Bis[μ3-2-(pyridin-3-yl)acetato-κ3 O:O:O′]bis­[μ2-2-(pyridin-3-yl)acetato-κ2 O:O′]bis­[chlorido­(1,10-phenanthroline-κ2 N,N′)dysprosium(III)]

Yan Lin; Jian-Ping Yu

doi:10.1107/S2414314622002310

. 2022 Mar 31;7(Pt 3):x220231. doi: 10.1107/S2414314622002310

Bis[μ₃-2-(pyridin-3-yl)acetato-κ³ O:O:O′]bis[μ₂-2-(pyridin-3-yl)acetato-κ² O:O′]bis[chlorido(1,10-phenanthroline-κ² N,N′)dysprosium(III)]

Yan Lin ^a,^*, Jian-Ping Yu ^a

Editor: L Van Meervelt^b

PMCID: PMC9462020 PMID: 36339809

A novel Dy^III complex based on 3-pyridylacetic acid and 1,10-phenanthroline ligands shows a dinuclear structure.

Keywords: crystal structure

Abstract

The title Dy^III complex, [Dy₂(C₇H₆NO₂)₄Cl₂(C₁₂H₈N₂)₂] or [Dy₂(μ ₃-PAA)₄(Cl)₂(phen)₂] (PAA = 3-pyridylacetate, phen = 1,10-phenanthroline), obtained by reaction of Dy(ClO₄)₃, 3-pyridylacetic acid ligands and 1,10-phenanthroline, exhibits a dinuclear structure. Adjacent binuclear dimers are further connected via face-to-face π–π stacking interactions resulting in supramolecular chains along the c-axis direction.

Structure description

Coordination complexes composed of metal cations and organic ligands have received much attention because of their diverse structures and intriguing properties such as photoluminescence, magnetism, proton conduction and so on. Lanthanide ions are considered to be excellent metal ions for the construction of such systems because of their unique 4f electrons and can show remarkable photoluminescent, magnetic and catalytic properties. Among numerous ligands, pyridinecarboxylate ligands bearing O and N coordination atoms have attracted considerable interest and have proved to be a class of excellent bridging linkers in fabricating metal coordination complexes with appealing structures. The 3-pyridylacetate ligand (3-PAA), one of the most simple pyridinecarboxylate ligands, has attracted particular interest owing to its strong coordination and varied coordination modes, resulting in diverse structures with excellent properties. So far, coordination complexes constructed by the 3-PAA ligand have focused on transition-metal cations, but lanthanide complexes based on the 3-PAA ligand are still rare. Thus, in this work, we prepared the title compound [Dy₂(μ ₂-PAA)₄(Cl)₂(phen)₂] (1) (3-PAA = 3-pyridylacetate, phen = 1,10-phenanthroline), which displays a dinuclear structure.

The asymmetric unit of 1 (Fig. 1 ▸) consists of one crystallographically independent Dy^III ion, one Cl⁻ anion, two PAA ligands and one phen molecule. The Dy^III cation is eight-coordinated by five carboxylate oxygen atoms from four different PAA⁻ ligands, one Cl⁻ ion, and two nitrogen atoms from one chelating phen molecule. The Dy—O bond lengths range from 2.3069 (17) to 2.5170 (15) Å, and the Dy—N bond distances are 2.5386 (18) and 2.5516 (17)Å, which are similar to those in the complex [Zn(μ-L)(μ-dicl)Dy(NO₃)₂]·H₂O {L = N,N′-dimethyl-N,N′-bis(2-hydroxy-3-formyl-5-bromobenzyl, dicl = deprotonated diclofenac = 2-[(2,6-dichlorophenyl)amino] benzene acetate; Echenique-Errandonea et al., 2019 ▸}. The two PAA⁻ ligands exhibit two different coordination modes. One acts as a tridentate ligand with a μ ₂-η¹:η² mode, while the other serves as a bidentate ligand with a μ ₂-κO ³:κO ⁴ mode. It is worth emphasizing that the N atom of the PAA ligand is noncoordinating in 1. As shown in Fig. 2 ▸, two neighboring Dy^III ions are linked by four bridging carboxyl groups of four PAA⁻ ligands, forming the binuclear structure of 1, in which the nearest Dy⋯Dy separation is 3.8976 (19) Å. These adjacent binuclear dimers are further connected via face-to-face π–π stacking interactions involving the phenyl and pyridine rings of the phen ligands, the centroid-to-centroid distance being 3.6116 (10) Å, leading to the formation of supramolecular chains along the c-axis direction (Fig. 3 ▸). For background information on the lanthanide ions and the 3-pyridylacetic acid ligand, see: Chakraborty et al. (2021 ▸); Xin et al. (2019 ▸); Ma et al. (2020 ▸); Wang et al. (2011 ▸); Teo et al. (2009 ▸); Adams et al. (2006 ▸).

