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. 1966 Jan;98(1):189–192. doi: 10.1042/bj0980189

Absorption spectra of sperm-whale ferrimyoglobin

George I H Hanania 1, Arpi Yeghiayan 1, Bruce F Cameron 1,*
PMCID: PMC1264813  PMID: 5938641

Abstract

1. Sperm-whale ferrimyoglobin was found to contain 0·308% of Fe, on a dry weight basis, corresponding to a molecular weight of 18130. The solid takes up moisture to an equilibrium state, and was then assayed to contain 0·280% of Fe. 2. Absorption spectra are presented for acidic ferrimyoglobin, Fe+(H2O), and its conjugate base, Fe–OH, as well as for the fluoride and cyanide complexes, within the range 200–2500mμ. Data for ferromyoglobin–carbon monoxide, Fe(II)–CO, in the visible region are also included. 3. Minor spectral differences have been found between whale and horse myoglobins, particularly in the effect of temperature on the visible-absorption spectrum of Fe–OH.

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Selected References

These references are in PubMed. This may not be the complete list of references from this article.

  1. Cameron B. F. Determination of iron in heme compounds. II. Hemoglobin and myoglobin. Anal Biochem. 1965 May;11(2):164–169. doi: 10.1016/0003-2697(65)90002-3. [DOI] [PubMed] [Google Scholar]
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