Adjustment of light intensity and CO2 supply to increasing cell densities during growth in HD culture (Table S1); three new anabaenopeptins from N. punctiforme KVJ2 and the similar congeners (Table S2); 1H and 13C data for anabaenopeptin KVJ827 in DMSO-D6 at 300 K (Table S3); MALDI-TOF spectra for selected peaks of N. punctiforme PCC 73102 as shown in Fig. 3 and 4 (Fig. S1); observed PSD fragments of nostopeptolides 1052 and A for Fig. S2 (Table S4); MALDI-TOF PSD spectra for nostopeptolides 1052 and A of N. punctiforme PCC 73102 (Fig. S2); observed PSD fragments of nostamide A for Fig. S3 (Table S5); MALDI-TOF PSD spectrum of nostamide A (Fig. S3); HPLC profile of the HD supernatant of N. punctiforme PCC 73102 (Fig. S4); HPLC profiles of cellular extracts and supernatants of N. punctiforme PCC 73102 with or without shaking and with or without supernatant exchange (Fig. S5); key HMBC and 1H-1H COSY correlations for anabaenopeptin KVJ827 (Fig. S6); 1H (Fig. S7) and 13C (Fig. S8) NMR spectra of anabaenopeptin KVJ827 in DMSO-D6; 1H-1H COSY spectrum of anabaenopeptin KVJ827 in DMSO-D6 (Fig. S9); HSQC (Fig. S10) and HMBC (Fig. S11) spectra of anabaenopeptin KVJ827 in DMSO-D6; observed fragments for Fig. S12 (Table S6); MALDI-TOF MS PSD spectra of anabaenopeptins KVJ827, KVJ841, and KVJ811 (Fig. S12); extracted ion chromatograms at negative ion mode of FDAA derivatives of standard amino acids by HPLC-MS (Fig. S13); extracted ion chromatograms at negative ion mode of FDAA derivatives of acid hydrolysates of anabaenopeptin KVJ811 (Fig. S14), KVJ827 (Fig. S15), and KVJ841 (Fig. S16) by HPLC-MS; stereochemistry determination of Ile in anabaenopeptin KVJ841 by using Sanger reagent DNFB (Fig. S17).
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