The asymmetric unit of 1 with 40% probability displacement ellipsoids. H atoms are omitted for clarity. Symmetry code: (A) 1 − x, 1 − y, 2 − z.

The dinuclear structure of 1. H atoms are omitted for clarity. Symmetry code: (A) 1 − x, 1 − y, 2 − z.

The supramolecular chain along the c-axis direction formed by face-to-face π–π stacking interactions.

Synthesis and crystallization

Dy(ClO₄)₃ (0.2 mmol), 3-pyridylacetic acid (3-PAA, 0.25 mmol), 1,10-phenanthroline (0.25 mmol), HCl (0.25mmol) and Et₃N were dissolved in 5 mL of acetonitrile and then sealed into a 25 mL Teflon-lined stainless steel vessel. The vessel was kept at 433 K for 3 d under autogenous pressure and then cooled to room temperature at a rate of 5.63 K h⁻¹. Colorless block-shaped crystals were obtained by filtration of the resulting solution. Yield based on Dy: 38%.

Refinement

Crystal data, data collection and structure refinement details are summarized in Table 1 ▸. The instruction "delu 0.002 0.001 C11 C12" was used during the refinement to limit the displacement parameters of the specified atoms.

Table 1. Experimental details.

Crystal data
Chemical formula	[Dy₂(C₇H₆NO₂)₄Cl₂(C₁₂H₈N₂)₂]
M _r	1300.82
Crystal system, space group	Monoclinic, P2₁/c
Temperature (K)	296
a, b, c (Å)	8.8922 (1), 21.5425 (3), 12.9887 (1)
β (°)	101.755 (1)
V (Å³)	2435.94 (5)
Z	2
Radiation type	Mo Kα
μ (mm⁻¹)	3.22
Crystal size (mm)	0.22 × 0.20 × 0.19

Data collection
Diffractometer	Bruker SAINT CCD area detector
Absorption correction	Multi-scan (SADABS; Bruker, 2008 ▸)
T _min, T _max	0.626, 0.746
No. of measured, independent and observed [I > 2σ(I)] reflections	16420, 4487, 3954
R _int	0.024
(sin θ/λ)_max (Å⁻¹)	0.606

Refinement
R[F ² > 2σ(F ²)], wR(F ²), S	0.021, 0.056, 1.01
No. of reflections	4487
No. of parameters	325
No. of restraints	1
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.59, −0.34

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Computer programs: SMART and SAINT (Bruker, 2008 ▸), SHELXS97 (Sheldrick, 2008 ▸), and SHELXTL (Sheldrick, 2008 ▸).

Supplementary Material

Crystal structure: contains datablock(s) I, New_Global_Publ_Block. DOI: 10.1107/S2414314622002310/vm4049sup1.cif

x-07-x220231-sup1.cif^{(22.2KB, cif)}

CCDC reference: 2155088

Additional supporting information: crystallographic information; 3D view; checkCIF report

full crystallographic data

Crystal data

[Dy₂(C₇H₆NO₂)₄Cl₂(C₁₂H₈N₂)₂]	F(000) = 1276
M_r = 1300.82	D_x = 1.773 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
a = 8.8922 (1) Å	Cell parameters from 7687 reflections
b = 21.5425 (3) Å	θ = 2.5–27.3°
c = 12.9887 (1) Å	µ = 3.22 mm⁻¹
β = 101.755 (1)°	T = 296 K
V = 2435.94 (5) Å³	Block, yellow
Z = 2	0.22 × 0.20 × 0.19 mm

