Eco-friendly Screen Printing of Silver Nanowires for Flexible and Stretchable Electronics

Abstract

Screen printing is a promising route towards high throughput printed electronics. Currently formulation of nanomaterial based conductive inks involves complex formulation with often toxic surfactants in the ink’s composition, making them unsuitable as an eco-friendly printing technology. This work reports the development of a silver nanowire (AgNW) ink with a relatively low conductive particle loading ink of 7 wt%. The AgNW ink involves simple formulation and comprises a biodegradable binder and a green solvent with no toxic surfactants in the ink formulation, making it an eco-friendly printing process. The formulated ink is suitable for printing on diverse range of substrates such as polydimethylsiloxane (PDMS), polyethylene terephthalate (PET), polyimide (PI) tape, glass, and textile. By tailoring the rheological behaviour of the ink and developing a one-step post-printing process, a minimum feature size of 50 μm and a conductivity as high as 6.70×10⁶ S·m⁻¹ was achieved. Use of a lower annealing temperature of 150 °C makes the process suitable for plastic substrates. A flexible textile heater and a wearable hydration sensor were fabricated using the reported AgNW ink to demonstrate its potential for wearable electronic applications.

Graphical Abstract

Introduction

Printed electronics (PE) are revolutionizing the field of flexible and stretchable electronics.¹ Features like low-cost fabrication, less material wastage, adaptability to roll-to-roll manufacturing process, and compatibility with elastomeric substrates has attracted researchers to develop sensors for non-planar surfaces like human skin.²

A wide variety of printing methods, broadly defined as non-contact and contact-based, have been reported for printing nanomaterial-based inks on stretchable and flexible substrates.³ Among different non-contact printing methods, Electrohydrodynamic (EHD) printing offers high resolution printing by producing droplets much smaller than the nozzle diameter. This unique feature provides printability of metal nanowire (NWs) (generally >10 μm in length) without the issue of nozzle clogging as encountered in inkjet printing.^4–6 However, EHD printing suffers from low throughput which hinders its applicability at commercial level.⁷ Gravure printing, on the other hand, is a contact-based printing method and is suitable for large-scale applications due to its low cost, high speed, and compatibility with roll-to-roll processes.⁸ However, the issue of ink drag-out from the cells during doctor blade wiping can lead to deteriorated pattern fidelity.⁹

Screen printing involves deposition of ink by pressing it through a patterned stencil with a squeegee.¹⁰ It is well suited for rapid and scalable manufacturing of printed electronics due to its low-cost and facile operability.^11,12 A distinctive feature of screen printing is that it offers printing of high-aspect-ratio patterns.¹³ Typically, a screen-printing process is limited to a resolution of 50–150 μm in accordance with a screen mask resolution of 40–120 μm.¹⁰ However, higher-resolution patterns can be achieved by modifying the surface energy of the substrate and/or viscosity of the printing ink.^14–17

Recently, nanomaterials such as metal nanoparticles (NPs), metal nanowires (NWs), carbon nanotubes (CNTs), graphene, and conductive polymers have been utilized for formulating conductive inks for screen printing.¹² Amongst these nanomaterials silver NWs (AgNWs) have received considerable interest for flexible and stretchable electronics due to their high electrical conductivity, mechanical robustness, and optical transparency.^18,19 For instance, Li et al. screen printed ultra-long AgNWs for fabricating flexible transparent conductive films and wearable energy storage devices. The high conductivity of 8.32×10⁵ S·m⁻¹ and optical transparency (~80%) of the printed patterns made them a compelling replacement for the rigid indium titanium oxide.¹⁴ Liang et al. formulated a water-based AgNW ink for fabricating stretchable conductors and wearable thin-film transistors on flexible substrates. A minimum feature size of 50 μm and a high conductivity of 4.67×10⁶ S·m⁻¹ were achieved.¹⁹ Furthermore, a thixotropic ternary ink consisting of hydrous ruthenium oxide (RuO₂.xH₂O) NPs, AgNWs, and graphene oxide were used to screen print micro-supercapacitors. The hybrid ink aided in achieving a high resolution of 50 μm and a conductivity of 5×10⁵ S·m⁻¹.²⁰ Despite the great success in formulating AgNW-based screen-printing inks for flexible and stretchable electronics, a few challenges remain: 1) The existing inks typically involve complex formulations. 2) The inks are not eco-friendly (e.g., the polymer binder is not biodegradable). 3) High conductive particle loading, and multiple post-printing steps are typically required to achieve the desired electrical conductivity. In addition, developing a single printing process, which is suitable for printing on various flexible substrates like plastics, elastomers, papers, and rough textile surfaces, is also desirable.^21–23

Water-based screen-printing inks have gained interest due to their eco-friendly nature as they address the disposability threat possessed by organic solvents.²⁴ Camargo et al. screen-printed disposable electrodes by formulating an eco-friendly water-based conductive ink comprising of chitosan, graphite powder, and glycerol.²⁴ Similarly, Franco et al. formulated a graphene ink by utilizing a carboxy methyl cellulose as a water-soluble polymer.²⁵

