMed] [Google Scholar]
  47. Zhang T.; Han X.; Liu H.; Biset-Peiró M.; Zhang X.; Tan P.; Tang P.; Yang B.; Zheng L.; Morante J. R.; Arbiol J. Quasi-Double-Star Nickel and Iron Active Sites for High-Efficiency Carbon Dioxide Electroreduction. Energy Environ. Sci. 2021, 14, 4847–4857. 10.1039/d1ee01592c. [DOI] [Google Scholar]
  48. Ni W.; Xue Y.; Zang X.; Li C.; Wang H.; Yang Z.; Yan Y.-M. Fluorine Doped Cagelike Carbon Electrocatalyst: An Insight into the Structure-Enhanced CO Selectivity for CO2 Reduction at High Overpotential. ACS Nano 2020, 14, 2014–2023. 10.1021/acsnano.9b08528. [DOI] [PubMed] [Google Scholar]
  49. Liu Y.; Liu Z.; Lu N.; Preiss E.; Poyraz S.; Kim M. J.; Zhang X. Facile Synthesis of Polypyrrole Coated Copper Nanowires: A New Concept to Engineered Core–Shell Structures. Chem. Commun. 2012, 48, 2621–2623. 10.1039/c2cc16961d. [DOI] [PubMed] [Google Scholar]
  50. Dunwell M.; Luc W.; Yan Y.; Jiao F.; Xu B. Understanding Surface-Mediated Electrochemical Reactions: CO2 Reduction and Beyond. ACS Catal. 2018, 8, 8121–8129. 10.1021/acscatal.8b02181. [DOI] [Google Scholar]
  51. Zhao C.; Wang Y.; Li Z.; Chen W.; Xu Q.; He D.; Xi D.; Zhang Q.; Yuan T.; Qu Y.; Yang J.; Zhou F.; Yang Z.; Wang X.; Wang J.; Luo J.; Li Y.; Duan H.; Wu Y.; Li Y. Solid-Diffusion Synthesis of Single-Atom Catalysts Directly from Bulk Metal for Efficient CO2 Reduction. Joule 2019, 3, 584–594. 10.1016/j.joule.2018.11.008. [DOI] [Google Scholar]
  52. Li C. W.; Kanan M. W. CO2 Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu2O Films. J. Am. Chem. Soc. 2012, 134, 7231–7234. 10.1021/ja3010978. [DOI] [PubMed] [Google Scholar]
  53. Gu J.; Hsu C.-S.; Bai L.; Chen H. M.; Hu X. Atomically Dispersed Fe3+ Sites Catalyze Efficient CO2 Electroreduction to CO. Science 2019, 364, 1091–1094. 10.1126/science.aaw7515. [DOI] [PubMed] [Google Scholar]
  54. Chen K.; Cao M.; Ni G.; Chen S.; Liao H.; Zhu L.; Li H.; Fu J.; Hu J.; Cortés E.; Liu M. Nickel Polyphthalocyanine with Electronic Localization at the Nickel Site for Enhanced CO2 Reduction Reaction. Appl. Catal., B 2022, 306, 121093. 10.1016/j.apcatb.2022.121093. [DOI] [Google Scholar]
  55. Zhu L.; Lin Y.; Liu K.; Cortés E.; Li H.; Hu J.; Yamaguchi A.; Liu X.; Miyauchi M.; Fu J.; Liu M. Tuning the Intermediate Reaction Barriers by a CuPd Catalyst to Improve the Selectivity of CO2 Electroreduction to C2 Products. Chin. J. Catal. 2021, 42, 1500–1508. 10.1016/s1872-2067(20)63754-8. [DOI] [Google Scholar]
  56. Luo W.; Zhang Q.; Zhang J.; Moioli E.; Zhao K.; Züttel A. Electrochemical Reconstruction of ZnO for Selective Reduction of CO2 to CO. Appl. Catal., B 2020, 273, 119060. 10.1016/j.apcatb.2020.119060. [DOI] [Google Scholar]

Associated Data

This section collects any data citations, data availability statements, or supplementary materials included in this article.

Supplementary Materials

am2c09129_si_001.pdf (5MB, pdf)

Articles from ACS Applied Materials & Interfaces are provided here courtesy of American Chemical Society

RESOURCES