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Data collection

Bruker SAINT CCD area detector diffractometer	4487 independent reflections
Radiation source: fine-focus sealed tube	3954 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.024
phi and ω scans	θ_max = 25.5°, θ_min = 1.9°
Absorption correction: multi-scan (SADABS; Bruker, 2008)	h = −10→10
T_min = 0.626, T_max = 0.746	k = −26→23
16420 measured reflections	l = −15→15

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Refinement

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.021	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.056	H-atom parameters constrained
S = 1.00	w = 1/[σ²(F_o²) + (0.035P)²] where P = (F_o² + 2F_c²)/3
4487 reflections	(Δ/σ)_max = 0.002
325 parameters	Δρ_max = 0.59 e Å⁻³
1 restraint	Δρ_min = −0.34 e Å⁻³

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Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. H atoms were placed in calculated positions with C—H = 0.93 Å in phenyl and pyridine rings while C–H = 0.97 Å in CH₂ groups and refined in riding mode with U_iso(H) = 1.2U_eq(C).

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Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²)

	x	y	z	U_iso*/U_eq
Dy1	0.387207 (12)	0.510416 (5)	0.855827 (7)	0.03127 (3)
Cl1	0.13833 (7)	0.58009 (3)	0.81071 (5)	0.05938 (19)
O3	0.57734 (18)	0.58550 (8)	0.90135 (12)	0.0487 (5)
N3	0.4153 (2)	0.55350 (10)	0.67882 (13)	0.0420 (5)
O1	0.57990 (18)	0.44419 (8)	0.80320 (11)	0.0472 (4)
N4	0.2364 (2)	0.45183 (9)	0.69718 (13)	0.0383 (5)
C7	0.6642 (3)	0.43988 (11)	0.89307 (17)	0.0365 (6)
C14	0.6799 (3)	0.60069 (12)	0.97945 (18)	0.0455 (6)
C18	0.3415 (3)	0.54877 (14)	0.48832 (18)	0.0544 (7)
C26	0.3341 (3)	0.52662 (12)	0.58975 (17)	0.0416 (6)
C25	0.2402 (3)	0.47369 (12)	0.59934 (17)	0.0420 (6)
C21	0.1571 (3)	0.44537 (15)	0.50734 (18)	0.0545 (8)
C6	0.8200 (3)	0.41057 (12)	0.90869 (18)	0.0441 (6)
H6A	0.8755	0.4280	0.8585	0.053*
H6B	0.8770	0.4202	0.9788	0.053*
C24	0.1525 (3)	0.40185 (12)	0.7037 (2)	0.0498 (7)
H24A	0.1480	0.3871	0.7702	0.060*
C5	0.8108 (3)	0.34153 (13)	0.8952 (2)	0.0476 (7)
C19	0.2538 (4)	0.51931 (16)	0.3983 (2)	0.0687 (10)
H19A	0.2583	0.5344	0.3319	0.082*
C22	0.0729 (3)	0.39253 (16)	0.5185 (2)	0.0696 (9)
H22A	0.0181	0.3724	0.4592	0.084*
C12	0.7310 (3)	0.69858 (12)	0.8813 (2)	0.0494 (7)
C8	0.7993 (3)	0.70351 (14)	0.7954 (2)	0.0662 (9)
H8A	0.8829	0.6781	0.7929	0.079*
C11	0.6079 (3)	0.73727 (15)	0.8813 (2)	0.0690 (9)
H11A	0.5574	0.7359	0.9374	0.083*
C23	0.0701 (3)	0.36993 (15)	0.6167 (2)	0.0657 (9)
H23A	0.0149	0.3343	0.6252	0.079*
N2	0.7518 (3)	0.74312 (14)	0.7148 (2)	0.0894 (9)
C17	0.4394 (4)	0.59840 (15)	0.4816 (2)	0.0658 (8)
H17A	0.4493	0.6133	0.4161	0.079*
C13	0.7883 (3)	0.65317 (14)	0.9671 (2)	0.0682 (9)
H13A	0.8129	0.6757	1.0331	0.082*
H13B	0.8831	0.6352	0.9547	0.082*
O2	0.61601 (17)	0.46036 (8)	0.97223 (11)	0.0421 (4)
O4	0.70410 (19)	0.57482 (8)	1.06850 (12)	0.0509 (5)
C15	0.5041 (3)	0.60095 (13)	0.6677 (2)	0.0565 (8)
H15A	0.5597	0.6197	0.7281	0.068*
C20	0.1653 (4)	0.47066 (18)	0.4064 (2)	0.0720 (10)
H20A	0.1078	0.4527	0.3458	0.086*
C16	0.5196 (4)	0.62483 (14)	0.5697 (2)	0.0690 (9)
H16A	0.5842	0.6583	0.5659	0.083*
C1	0.7804 (4)	0.30426 (16)	0.9734 (3)	0.0882 (12)
H1A	0.7679	0.3235	1.0352	0.106*
C10	0.5589 (4)	0.77733 (16)	0.8009 (3)	0.0875 (12)
H10A	0.4759	0.8035	0.8011	0.105*
C4	0.8326 (4)	0.31262 (18)	0.8051 (3)	0.0958 (12)
H4A	0.8526	0.3356	0.7487	0.115*
N1	0.7671 (5)	0.24248 (16)	0.9688 (3)	0.1415 (16)
C3	0.8239 (5)	0.2480 (2)	0.8001 (4)	0.1398 (18)
H3A	0.8416	0.2267	0.7413	0.168*
C9	0.6330 (5)	0.77806 (17)	0.7218 (3)	0.0939 (13)
H9A	0.5980	0.8055	0.6668	0.113*
C2	0.7889 (5)	0.2167 (2)	0.8833 (5)	0.140 (2)
H2A	0.7800	0.1738	0.8781	0.168*