In this work, we report development of AgNW based ink that comprises of poly(ethylene) oxide (PEO) as a biodegradable binder and deionized (DI) water as a “green solvent” with no toxic surfactants in the ink formulation, making it an eco-friendly printing technology. A relatively low AgNW loading (7 wt%) and a single step low-temperature post-printing treatment features the merit of low-cost screen printing. The screen printed AgNW lines exhibit conductivity as high as 6.70×10⁶ S·m⁻¹. Uniform and continuous lines with a minimum feature size of 50 μm are achieved by tailoring the rheological properties of the ink. In addition, it is capable for printing on diverse range of substrates such as polydimethylsiloxane (PDMS), polyethylene terephthalate (PET), polyimide (PI) tape, glass, and even rough textile surface, which is difficult to print with other printing methods. Lastly, wearable devices based on the printed AgNWs are demonstrated by fabricating flexible heaters on textiles and wearable hydration sensors on PDMS.

Results and discussion

Conductive inks for screen printing are usually a mixture of three components: conductive nano or micro particles as fillers, an organic binder/additive, and a solvent. Printability of the ink and conductivity of the printed pattern are influenced by solid loading, particle dispersion, and density of the conductive fillers.¹⁹ Organic binders/additives in combination with solvents promote dispersion stability, particle wettability, and adhesion to the substrate.⁸ They also provide the desired rheological behaviour to the ink for screen printing and regulate ink drying during and after printing.²⁶ In this work, AgNWs were used as conductive fillers for the ink. To tune the viscosity of the ink, poly(ethylene oxide) (PEO), a non-ionic water-soluble polymer, was used as a rheological agent. The high molecular weight of PEO (average Mv ~1,000,000) assists in dramatically increasing the viscosity of the ink and provided a shear-thinning thixotropic behaviour. Furthermore, it can act as a surfactant as the hydroxy groups in PEO can bond with the surface of AgNWs and improve their dispersion in the ink.⁸ DI water and ethanol served as solvents for the ink. The key properties of non-toxic ethanol, i.e., lower boiling point and lower surface tension than water, prevent undesirable aggregation of AgNWs, which results from contact line recession and dewetting during the evaporation process. However, the solubility of high molecular weight PEO in pure ethanol at room temperature is a challenge.²⁷ Therefore, a solvent mixture consisting of DI water and ethanol in the weight ratio of 50:50 was used. DI water was selected as the second solvent due to its environmental friendliness. In a typical ink formulation, PEO powders with four different concentrations (4%, 5%, 6%, and 7% weight ratio) were first mixed with ethanol and DI water by stirring for 24 h to form a homogenous solution. Then, AgNWs were added into the PEO solutions to make four different inks with 7 wt% AgNW solid loading (Figure 1a) and PEO weight ratio of 4% (AgNW Ink A), 5% (AgNW Ink B), 6% (AgNW Ink C) and 7% (AgNW Ink D). The inks weare mixed for 30 min to obtain an even dispersion.

Figure 1.

(a) Constituents of AgNW based screen printing ink and photograph of the AgNW Ink B (7 wt% AgNW-5 wt% PEO). (b) Viscosity as a function of shear rate for the AgNW Ink B. (c) Rheological behaviour of the AgNW Ink B during the screen-printing process. (d) Oscillatory rheological test for the AgNW Ink B ink showing variation of G’ and G” as a function of shear stress. (e) Illustration of the screen-printing process.

Performance of a screen-printed pattern is governed by the viscosity and rheological behaviour of the ink^.19 Therefore, rheological characterization of the ink was performed using a parallel-plate rheometer. Firstly, 7 wt% AgNWs (AgNW Ink B) was tested alongside 5 wt% PEO solution (without AgNWs) to determine the influence of AgNWs on the rheological properties of the ink (Figure S1a). At the same shear rate of 0.1 s⁻¹, viscosity of the AgNW Ink B and 5 wt% PEO solution (without AgNWs) was 144.45 and 36.30 Pa·s, respectively. The difference in viscosity was observed because NWs can act as an active crosslinker and can constitute a solid 3D network in the ink suspension causing higher viscosity.^19,20 Moreover, at low shear rates, random orientation of the AgNWs in the suspension causes an increase in viscosity. Hemmati et al. also observed that rheological behaviour and flow characteristics of the AgNWs depends on their solid content in the suspension²⁸ which in our work was fixed as 7 wt% among all PEO solution. Furthermore, in the absence of a rheological modifier, the shear-thinning behaviour showed by pure AgNW suspension is unsuitable for screen printing (viscosity of <1 Pa·s) due to the to the formation of macroscopic AgNW aggregates above 5 s⁻¹ shear rate.²⁹ Based on the above-mentioned reasons, further rheological characterization was performed only on different wt% PEO solutions.

