Table 3.
Corrole | Eox1 | Eox2 | Eox3 | Ered1 | EHOMO d | ELUMO e | ΔE |
---|---|---|---|---|---|---|---|
1 * | +0.65 V a | +0.78 V c | +0.95 V c | −1.29 V b | −5.45 | −3.51 | 1.94 |
2 | +0.80 V a | +1.32 V c | - | −1.18 V b | −5.60 | −3.62 | 1.98 |
3 | +0.60 V a | +1.09 V c | +1.93 V c | −1.21 V b | −5.40 | −3.59 | 1.81 |
4 | +0.21 V a | +0.95 V c | +1.62 V c | −1.37 V b | −5.01 | −3.43 | 1.58 |
a Anodic peak = Epa; b Cathodic peak = Epc; c E1/2 = Epa + Epc/2; d EHOMO = −[4.8 + Eox1 (versus SHE]eV; e ELUMO = −[4.8 + Ered1 (versus SHE]eV; * Ref. [5].