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Atomic displacement parameters (Å²)

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Dy1	0.03380 (6)	0.03284 (7)	0.02427 (6)	0.00167 (4)	−0.00091 (4)	0.00130 (4)
Cl1	0.0556 (4)	0.0664 (4)	0.0473 (3)	0.0255 (3)	−0.0104 (3)	−0.0088 (3)
O3	0.0544 (10)	0.0502 (11)	0.0343 (8)	−0.0156 (8)	−0.0077 (7)	0.0103 (8)
N3	0.0500 (11)	0.0439 (12)	0.0303 (9)	0.0042 (10)	0.0043 (8)	0.0054 (8)
O1	0.0509 (9)	0.0605 (11)	0.0286 (8)	0.0160 (9)	0.0047 (7)	−0.0012 (7)
N4	0.0372 (10)	0.0439 (12)	0.0312 (9)	0.0055 (9)	0.0009 (8)	−0.0030 (8)
C7	0.0383 (12)	0.0338 (13)	0.0362 (12)	0.0016 (10)	0.0051 (10)	0.0017 (10)
C14	0.0493 (14)	0.0429 (15)	0.0403 (13)	−0.0087 (12)	−0.0003 (11)	0.0052 (11)
C18	0.0604 (16)	0.0681 (19)	0.0349 (13)	0.0217 (14)	0.0098 (11)	0.0097 (12)
C26	0.0482 (14)	0.0459 (15)	0.0290 (11)	0.0127 (12)	0.0041 (10)	0.0035 (10)
C25	0.0397 (13)	0.0538 (15)	0.0303 (12)	0.0140 (12)	0.0020 (10)	−0.0057 (11)
C21	0.0440 (14)	0.080 (2)	0.0353 (13)	0.0073 (14)	−0.0017 (11)	−0.0138 (13)
C6	0.0365 (12)	0.0509 (16)	0.0445 (13)	0.0049 (11)	0.0071 (10)	−0.0035 (11)
C24	0.0494 (14)	0.0535 (17)	0.0448 (14)	−0.0060 (13)	0.0053 (11)	−0.0079 (12)
C5	0.0319 (12)	0.0499 (16)	0.0566 (15)	0.0096 (11)	−0.0013 (11)	−0.0084 (12)
C19	0.078 (2)	0.095 (3)	0.0318 (14)	0.0236 (18)	0.0077 (14)	0.0053 (14)
C22	0.0583 (17)	0.097 (2)	0.0471 (15)	−0.0097 (18)	−0.0034 (13)	−0.0313 (16)
C12	0.0444 (13)	0.0429 (15)	0.0568 (15)	−0.0134 (10)	0.0005 (12)	0.0090 (12)
C8	0.0567 (17)	0.0577 (19)	0.086 (2)	−0.0059 (15)	0.0176 (16)	0.0155 (16)
C11	0.0628 (16)	0.067 (2)	0.078 (2)	−0.0037 (13)	0.0156 (16)	−0.0113 (17)
C23	0.0564 (16)	0.072 (2)	0.0648 (17)	−0.0175 (15)	0.0045 (14)	−0.0239 (15)
N2	0.101 (2)	0.090 (2)	0.0763 (17)	−0.0263 (18)	0.0171 (16)	0.0270 (16)
C17	0.0842 (19)	0.076 (2)	0.0398 (14)	0.0175 (18)	0.0187 (13)	0.0244 (14)
C13	0.0551 (16)	0.072 (2)	0.0658 (18)	−0.0288 (15)	−0.0150 (14)	0.0267 (15)
O2	0.0440 (9)	0.0520 (10)	0.0284 (8)	0.0135 (8)	0.0028 (7)	−0.0033 (7)
O4	0.0602 (11)	0.0502 (11)	0.0347 (8)	−0.0181 (9)	−0.0083 (8)	0.0070 (8)
C15	0.0703 (18)	0.0530 (17)	0.0455 (14)	−0.0066 (15)	0.0101 (13)	0.0103 (12)
C20	0.072 (2)	0.111 (3)	0.0272 (13)	0.016 (2)	−0.0040 (13)	−0.0135 (16)
C16	0.094 (2)	0.0609 (19)	0.0574 (17)	−0.0034 (17)	0.0266 (15)	0.0194 (14)
C1	0.128 (3)	0.057 (2)	0.065 (2)	−0.012 (2)	−0.016 (2)	0.0032 (17)
C10	0.069 (2)	0.051 (2)	0.129 (3)	0.0161 (17)	−0.011 (2)	0.004 (2)
C4	0.077 (2)	0.103 (3)	0.116 (3)	−0.003 (2)	0.041 (2)	−0.048 (2)
N1	0.183 (3)	0.057 (2)	0.146 (3)	−0.026 (2)	−0.057 (3)	0.026 (2)
C3	0.079 (2)	0.124 (3)	0.222 (4)	−0.001 (3)	0.044 (3)	−0.118 (3)
C9	0.103 (3)	0.060 (2)	0.100 (3)	−0.015 (2)	−0.025 (2)	0.026 (2)
C2	0.082 (3)	0.062 (3)	0.240 (6)	0.028 (2)	−0.052 (3)	−0.042 (3)