Figure S1b demonstrates that all PEO solutions (4%, 5%, 6%, and 7% weight ratio) exhibited shear thinning behaviour of a non-Newtonian fluid that can be observed through decreasing viscosity with increasing shear rate. This characteristic property allows for a high-resolution print as the ink rapidly recovers to its initial viscosity once the squeegee stroke has ended.²⁹ It can be observed that solution with a higher PEO amount showed higher viscosity at the same shear rate. The degree of entanglements of the polymer coils increases with the polymer concentration, producing a higher viscosity.³⁰

Next, the screen-printing process can be categorized into three distinct steps where each step is associated with a shear rate during the printing process. The first step involves ink transfer onto the stencil. In this stage, the ink is subjected to small deformations and low shear. During the second step (printing stroke), large shear rate acts on the ink which allows it flowing through the stencil/mesh screen.²⁹ In the final step, ink progressively returns to the viscosity in the first step. Peak hold step test was conducted to simulate the above-mentioned steps in the printing process.^19,30–31 The test involved holding the PEO solution at different shear rates in three intervals as shown in Figure S1c. In the first interval, a shear rate 0.1 s⁻¹ was maintained for 30 s. Second interval simulated the printing stroke with a shear rate of 200 s⁻¹ for 30 s. Finally, shear rate in the third interval was decreased to 0.1 s⁻¹ and maintained for 200 s to observe the viscosity recovery after printing. 4 wt% PEO solution showed the lowest viscosity of 8.08 Pa·s at the 0.1 s⁻¹ shear rate at the time of 20 s. The solution recovered to 100% (at 90 s) of its initial viscosity after the shear rate was reduced from 200 to 0.1 s⁻¹. Although 4 wt% PEO solution displayed 100% recovery, its low viscosity could cause ink spreading after printing which could negatively impact the line resolution. Table S1 depicts that with increasing PEO concentration, the solution takes longer time to recover to its initial viscosity.

The imposed shear deformation during printing disrupts the entangled polymer coils. Longer recovery time of the solution with higher PEO content is because the rate of disruption of the entangled polymer coils is higher than the rate of formation of the new ones.³² Recovery time of the ink plays a crucial role in levelling the ink after printing, leading to a uniform deposition with no voids and/or irregularities.^17,27 Amongst all four PEO solutions, the 5 wt% PEO demonstrated the ideal rheological behaviour for screen printing. Henceforth, AgNW Ink B (7 wt% AgNWs with 5 wt% PEO) was tested for all future experiments.

Figure 1b demonstrates the viscosity at different shear rates from the steady-state flow step test. The AgNW Ink B exhibited a shear thinning behaviour with a viscosity of 144.45 Pa·s at 0.1 s⁻¹ shear rate. The peak hold test in Figure 1c and Table 1 show that AgNW Ink B recovered to 83.8% of the initial viscosity in 30 s after the printing stroke, which portrays desirable elasticity of the ink. Usually, inks incorporating Ag particles/flakes can barely exceed 70% recovery.²⁶ The better performance of AgNW Ink B from particle-based inks stems from the outstanding properties of AgNWs in the ink formulation. However, the recovery of the AgNW Ink B was lower than the pure 5 wt% PEO solution. This was because of the combined influence of rearrangement of polymer coils in PEO and reorientation of AgNWs from an aligned state at high shear rate to a random network under low shear rate.^28,32 Figure S2 and Table S2 provide the recovery values for different wt% PEO solutions and AgNW-based inks. For AgNWs, the rate of rearrangement and hence, viscosity recovery is controlled by the wire-wire interaction and hydrodynamic forces, both of which depends on the AgNW content in the suspension.²⁸

Table 1.

Viscosity of AgNW Ink B at different shear rates. Each shear rate corresponded to a printing step in the screen-printing process.

Screen Printing Ink	0.1 s−1 @ 20s	200 s−1 @ 50s	0.1 s−1 @ 80s	Recovery @ 80s (%)	0.1 s−1 @ 90s	Recovery @ 90s (%)
AgNW-PEO Ink B	134.31	2.56	99.19	73.9	112.54	83.8

Oscillatory rheological measurements were conducted for AgNW Ink B to further characterize its viscoelastic effect in a stress sweep step test. Figure 1d presents the variation of storage modulus G′ (elastic component) and loss modulus G′′ (viscous component) as a function of shear stress. The viscoelastic behaviour can then be evaluated using the loss factor tan (δ) according to Eq. (1)

$$\text{tan}(\delta )=\frac{G\prime \prime }{G\prime }$$ (1)

From Eq. (1), it can be inferred that when tan (δ) is higher than 1, the viscous component G′′ will dominate and the ink will exhibit liquid-like behaviour. However, when tan (δ) is lower than 1, the ink will demonstrate solid-like behaviour. Region I in figure 1d shows the linear viscoelastic region. Here, the ink can endure mechanical deformations without disrupting its molecular structure. With increasing shear stress, the ink structure starts to disintegrate and the value of G′ and G′′ gradually decreases, although the AgNW Ink B still maintains elastic behaviour. At a shear stress of 306.9 Pa, the storage modulus becomes equal to the loss modulus (G′=G′′). With further increase in shear stress, G′′ exceeds G′ and the ink displays fluid-like behaviour.