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Geometric parameters (Å, º)

Dy1—O4ⁱ	2.3069 (17)	C19—C20	1.327 (5)
Dy1—O3	2.3275 (16)	C19—H19A	0.9300
Dy1—O2ⁱ	2.3261 (14)	C22—C23	1.371 (4)
Dy1—O1	2.4323 (16)	C22—H22A	0.9300
Dy1—O2	2.5170 (15)	C12—C11	1.376 (4)
Dy1—N3	2.5386 (18)	C12—C8	1.378 (4)
Dy1—N4	2.5516 (17)	C12—C13	1.493 (4)
Dy1—Cl1	2.6392 (6)	C8—N2	1.350 (4)
Dy1—C7	2.850 (2)	C8—H8A	0.9300
Dy1—Dy1ⁱ	3.8976 (2)	C11—C10	1.356 (4)
O3—C14	1.261 (3)	C11—H11A	0.9300
N3—C15	1.317 (3)	C23—H23A	0.9300
N3—C26	1.362 (3)	N2—C9	1.315 (5)
O1—C7	1.256 (2)	C17—C16	1.346 (4)
N4—C24	1.323 (3)	C17—H17A	0.9300
N4—C25	1.362 (3)	C13—H13A	0.9700
C7—O2	1.271 (3)	C13—H13B	0.9700
C7—C6	1.498 (3)	O2—Dy1ⁱ	2.3261 (14)
C14—O4	1.262 (3)	O4—Dy1ⁱ	2.3069 (17)
C14—C13	1.515 (4)	C15—C16	1.405 (4)
C18—C19	1.417 (4)	C15—H15A	0.9300
C18—C26	1.415 (3)	C20—H20A	0.9300
C18—C17	1.393 (4)	C16—H16A	0.9300
C26—C25	1.434 (4)	C1—N1	1.336 (5)
C25—C21	1.409 (3)	C1—H1A	0.9300
C21—C22	1.386 (4)	C10—C9	1.329 (5)
C21—C20	1.435 (4)	C10—H10A	0.9300
C6—C5	1.498 (4)	C4—C3	1.395 (6)
C6—H6A	0.9700	C4—H4A	0.9300
C6—H6B	0.9700	N1—C2	1.291 (7)
C24—C23	1.396 (4)	C3—C2	1.362 (7)
C24—H24A	0.9300	C3—H3A	0.9300
C5—C1	1.364 (4)	C9—H9A	0.9300
C5—C4	1.374 (4)	C2—H2A	0.9300

O4ⁱ—Dy1—O3	138.19 (5)	C25—C21—C20	119.7 (3)
O4ⁱ—Dy1—O2ⁱ	74.46 (6)	C5—C6—C7	112.05 (19)
O3—Dy1—O2ⁱ	73.64 (6)	C5—C6—H6A	109.2
O4ⁱ—Dy1—O1	88.97 (6)	C7—C6—H6A	109.2
O3—Dy1—O1	87.84 (6)	C5—C6—H6B	109.2
O2ⁱ—Dy1—O1	125.15 (5)	C7—C6—H6B	109.2
O4ⁱ—Dy1—O2	73.42 (6)	H6A—C6—H6B	107.9
O3—Dy1—O2	71.86 (6)	N4—C24—C23	124.0 (3)
O2ⁱ—Dy1—O2	72.89 (6)	N4—C24—H24A	118.0
O1—Dy1—O2	52.27 (5)	C23—C24—H24A	118.0
O4ⁱ—Dy1—N3	141.73 (6)	C1—C5—C4	116.8 (3)
O3—Dy1—N3	77.03 (6)	C1—C5—C6	120.8 (3)
O2ⁱ—Dy1—N3	142.50 (7)	C4—C5—C6	122.4 (3)
O1—Dy1—N3	75.81 (6)	C20—C19—C18	121.6 (3)
O2—Dy1—N3	118.94 (6)	C20—C19—H19A	119.2
O4ⁱ—Dy1—N4	77.16 (6)	C18—C19—H19A	119.2
O3—Dy1—N4	141.62 (6)	C21—C22—C23	120.1 (3)
O2ⁱ—Dy1—N4	143.32 (6)	C21—C22—H22A	120.0
O1—Dy1—N4	76.54 (5)	C23—C22—H22A	120.0
O2—Dy1—N4	120.04 (6)	C11—C12—C8	115.8 (3)
N3—Dy1—N4	65.29 (6)	C11—C12—C13	123.2 (3)
O4ⁱ—Dy1—Cl1	101.26 (5)	C8—C12—C13	121.0 (3)
O3—Dy1—Cl1	101.19 (5)	N2—C8—C12	123.8 (3)
O2ⁱ—Dy1—Cl1	83.42 (4)	N2—C8—H8A	118.1
O1—Dy1—Cl1	151.41 (4)	C12—C8—H8A	118.1
O2—Dy1—Cl1	156.30 (4)	C12—C11—C10	121.0 (3)
N3—Dy1—Cl1	79.86 (5)	C12—C11—H11A	119.5
N4—Dy1—Cl1	79.81 (4)	C10—C11—H11A	119.5
O4ⁱ—Dy1—C7	82.55 (6)	C24—C23—C22	118.2 (3)
O3—Dy1—C7	76.68 (6)	C24—C23—H23A	120.9
O2ⁱ—Dy1—C7	99.24 (6)	C22—C23—H23A	120.9
O1—Dy1—C7	25.99 (5)	C9—N2—C8	115.9 (3)
O2—Dy1—C7	26.47 (5)	C16—C17—C18	120.1 (3)
N3—Dy1—C7	96.17 (6)	C16—C17—H17A	120.0
N4—Dy1—C7	99.62 (6)	C18—C17—H17A	120.0
Cl1—Dy1—C7	175.87 (5)	C12—C13—C14	116.1 (2)
O4ⁱ—Dy1—Dy1ⁱ	69.87 (4)	C12—C13—H13A	108.3
O3—Dy1—Dy1ⁱ	68.34 (4)	C14—C13—H13A	108.3
O2ⁱ—Dy1—Dy1ⁱ	38.11 (4)	C12—C13—H13B	108.3
O1—Dy1—Dy1ⁱ	87.04 (3)	C14—C13—H13B	108.3
O2—Dy1—Dy1ⁱ	34.78 (3)	H13A—C13—H13B	107.4
N3—Dy1—Dy1ⁱ	141.81 (4)	C7—O2—Dy1ⁱ	160.55 (14)
N4—Dy1—Dy1ⁱ	143.32 (4)	C7—O2—Dy1	91.55 (12)
Cl1—Dy1—Dy1ⁱ	121.533 (15)	Dy1ⁱ—O2—Dy1	107.11 (6)
C7—Dy1—Dy1ⁱ	61.17 (4)	C14—O4—Dy1ⁱ	137.13 (15)
C14—O3—Dy1	138.89 (15)	N3—C15—C16	123.7 (3)
C15—N3—C26	117.5 (2)	N3—C15—H15A	118.1
C15—N3—Dy1	123.72 (16)	C16—C15—H15A	118.1
C26—N3—Dy1	118.73 (16)	C19—C20—C21	120.9 (3)
C7—O1—Dy1	95.93 (14)	C19—C20—H20A	119.6
C24—N4—C25	117.5 (2)	C21—C20—H20A	119.6
C24—N4—Dy1	124.18 (15)	C17—C16—C15	118.9 (3)
C25—N4—Dy1	118.28 (15)	C17—C16—H16A	120.6
O1—C7—O2	119.4 (2)	C15—C16—H16A	120.6
O1—C7—C6	121.2 (2)	N1—C1—C5	125.6 (4)
O2—C7—C6	119.44 (19)	N1—C1—H1A	117.2
O1—C7—Dy1	58.08 (12)	C5—C1—H1A	117.2
O2—C7—Dy1	61.98 (11)	C9—C10—C11	118.1 (3)
C6—C7—Dy1	172.26 (17)	C9—C10—H10A	120.9
O4—C14—O3	125.6 (2)	C11—C10—H10A	120.9
O4—C14—C13	115.7 (2)	C5—C4—C3	118.4 (4)
O3—C14—C13	118.7 (2)	C5—C4—H4A	120.8
C19—C18—C26	119.7 (3)	C3—C4—H4A	120.8
C19—C18—C17	122.6 (3)	C2—N1—C1	116.0 (4)
C26—C18—C17	117.7 (2)	C2—C3—C4	118.4 (4)
N3—C26—C18	122.0 (2)	C2—C3—H3A	120.8
N3—C26—C25	118.8 (2)	C4—C3—H3A	120.8
C18—C26—C25	119.2 (2)	N2—C9—C10	125.3 (3)
N4—C25—C21	122.2 (2)	N2—C9—H9A	117.4
N4—C25—C26	118.8 (2)	C10—C9—H9A	117.4
C21—C25—C26	119.0 (2)	N1—C2—C3	124.7 (4)
C22—C21—C25	117.9 (2)	N1—C2—H2A	117.6
C22—C21—C20	122.4 (3)	C3—C2—H2A	117.6