Figure 1e illustrates the screen-printing process. A laser cut stainless-steel stencil of ~100 μm in thickness was employed. Thinner stencil can impart the mechanical flexibility needed to deform the stencil during the printing stroke.¹⁰ An off-contact distance of 2 mm was used between the stencil and the substrate, achieved by using PDMS spacers whose adhesive surface provided the benefit of securing the stencil and the substrate during the printing process. The off-contact distance assists in applying the desired squeegee pressure to deform the stencil. It also prevents the stencil from resting back on to the wet printed layer, thus eliminating smudging of the printed pattern. During printing stroke, the stencil bends and forms a contact between the stencil and the substrate. The ink fills into the stencil openings in front of the squeegee and finally, the stencil snaps back to its initial position transferring the ink on to the target substrate.¹⁷ Traces from the first printing pass were baked for 5 min at 75 °C without removing the stencil. Baking is necessary because wet ink in the second printing pass cannot be overprinted without smearing and smudging. A second printing pass was performed by moving the squeegee in the reverse direction.

The post-printing treatment involved thermally annealing the AgNW patterns printed on glass in air within a temperature range of 100 to 250 °C to determine the influence of residual solvents and PEO on electrical performance. Figure 2a illustrates that the resistance of the printed patterns decreased with the increasing annealing temperature for a fixed annealing time of 30 min. The resistance dropped sharply from an initial value of 8.72 Ω to 0.73 Ω at 150 °C and further reduced to 0.71 Ω at 165 °C. Increasing the temperature above 200 °C initiated burning of the AgNWs which negatively impacted the electrical properties. Figure 2b shows that an annealing temperature of 150 °C and an annealing time of 30 min were sufficient to achieve a minimum resistance. The decrease in resistance of the printed patterns can be attributed to fusion of the AgNW junctions (Figure 2c), removal of the solvents, and partial removal of PEO (Figure 2d)³³. The relatively lower annealing temperature made the post-printing treatment compatible with polymeric substrates like PET, PI and PDMS. PEO is water soluble, however using water washing as a post-printing treatment can be cumbersome and unsuitable at large scale. Moreover, it can also wash away the AgNWs from the printed pattern impacting its electrical properties.^27,34 Figure S2a shows adopting water-washing as the only post-printing treatment is not enough to achieve the desired electrical conductivity. The resistance after thermal annealing at 150 °C for 30 min (Figure 2b) was (0.65±0.072) Ω and after seven wash cycles was (6.73±0.135) Ω as shown in Figure S3a. Besides, small amount of residual PEO can provide solvent resistance to the AgNW film. This could be due to the generation of water insoluble substances on possible cross-linking of PEO during the heat treatment process.²⁷ Cross-linking constraints the PEO chain segments by tying the carbon atoms from different polymer chains together. This way, the original viscous linear segments of the polymer are transformed into an insoluble gel network preventing the polymer chains from escaping into the solvent solution.^32,35 As expected, the screen printed AgNW patterns showed stable resistance even after immersing them in two different solvents for prolonged time periods (Figure S3b).

Figure 2.

(a) Influence of post-print treatment process. Resistance of screen-printed AgNW patterns as a function of annealing temperature for a fixed time of 30 min. Inset showing the resistance values for the annealing temperature between 150 °C to 250 °C. (b) Variation of resistance with annealing time for a fixed temperature of 150 °C and 165 °C. (c) High resolution scanning electron microscopy (SEM) image of fused AgNW junctions after post-printing treatment. Scale bar 500 nm. (d) TGA and DTG thermograms of AgNW Ink B. Inset showing TGA and DTG thermograms between 100 and 260 °C. (e) Calculated conductivity and sheet resistance of AgNW lines with increasing printing passes. At least three samples were tested for each line width. (e) Printed line width and thickness of screen printed AgNW lines with increasing printing passes using a 200 μm designed line width.

To further decrease the resistance of the printed patterns and to increase the uniformity, the influence of printing passes was studied. As shown in Figure 2e, the conductivity of the printed AgNW patterns increased with the second printing pass and remained nearly constant with further increase of printing passes. The sheet resistance and conductivity of printed AgNW patterns after two printing passes and thermal annealing were 0.052 ± 0.01 Ω·sq⁻¹ and (6.29 ± 0.64) ×10⁶ S·m⁻¹, respectively. Increase in conductivity with the second pass is probably associated with a more uniform printed pattern with lesser printing defects (Figure S4). Besides, line width and thickness of the printed patterns increased with the number of passes (Figure 2f). Since higher printing passes can negatively influence the resolution of the patterns, two printing passes were found to be optimal. The line width of the printed trace increased from 222.4 μm in the first printing pass to 227.2 μm in the second printing pass.