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Symmetry code: (i) −x+1, −y+1, −z+2.

Funding Statement

We acknowledge financial support from the NSF of Jiangxi Provincial Education Department (No. GJJ190756).

References

Adams, C. J., Crawford, P. C., Guy Orpen, A. & Podesta, T. J. (2006). Dalton Trans. pp. 4078–4092. [DOI] [PubMed]
Bruker (2008). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Chakraborty, G., Park, I.-H., Medishetty, R. & Vittal, J. J. (2021). Chem. Rev. 121, 3751–3891. [DOI] [PubMed]
Echenique-Errandonea, E., Zabala-Lekuona, A., Cepeda, J., Rodríguez-Diéguez, A., Seco, J. M., Oyarzabal, I. & Colacio, E. (2019). Dalton Trans. 48, 190–201. [DOI] [PubMed]
Ma, Y. J., Hu, J. X., Han, S. D., Pan, J., Li, J. H. & Wang, G. M. (2020). J. Am. Chem. Soc. 142, 2682–2689. [DOI] [PubMed]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. [DOI] [PubMed]
Teo, P., Koh, L. L. & Hor, T. S. A. (2009). Dalton Trans. pp. 5637–5646. [DOI] [PubMed]
Wang, L., Yin, X. H., Hao, H. J., Lin, W., Tan, X. H. & Lin, C. W. (2011). Z. Kristallogr. New. Cryst. Struct. pp. 219–220.
Xin, Y., Wang, J. H., Zychowicz, M., Zakrzewski, J. J., Nakabayashi, K., Sieklucka, B., Chorazy, S. & Ohkoshi, S. (2019). J. Am. Chem. Soc. 141, 18211–18220. [DOI] [PubMed]

Associated Data

This section collects any data citations, data availability statements, or supplementary materials included in this article.

Supplementary Materials

Crystal structure: contains datablock(s) I, New_Global_Publ_Block. DOI: 10.1107/S2414314622002310/vm4049sup1.cif

x-07-x220231-sup1.cif^{(22.2KB, cif)}

CCDC reference: 2155088

Additional supporting information: crystallographic information; 3D view; checkCIF report

[bb1] Adams, C. J., Crawford, P. C., Guy Orpen, A. & Podesta, T. J. (2006). Dalton Trans. pp. 4078–4092. [DOI] [PubMed]

[bb2] Bruker (2008). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.

[bb3] Chakraborty, G., Park, I.-H., Medishetty, R. & Vittal, J. J. (2021). Chem. Rev. 121, 3751–3891. [DOI] [PubMed]

[bb4] Echenique-Errandonea, E., Zabala-Lekuona, A., Cepeda, J., Rodríguez-Diéguez, A., Seco, J. M., Oyarzabal, I. & Colacio, E. (2019). Dalton Trans. 48, 190–201. [DOI] [PubMed]

[bb5] Ma, Y. J., Hu, J. X., Han, S. D., Pan, J., Li, J. H. & Wang, G. M. (2020). J. Am. Chem. Soc. 142, 2682–2689. [DOI] [PubMed]

[bb6] Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. [DOI] [PubMed]

[bb7] Teo, P., Koh, L. L. & Hor, T. S. A. (2009). Dalton Trans. pp. 5637–5646. [DOI] [PubMed]

[bb8] Wang, L., Yin, X. H., Hao, H. J., Lin, W., Tan, X. H. & Lin, C. W. (2011). Z. Kristallogr. New. Cryst. Struct. pp. 219–220.

[bb9] Xin, Y., Wang, J. H., Zychowicz, M., Zakrzewski, J. J., Nakabayashi, K., Sieklucka, B., Chorazy, S. & Ohkoshi, S. (2019). J. Am. Chem. Soc. 141, 18211–18220. [DOI] [PubMed]

PERMALINK

Bis[μ₃-2-(pyridin-3-yl)acetato-κ³ O:O:O′]bis[μ₂-2-(pyridin-3-yl)acetato-κ² O:O′]bis[chlorido(1,10-phenanthroline-κ² N,N′)dysprosium(III)]

Yan Lin

Jian-Ping Yu

Roles

Abstract

Structure description

Figure 1.

Figure 2.

Figure 3.

Synthesis and crystallization

Refinement

Table 1. Experimental details.

Supplementary Material

full crystallographic data

Crystal data

Data collection

Refinement

Special details

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²)

Atomic displacement parameters (Å²)

Geometric parameters (Å, º)

Funding Statement

References

Associated Data

Supplementary Materials

ACTIONS

PERMALINK

RESOURCES

Cite

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PERMALINK

Bis[μ3-2-(pyridin-3-yl)acetato-κ3 O:O:O′]bis­[μ2-2-(pyridin-3-yl)acetato-κ2 O:O′]bis­[chlorido­(1,10-phenanthroline-κ2 N,N′)dysprosium(III)]

Yan Lin

Jian-Ping Yu

Roles

Abstract

Structure description

Figure 1.

Figure 2.

Figure 3.

Synthesis and crystallization

Refinement

Table 1. Experimental details.

Supplementary Material

full crystallographic data

Crystal data

Data collection

Refinement

Special details

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

Atomic displacement parameters (Å2)

Geometric parameters (Å, º)

Funding Statement

References

Associated Data

Supplementary Materials

ACTIONS

PERMALINK

RESOURCES

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Bis[μ₃-2-(pyridin-3-yl)acetato-κ³ O:O:O′]bis[μ₂-2-(pyridin-3-yl)acetato-κ² O:O′]bis[chlorido(1,10-phenanthroline-κ² N,N′)dysprosium(III)]

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²)

Atomic displacement parameters (Å²)