Optical images shown in Figure 3a represent printed AgNW lines on glass with various line widths of 50, 75, 100, 150 and 200 μm. All the printed lines demonstrated sharp edges and uniform line widths. In this work, a printed line width resolution of 50 μm was achieved. The printed line width and thickness as functions of the designed stencil width are displayed in Figure 3b. The width of the printed line was slightly larger than the stencil width, resulting from the combined effect of ink penetration into the gap between the stencil and the substrate and ink spreading after printing.¹⁷ The thickness of the printed lines appeared to increase linearly with line width.

Figure 3.

(a) Optical microscope images of AgNW lines printed on a glass substrate with line widths of (i) 200, (ii) 150, (iii) 100, (iv) 75 and (v) 50 μm. Scale bar 100 μm. (b) Printed line width and thickness of AgNW lines as a functions of the designed line width. (c) Calculated sheet resistance and conductivity of screen printed AgNW lines with various designed line widths. At least three samples were tested for each line width. SEM image of printed AgNW line and corresponding NW alignment for (d) 50 μm line width and (e) 200 μm line width.

To characterize the electrical properties of the screen-printed patterns, AgNW lines of 6 mm in length with different widths of 50, 100, 150, 200 and 250 μm were printed on a PI tape and thermally annealed. Figure 3c represents the conductivity and sheet resistance as functions of the designed stencil width. It is seen that the sheet resistance decreases, and electrical conductivity increases with the line width. This could be attributed to the differences in AgNW alignment at different line width as shown in Figure 3d and 3e. During the printing stroke, squeegee introduces a shearing force to the AgNWs which can align them in the printing direction.⁶ Interestingly, the AgNWs show better alignment along the printing direction for a larger line width. Printing speed is an important parameter in a screen-printing process. Lower printing speed is desired for narrower lines in order to completely transfer the ink onto the substrate (Figure S5). In our case, for example, the optimized printing speeds for the line widths of 50 and 200 μm were ~6 and 12 cm·s⁻¹. However, lower printing speed causes lower-degree AgNW alignment. Figure S6 shows the AgNW alignment for different printed line widths. Better alignment of AgNWs can generally lead to higher conductivity of the printed AgNW patterns. Table 2 compares the resolution, electrical conductivity and post printing treatment processes between our work and reported screen printing works utilizing different inks. For a low AgNW solid loading (7 wt%) and one-step post printing treatment, lines printed using AgNW Ink B exhibited a better electrical conductivity than those achieved by the Ag particle/flake-based inks.³⁵

Table 2.

Comparison of ink composition, line resolution, electrical conductivity, and post-printing treatment in screen printing between various literatures.

Screen Printing Ink	Line Resolution (μm)	Electrical Conductivity (S·m−1)	Post-Printing Treatment	Ref.
Ag NPs, 77 wt%	22	1.81 × 107	1) Heat: 200 °C, 30 min	[17]
Ag NPs, 80 wt%	-	2.43 × 107	1) Heat: 450 °C, 15 min	[37]
Ag flakes, 43 wt%	50	738 × 102	1) Heat: 80 °C, 30 min	[38]
Ag flake, 70 wt%	-	6.67 × 106	1) Heat at 120 °C for 10 min to remove solvents. 2) Heat: 850 °C, 10 min	[36]
Graphene, 10 mg/mL		2.8 × 102	1) Overnight heating at 90 °C or 40 s of microwaving	[39]
Graphene, 80 mg/mL	40	1.86 × 105	1) Heat: 300 °C for 30 min	[10]
Graphene & Carbon Black 85:15 wt% ratio	90	2.15 × 104	1) Drying at 10 °C for 8 min. Compressed rolling. 2) Drying at 150 °C for 8 min.	[40]
AgNWs, 0.9 wt%	50	5.5 × 106 (For 0.5 mm)	1) Drying at 80 °C for 10 min to evaporate solvents. 2) Immersing AgNW samples in warm water (60 °C) or ethanol for 5 min to remove PVP. 3) Illuminating AgNWs by a high-intensity pulsed light with a broad wavelength of 200–1500 nm.	[41]
AgNWs, 1.97 wt%	-	1.9 × 105	1) Heat at 120 °C for 10 min to remove terpineol. 2) Washing in acetone for 2 min to remove ethylene cellulose. 3) Washing in ethanol bath for 5 min to remove PVP. 2) Laser sintering of AgNWs with Yb: fiber laser.	[42]
AgNWs, 6.6 wt%	50	4.67 × 106	1) Multiple cycles of heating at 150 °C for 5 min to evaporate the solvent. 2) Washing with ethanol and water mixture (1:20) for 5 min to remove part of the additives. 3) Annealed at 150 °C for 5 min to fuse the AgNW junctions.	[19]
AgNWs, 10 wt%		3.4 × 106	1) Dry at 110 °C for 10 min	[43]
AgNWs, 7 wt%	50	6.70 × 106 (For 0.25 mm)	1) Heat: 150 °C for 30 min	Our Work

Besides, the use of a lower sintering temperature (150 °C) in our work makes the process compatible with flexible plastic substrates. The combination of high resolution, high conductivity, and relatively low-temperature post printing process, makes our formulated AgNW ink stand out from the previously reported works.

The screen printed AgNW patterns were further characterized to evaluate their flexibility and stretchability, which are a key requirement for wearable electronics.⁴ For tensile tests, the AgNW pattern was first printed on a PDMS substrate, and then encapsulated by another layer of PDMS. Figures 4a and b shows the performance of the AgNW-PDMS conductor under uniaxial tensile strain. Besides, the AgNW-PDMS conductor showed stable performance even after 450 cycles of tensile stretching and releasing between 0 and 10% strain (Figure 4c). For testing the bending performance, AgNW patterns were printed on a flexible PET substrate of thickness 0.15 mm. Figure 4d depicts that the maximum bending strain on the AgNW pattern was 4.68% at the smallest bending curvature radius of 1.6 mm. For the cyclic bending test (Figure 4e), the resistance of the screen-printed pattern changes only 2% after 530 cycles of bending with at 5 mm bending radius and 1.5% bending strain%. Moreover, Figure 4f shows stable performance (LED light stays turned ON) of a screen printed Peano curve under severe deformation conditions such as bending, folding, and squeezing.

Figure 4.

(a) Resistance change of screen printed AgNW-PDMS conductor as a function of uniaxial tensile strain (0 to 20.67%). (b) Tensile loading and unloading plot of screen printed AgNW-PDMS composite as a function of tensile strain. (c) Resistance changes under 450 tensile stretching and releasing cycles of 10% strain. (d) Resistance changes as a function of bending curvature radius (8.56–1.6 mm). (e) Resistance changes under 530 bending cycles with 5 mm bending radius and 1.5% bending strain. Inset showing resistance change between 50 to 100 bending cycles. (f) Images of screen printed Peano curve on PDMS under different mechanical deformations of bending, folding, and squeezing. Scale bar: 5 mm.

Using the screen-printing process, different AgNW patterns such as lines, curves, and fractal pattern of Peano curve were printed on different substrates such as glass (Figure 5a–d), PDMS (Figure 5e–g), textile (Figure 5h–i), and PET sheet (Figure 5j). The optical images reveal that the printed curved lines (Figure 5k–m) have continuous and smooth boundaries. Compatibility of the current printing process with different substrates along with good electromechanical performance strengthens its adaptability for wearable electronic applications.

Figure 5.

Demonstration of screen-printing capability. Printed AgNW patterns on glass slide, (a) 50 to 250 μm lines, (b) Peano curve, (c) curved lines, and (d) interdigitated pattern. Printed AgNW patterns on PDMS, hydration sensor on (e) relaxed wrist, (f) flexed wrist, and (g) Peano curve. Printed AgNW patterns on textile (h) serpentine pattern and (i) serpentine array. (j) AgNW electrode array printed on PET sheet. Scale bar 10 mm. (k), (l), and (m) Optical images of printed curved lines with the corresponding insets showing smooth boundaries.

To demonstrate the application potential of screen printing, a textile-based flexible heater and a wearable hydration sensor were fabricated. Thermal therapy is widely used to treat osteoarthritis and carpal tunnel syndrome.⁴⁴ In the case of osteoarthritis, heat wrap increases tissue temperature which leads to improved blood flow. It also improves muscle extensibility by reducing stiffness and inflammation of the injured tissue.⁴⁵

It also alleviates pain during rehabilitation in sports related injuries.⁴⁶ In this work a textile-based heater was fabricated by directly screen printing the AgNW ink on the textile followed by the post-printing step. The morphology of both the textile and the screen-printed AgNW patterns on textile was evaluated using confocal microscopy. The maximum height of the profile (Rz) for the textile was found to be 104 μm, showing high surface roughness. Figure S7 and S8 show the 3D height maps and thickness profiles of the screen-printed patterns on the textile.

In Figure 6a, a stepwise voltage ranging from 1 to 5 V was applied to the textile-based heater. It can be seen that the temperature of the heater rose with the increasing voltage and at 5 and 6 V, the maximum temperatures were ~46 °C and 57 °C, respectively. Commercial heating pads usually operate in the temperature range of 40 to 60 °C, and therefore further testing on the textile-based heater was done at 5 V.

Figure 6.

Screen-printed textile based AgNW heater. (a) Temperature evolution of heater under stepwise voltage from 0 to 6 V. (b) Infrared (IR) thermal image of the textile-based heater at 5 V and 0V. (c) Temperature evolution of the heater under repeated heating cycle operations (160 cycles). (d) Heater performance for 18 min at 5V. Inset showing photograph of the textile-based heater. (e) IR images of the heater during (i) relaxed wrist, (ii), (iii) and (iv) various wrist flexing positions. (f) Impedance of the screen-printed wearable hydration sensor before and after applying lotion on the skin. (g) Impedance versus time of the hydration sensor at 100 kHz. Inset showing the hydration sensor on wrist. Scale bar: 10 mm.

Figure 6b shows infrared (IR) thermal image of the textile-based heater at 5 V. For practical applications, reliability and heating stability of the heater is crucial. Figure 6c shows 160 heating and cooling cycles on the textile-based heater. In each cycle, a voltage of 5 V was applied to the heater for 15 s and then turned off to naturally cool for 15 s. The temperature ranged between 42 °C and 34 °C. The heater could not return to room temperature (RT) within 15 s due to the relative slow thermal transport of the textile. Figure 6d shows long-term performance of the heater. Figure 6e depicts the textile heater on wrist and its stable performance when flexing the wrist., The heater can also withstand different folding deformation as shown in Figure S9.

As another application demonstration, an epidermal hydration sensor was screen printed. Skin hydration is a crucial physiological parameter for assessing the status of the skin diseases such as eczema, cracking of stratum corneum, and acne, which can lead to damaged skin and increased transdermal water loss. ⁴⁷ Although, skin hydration can be obtained through measurements of electrical impedance, thermal conductivity, and spectroscopy, impedance is a direct indicator of hydration due to the high influence of water content on skin permittivity and conductivity.⁴⁷ A hydration sensor was fabricated by printing AgNW ink on a glass substrate followed by spin coating liquid PDMS, such that the AgNWs were embedded below the PDMS surface to form a AgNW/PDMS composite.^48,49 To evaluate the performance of the hydration sensor, impedance measurements were performed at different time periods to correlate with the hydration level of the skin. Figure 6f depicts that impedance dropped sharply after applying lotion on the skin. At 100 kHz, the impedances before and after applying lotion were 1.694 kΩ and 1.190 kΩ, respectively (Figure 6g). As time progressed, the impedance gradually increased and recovered back to its initial level in 28 minutes, similar to previously reported results.^49,50 While the effect of the external ambient conditions on the sensor performance was not characterized in this work, our previous work showed that the hydration sensor produced stable performance in response to the skin hydration, regardless of the external environmental conditions of the wearer.⁴⁸

Experimental

Synthesis of AgNWs/PEO

AgNWs were fabricated by modified polyol process⁵¹. First, 60 ml of 0.147 M polyvinylpyrrolidone (PVP) (Mv ∼40,000; Sigma-Aldrich) solution in ethylene glycol (EG) was added to a three-neck round-bottom flask that was suspended in an oil bath at 151.5 °C. A stir bar was added to the flask and the solution was magnetically stirred at 260 rpm for 1h. Then, 200 μL of 24 mM CuCl2 (CuCl2·2H2O, 99.999+%; Alfa Aesar) solution in EG was added into the heated solution. After an additional 15 min heating, 60 ml of 0.094 M AgNO3 (99+%; Sigma-Aldrich) solution in EG was added to the flask. Upon nanowire formation, the solution was cooled to room temperature. Products were washed with acetone first, and then with ethanol. AgNWs were suspended in ethanol for ink preparation.

Preparation of AgNW/PEO Ink

Poly(ethylene oxide) powder (PEO, average Mv ~1,000,000 purchased from Sigma Aldrich) was first dissolved in a mixed solvent with a 50:50 weight ratio of ethanol and deionized water (DI water) to form solutions with different PEO content (4, 5, 6 and 7 wt%). Then, AgNWs with an average diameter of ~100 nm and an average length of ~25 μm were added into the PEO solutions to make four different screen-printing inks with 7 wt% AgNW solid loading and PEO weight ratio of 4% (Ink A), 5% (Ink B), 6% (Ink C) and 7% (Ink D). The as-prepared inks were magnetically stirred at 1000 rpm for 30 min to ensure an even dispersion. Then, AgNWs with an average diameter of ~100 nm and an average length of ~25 μm were added into the PEO solutions to make four different screen-printing inks with 7 wt% AgNW solid loading and PEO weight ratio of 4% (Ink A), 5% (Ink B), 6% (Ink C) and 7% (Ink D). The as-prepared inks were magnetically stirred at 1000 rpm for 30 min to ensure an even dispersion.

Screen Printing and Post Printing Treatment of AgNW Patterns

Screen printing was performed manually using a ~100 μm thick custom-made stainless-steel stencil from Stencils Unlimited. The stainless-steel stencil was separated from the glass substrate by a 2 mm thick PDMS spacers. For printing, AgNW ink was placed on top of the stencil and was manually pushed across the stencil’s opening with a rubber squeegee at an angle of ~45° angle with the stencil. The printing speed was manually optimized to ~6 and ~12 cm·s⁻¹ for narrower (such as 50 μm) and wider (such as 200 μm) line widths, respectively. The printing process was repeated two times for achieving a uniformly printed pattern. Between each printing pass, the sample were baked in an oven at 75 ⁰C for 5 min. The printed AgNW patterns were annealed at 150 ⁰C for 30 min as a post printing treatment step.

The morphologies of the screen printed AgNWs lines were studied by using field emission scanning electron microscopy (FESEM) (FEI Quanta 3D FEG) operated at 5 kV. The alignment of the printed AgNW lines was measured by analysing ~1000 AgNWs for each line width in the ImageJ software. The AgNW alignment was distributed from – 90° to 90° with 0° indicating the printing direction. An optical microscope (Nikon Eclipse LV150N) was used for obtaining the dimensions of the printed AgNW lines. A 4-probe method was used to measure the resistance of the printed lines using a digital multimeter (34001A, Keysight Technologies). Keyence VKx1100 confocal laser scanning microscope was used to measure the thickness of the screen-printed patterns and the morphology of the textile. Three samples of each case were tested for calculating an average sheet resistance and conductivity. Rheological behaviour of the formulated AgNW inks was studied using a TA instruments AR-G2 rotational rheometer. A 40 mm diameter parallel plate geometry and a gap height of 850 μm was used for the rheological experiments. All the rheological tests were performed at room temperature 25 °C. A pre-conditioning step of 0.1 s⁻¹ shear rate for 15 s was applied before each test. The steady-state flow sweep test was performed by varying the shear rates from 0.1 to 1000 s⁻¹. In the peak hold test, constant shear rate of 0.1 s⁻¹ for 30 s, 200 s⁻¹ for 30 s, and 0.1 s⁻¹ for 200 s was applied to simulate the screen-printing process. Oscillatory frequency sweep test was performed with a frequency sweep from 0.1 to 100 rad·s⁻¹. Storage (G′) and loss modulus (G′′) were determined through the stress sweep test, performed at an oscillation stress of 1–1000 Pa and a frequency of 100 rad·s⁻¹. The stretchability analysis of the screen printed AgNW lines on PDMS was performed using a custom made motorized linear stage and a digital multimeter (Keysight DAQ970A) to monitor the real time resistance change. Before printing, PDMS was treated with oxygen plasma for 1 min to make the surface hydrophilic. AgNW patterns were printed on a flexible PET substrate for evaluating the bending performance. The solvent resistance of the screen printed AgNW pattern was evaluated by submerging the pattern into two different solvents, first, 80:20 weight ratio of DI water and ethanol and then acetone. Thermal gravimetric analysis (TGA) was performed on a TA Instruments Discovery SDT 650 in air at a rate of 5 °C/min.

Fabrication of Textile-based Heater and Hydration Sensor

AgNW Ink B was screen printed on textile (80% Nylon and 20% Spandex with a thickness of 0.4 mm) followed by post printing treatment. For testing, a DC power was used to supply current to the heater through the contact pads. An IR camera (FLIR A655sc) was used to record the temperature distribution across the heater.

The hydration sensor was fabricated by screen printing interdigitated pattern on a glass substrate followed by post printing treatment process. Next, liquid PDMS was spin coated at 400 rpm for 30 s on the printed pattern and cured at 75 °C for 3 h. The hydration sensor was peeled off from the glass substrate and then applied on the skin for impedance measurements using Keysight 4395A Impedance Analyzer. A sensing frequency of 100 to 200 kHz was used to evaluate skin hydration level before and after applying a hydrating lotion on the skin.

Conclusions

In summary, AgNW based ink for screen printing of flexible and stretchable electronics was developed. The formulated AgNW ink contains a relatively low solid loading of 7.0 wt% AgNWs, showing a viscosity of 144.45 Pa·s at 0.1 s⁻¹ shear rate, which is an appropriate rheological behaviour for screen printing. The use of biodegradable binder and DI water as a “green solvent” makes the process an eco-friendly printing method. Additionally, the screen-printing process enables printing on a diverse range of substrates including rough textiles surfaces which are usually hard to print upon using other printing methods. A single step post-printing treatment with a low thermal annealing temperature of 150 °C for 30 min was developed, leading to a conductivity as high as 6.70 × 10⁶ S·m⁻¹ even at lower AgNW loading of 7 wt%. Through screen printing, both uniform and sharp-edged lines with a resolution of 50 μm were printed. Complex patterns including interdigitated and Peano fractal patterns were also obtained. A textile-based heater on wrist was fabricated showing uniform and stable heating performance under cyclic heating/cooling and various bending deformations. Additionally, an epidermal hydration sensor was printed to measure the impedance of the human skin and correlate the data to the hydration level. The demonstrated results obtained through screen printing of the newly developed AgNW based ink highlighted its potential towards large scale production of wearable printed electronic devices.

Moreover, significant efforts are being made on developing strategies for eco-friendly wearable sensors with the majority of them being either using naturally occurring materials or recycling materials.⁵² For instance, Lei et al. developed a biocompatible semiconducting polymer for thin-film transistors utilizing cellulose. The thin-film transistors were fully degraded within 30 days in an acidic environment.⁵³ Williams et al. fabricated an all-carbon based thin-film transistors on paper in which both ink constituents (carbon nanotube and graphene) can be reclaimed and recycled.⁵⁴ Future work on recycling of AgNW-based screen-printed electronics can add to the sustainability of the developed process.